• Journal of Advanced Marine Engineering and Technology
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• 제20권2호
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• pp.92-92
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• 1996

Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

• Journal of Advanced Marine Engineering and Technology
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• 제20권2호
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• pp.24-31
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• 1996

Recently, with the rapid development in the oceanic systems such as the oceanic structures and vessel, there occurs much interest in the impingement erosion-corrosion. In this paper, Cu-metal was tested by using of erosion apparatus with water-jet type and was investigated under the behaviour of impingement erosion-corrosion according to various environmental conditions, and the properties of Cu-metal were evaluated through the measurement by weight loss, weight loss rate, protective efficiency. The results were compared with those obtained using Cu-metal applied to cathodic protection and Cu-alloys added to Zn or Al-metal. As a basis of those results, the best protective efficiencies could be taken as using cathodic protection method and Cu-alloy with Al & Zn material addings, and will be suggested as the fundamental data of the anti-impingement erosion-corrosion on Cu-metal of impeller material for oceanic centrifugal pump.

• 한국표면공학회지
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• 제52권2호
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• pp.103-110
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• 2019

As an anti-corrosion method in seawater, cathodic protection is widely recognized as the most effective and technically appropriate corrosion prevention methodology for marine structures against harsh corrosive environment. When applying the cathodic protection in seawater, the surface of the metal facilities the formation of compounds of $CaCO_3$ and $Mg(OH)_2$. These mixed compounds are generally called 'calcareous deposits'. This layer functions as a barrier against the corrosive environment and functions to further inhibit the corrosion process and then leading to a decrease in current demand for cathodic protection. However, calcareous deposit films are partially formed on the surface of the cathode and there are some difficulties to maintain both a corrosion resistance for a long period of time and a strong adhesion between deposits and base metal. In this study, the pulse electrodeposition process was applied to improve adhesion and corrosion resistance of the calcareous deposit films, and to solve the problem of hydrogen embrittlement at high current density. The uniform and compact calcareous deposit films were prepared by pulse electrodeposition process, and their properties were characterized using various surface analytical techniques together with electrochemical methods.

• Journal of Advanced Marine Engineering and Technology
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• 제9권2호
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• pp.126-142
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• 1985

The plane bending corrosiion fatigue test for the welded metal parats was performed in the air and in the natural sea water with and without applying cathodic protection. The specimens tested were the weld of SM41 steel plates, SM58 steel plates and of SM41 to SM58, which were all prepared by submerged arc welding. The main results obtained from the experiment are summarized as follows: (1) In case with SM41 and SM58 steel plates, lower value of impact strength, higher value of hardness and more noble electrode potential were observed in the welded metal part than in the HAZ and base metal. Also the lowest hardness zone in the HAZ was observed with SM58 which was not found with SM41. In case with weld specimen of SM41 to SM58, the impact strength and the electrode potential of the welded metal part showed again the lowest and most noble value but the hardness value was located between those of SM41 and SM58 base metal. (2) In the fatigue test, the specimens tested in the air and under the cathodic protection were both cracked in a purely mechanical mode, but the specimens tested without cathodic protection were cracked by the combination of mechanical fracture and electro-chemical corrosion. (3) The corrosion fatigue limit of the welded metal parts of the specimen was increased by the cathodic protection. As the protection potential was varied down to -800 mV vs. SCE the fatigue limit was increased to the value tested in the air, and the maximum fatigue limit appeared at the -1, 000 - -1, 200 mV vs. SCE. However, as the protection potential was further decreased below -1, 200 mV vs.SCE, the fatigue limit of weld of SM58 and of SM41-SM58 joining was decreased but the limit was almost constant in the case of weld of SM41. (4) It is suggested that when designing steel ship the corrosion fatigue limit of welded metal parts should be stressed as a designing strength of the structure of steel ship in addition to the conventional basis considering simply tensile strength of steel and safety factor.

• 한국재료학회지
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• 제8권6호
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• pp.571-576
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• 1998

본 연구에서는 용융탄산염 연료전지용 분리판으로서 오스테나이트계 스테인레스강 중, 310S를 사용하여 용융염 전해질 및 양극측 분위기에서 부식거동, 부식생성물의 형성과정 및 기구에 관한 고찰을 실시하였다. 분리판의 부식 진행과정은 부식반응 이후 안정 부식생성물이 형성되기까지 빠른 부식이 진행되는 부식생성물 형성단계와 안정 부식생성물 형성 후 보호파괴가 일어나기 까지의 부식 억제단계, 그리고 보호파괴 이후 부식이 다시 증가되는 부식 진행단계의 3단계 과정을 경유하며 진행하였다. 분리판 내 원소들의 농도분포는 부식생성물 형성영역에서는 Fe가, 부식 방어영역에서는 Cr이, 그리고 Ni은 Cr 고갈영역과 기지 안쪽에서 높게 형성되었다. 또한 양극측에서 분리판은 전해질의 이온화에 의한 부식이 주된 부식기구였으며, 최종 부식생성물은 $LiFeO_2$와 $LiCrO_2$였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.281-284
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• 1999

Bridge structure is known as one of important infrafacilities for comfortable human life. Recent long-span bridges, such as Kwang-Ahn Grand bridge, S대-Hae Grand Bridge, Young-Jong Grand Bridge, etc, have been designed and constructed near the seaside without in-depth consideration of concrete durability problems, It is in particular noted that corrosion of reinforcement steel in concrete is very important for the durability enhancement of concrete structures. The objective of this experimental study is to investigate the corrosion degree of reinforcing steels in concrete specimens which are exposed to cyclic wet and dry saltwaters, and then to develop pertinent corrosion protection system such as rational cover depth, corrosion inhibitors, cathodic system for reinforced concrete bridges exposed to marine environment.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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• pp.827-832
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• 2000

Bridge structure is known as one of important infrafacilities for comfortable human life. Recent long-span bridges, such as Kwang-Ahn Grand bridge, Seo-hae Grand Bridge, Young-Jong Grand Bridge, etc, have been designed and constructed near the seaside without in-depth consideration of concrete durability problem. It is in particular noted tat corrosion of reinforcement steel in concrete is very important for the durability enhancement of concrete structures. The objective of this experimental study is to investigate the corrosion behavior of reinforcing steels in concrete specimens which are exposed to cyclic wet and dry saltwaters, and then to develop pertinent corrosion protection system such as rational cover depth, corrosion inhibitors, cathodic system for reinforced bridges exposed to marine environment.

• 한국정밀공학회지
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• 제15권7호
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• pp.78-84
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• 1998

The problem of autobody corrosion has been addressed over the past decade by the increasing use of zinc and zinc alloy coated steels in automotive application. This paper describes the evaluation of formability, weldability and painted corrosion performance of galvalume steel sheet. This paper presents an overview of the program and some initial test results on the weldability, lifetime of the electrode tip shape of the spot welding and corrosion protection. Galvalume steel sheet improved corrosion performance and spot weldability of galvalume steel sheet was not changed under the influence of the variation of welding current. And tip shape has influenced on the lifetime of tip for galvalume steel sheet.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.1065-1068
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• 2008

해상교량은 바다에 노출되기 때문에 많은 경우 본래의 설계수명을 다하지 못하고 조기에 열화된다. 이러한 콘크리트 열화는 다공성인 콘크리트 내부에 염분이 침투함으로써 철근부식을 야기하고, 부식된 철근은 보통 $6{\sim}10$배까지 부피가 팽창하면서 콘크리트에 균열을 일으키고 결국 탈락(박리)으로 이어진다. 이와 같은 철근부식과 균열발생의 가속화는 구조물의 심각한 손상과 궁극적으로 붕괴까지 이어질 수 있다. 따라서 이러한 피해를 막기 위해서는 콘크리트 내 철근부식의 정확한 이해가 필요하며, 부식발생의 정량화에 의한 예측은 물론 적절한 방식법을 적용해야한다. 음극방식법은 비교적 최근에 개발된 철근콘크리트 구조물의 방식법 중 하나이며 요즈음도 해외 여러 나라에서 이에 대한 방식시스템 연구가 활발하다. 본 연구에서는 해상교량이나 항만부두 구조물의 상판부에 대한 예비실험 성격으로 슬랩 시험편(40cm ${\ast}$ 30cm ${\ast}$ 18cm)을 채택하였다. 시험환경은 15% 염분과 온도 $40^{\circ}C$의 가속화된 해양환경이었으며, 시험 기간 동안 주기적인 건습 반복을 실시하였다. 방식시험편은 음극방식 기술의 하나인 Zn-mesh에 의한 희생양극식을 채택하였다. 연구내용으로는 음극방식에 의한 방식성능을 관찰하였으며 신설구조물과 보수구조물에 대한 방식 효과를 비교하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제23권1호
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• pp.1-8
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• 1999