• Title/Summary/Keyword: Corrosion properties

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Effects of Ultrasonic Amplitude on Electrochemical Properties During Cavitation of Carbon Steel in 3.5% NaCl Solution

  • Jang, I.J.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.19 no.4
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    • pp.163-173
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    • 2020
  • Cavitation corrosion in many industrial plants has recently become a serious issue. Cavitation corrosion has generally been investigated using a vibratory method based on ASTM G32 standard, and the test can be divided into direct cavitation and indirect cavitation. Cavitation corrosion test uses the vibration frequency of the horn of 20 kHz with constant peak-to-peak displacement amplitude. In this work, the peak-to-peak amplitude was controlled from 15 ㎛ to 85 ㎛, and electrochemical measurements were obtained during indirect cavitation. The relationship between cavitation corrosion rate and electrochemical properties was discussed. Corrosion steps of carbon steel at the initial stage under cavitation condition in 3.5 % NaCl can be proposed. When the cavitation strength is relatively low, corrosion of the steel is more affected by the electrochemical process than by the mechanical process; but when the cavitation strength is relatively high, corrosion of the steel is affected more by the mechanical process than by the electrochemical process. This work confirmed that the critical ultrasonic amplitude of 0.42 %C carbon steel is 53.8 ㎛, and when the amplitude is less than 53.8 ㎛, the corrosion effect during the cavitation corrosion process is higher than the mechanical effect.

Effect of Manufacturing Process on Electrochemical Properties of CP-Ti and Ti-6Al-4V Alloys (CP-Ti 및 Ti-6Al-4V 합금의 전기화학적 특성에 미치는 제조공정의 영향)

  • Kim, K.T.;Cho, H.W.;Chang, H.Y.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.17 no.1
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    • pp.20-29
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    • 2018
  • Ti and its alloys show the excellent corrosion resistance to chloride environments, but they show less corrosion resistance in HCl, $H_2SO_4$, NaOH, $H_3PO_4$, and especially HF environments at high temperature and concentration. In this study, we used the commercially pure titanium and Ti-6Al-4V alloy, and evaluated the effect of the manufacturing process on the electrochemical properties. We used commercial products of rolled and forged materials, and made additive manufactured materials by DMT (Directed Metal Tooling) method. We annealed each specimen at $760^{\circ}C$ for one hour and then air cooled. We performed anodic polarization test, AC impedance measurement, and Mott-Schottky plot to evaluate the electrochemical properties. Despite of the difference of its microstructure of CP-Ti and Ti-6Al-4V alloys by the manufacturing process, the anodic polarization behavior was similar in 20% sulfuric acid. However, the addition of 0.1% hydrofluoric acid degraded the electrochemical properties. Among three kinds of the manufacturing process, the electrochemical properties of additive manufactured CP-Ti, and Ti-6Al-4V alloys were the lowest. It is noted that the test materials showed a Warburg impedance in HF acid environments.

C-Ring Stress Corrosion Test for Inconel 600 Tube and Inconel 690 welded by Nd:YAG Laser (Nd:YAG 레이저로 용접한 인코넬 600관과 인코넬 690의 C링 응력 부식시험)

  • 김재도;문주홍;정진만;김철중
    • Proceedings of the KWS Conference
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    • 1998.10a
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    • pp.288-291
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    • 1998
  • Inconel 600 alloy is used as the material of nuclear steam generator tubing because of its mechanical properties, formability, and corrosion properties. According to reports, the life time of nuclear power plants decreases because of the pitting, intergranular attack, primary water stress corrosion cracking(PWSCC), and intergranular stress corrosion cracking(IGSCC), and denting in the steam generator. The SCC test is very important because of SCC appears in various environment such as solutions, materials, and stress. The C-Rig specimen was made of the steam generator welded sleeve repairing by the pulsed Nd:YAG laser. In the corrosion invironment, corrosion solutions are Primary Water, Caustic, and Sulfate solution and corrosion time is 1624-4877hr. The permitted stress is 30-60ksi.In this C-Ring SCC test is the relationship between corrosion depth, crack and corrosion environment is evaluated. SCC was happens in Sulfate and Corrosion solution but doesn't happen in Primary Water. The corrosion time and stress is very affected by the severely environment of Sulfate or Caustic solution. The microstructure observation indicates that SCC causes interganular failure in the grain boundary of vertical direction.

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Microstructure and Corrosion Behavior of Mg-xSn (x = 1, 3, 5, 7, 9 wt.%) Alloys (Mg-xSn(x = 1, 3, 5, 7, 9 wt.%) 합금의 미세조직 및 부식특성)

  • Kang, Yong-Muk;Kim, Sang-Hyun;Jo, Su-Mi;Park, Kyung-Chul;Kim, Byeong-Ho;Park, Ik-Min;Park, Yong-Ho
    • Journal of Korea Foundry Society
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    • v.31 no.6
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    • pp.362-365
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    • 2011
  • In the present work, the corrosion properties of Mg-xSn (x = 1, 3, 5, 7 and 9 wt.%) alloys have been investigated. Potentiodynamic polarization and immersion tests were carried out in 3.5% NaCl solution of pH 7.2 at room temperature to measure the corrosion properties of Mg-xSn (x = 1, 3, 5, 7 and 9 wt.%) alloys. With increase of the Sn contents, the volume fraction of the $Mg_2Sn$ phase was increased. The corrosion rate of Mg-xSn alloys was increased up to 7 wt.%Sn and decreased above 9 wt.%Sn. Initiation of galvanic site during immersion mainly occurred at Mg/$Mg_2Sn$ interface and propagation went into ${\alpha}$-Mg. For this reason, corrosion properties of Mg-xSn (added from 1 wt.%Sn to 7 wt.%Sn alloys) alloys are decreased because the galvanic site was increased with increasing Sn addition. In Mg-9wt.%Sn alloy, however, the corrosion site were changed from Mg/$Mg_2Sn$ interface to ${\alpha}$-Mg/$M_2Sng$ interface in lamellar structure. Preferentially corrosion of ${\alpha}$-Mg/$M_2Sn$ interface in lamellar structure impeded corrosion propagation went into ${\alpha}$-Mg.

A Study on Kaolin and Titanium dioxide affecting Physical Properties of Electrocoating

  • Yang, Wonseog;Hwang, Woonsuk
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.203-208
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    • 2013
  • The electrocoating for automotive bodies is pigmented with a mixture of titanium dioxide and kaolin. In this study, the effects of titanium dioxide and kaolin contents in coating on electrodeposition process, drying, and surface properties such as surface roughness, gloss, impact resistance and corrosion resistance were investigated. Titanium dioxide and kaolin in coating do not have a decisive effect on curing reaction during drying and corrosion resistance but on gloss, surface roughness, impact resistance and electrodeposition process of coating. According to its size and shape on coating surface, pigment contents increased during drying process. However, the contents of kaolin and $TiO_2$ in coating didn't affect the corrosion resistance on zinc phosphated substrate, and the curing properties.

A Study on the Corrosion and Fatigue of Structural Materials for Rolling Stock (철도차량 구조재료의 부식 및 피로 특성 연구)

  • Jang Se-Ky;Kim Yong-Ki;Coo Byeong-Choon
    • Journal of the Korean Society for Railway
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    • v.8 no.4
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    • pp.299-307
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    • 2005
  • In general, structural integrity of rolling stock structures should last more than 25 years. During the lifetime corrosive degradation occurs. For structural design and diagnosis, quantitative relationship between corrosive degradation and variation of mechanical properties such as tensile strength and fatigue strength is needed. In this study, first of all we established the atmospheric corrosion test procedure. At regular intervals using specimens of SM490A and SS400 on the atmospheric corrosion test bed, we carried out tensile and fatigue tests. The fatigue strength decreases as the atmospheric corrosion period increases. In addition we studied the effect of post-weld heat treatment on the tensile and fatigue behaviour and performed electrochemical corrosion tests.

Study on Hygrothermal Degradation and Corrosion Protection of Epoxy Coatings Cured by Different Amine Based Curing Agents

  • Shon, Min-Young;Kwon, Huck-Sang
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.201-208
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    • 2010
  • Epoxy coatings cured by different amine based curing agents have been prepared. Atomic force microscopy (AFM) has been used to monitor the surface topology changes of epoxy coatings before and after hygrothermal cyclic test. The glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) of the epoxy coating were measured by Thermo-mechanical Analysis (TMA). The Electrochemical impedance spectroscopy (EIS) with hygrothermal cyclic test has been introduced to evaluate the corrosion protection of the epoxy coatings. In conclusion, thermal properties of epoxy coatings were in good agreement with the results of corrosion protection of epoxy coated carbon steel obtained result by EIS with hygrothermal cyclic test. The relationship between thermal properties, surface roughness changes and corrosion protection of epoxy coatings are discussed in this study.

Recent Corrosion Research Trends in Weld Joints

  • Kim, Hwan Tae;Kil, Sang Cheol;Hwang, Woon Suk
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.74-76
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    • 2007
  • The increasing interest in the corrosion properties of weld joints in the corrosive environment is placing stringent demands on the manufacturing techniques and performance requirements, and the manufacture employs the high quality and efficiency welding process to produce welds. Welding plays an important role in the fabrication of chemical plants, nuclear power plant, ship construction, and this has led to an increasing attention to the corrosion resistant weld joints. This paper covers a recent technical trends of welding technologies for corrosion resistance properties including the COMPENDEX DB analysis of welding materials, welding process, and welding fabrications.

Corrosion Inhibition Properties of Conifer Cone (Pinus resinosa) Extract in Chloride Contaminated Concrete Pore Solutions (염화물에 노출된 콘크리트 기공 내에 솔방울 추출물의 부식 방청 특성)

  • Karthick, Subbiah;Park, TaeJoon;Lee, Han Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.63-64
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    • 2021
  • The corrosion inhibition properties of conifer cone (Pinus resinosa) extract were studied in synthetic concrete pore solutions (SCPS) with and without chloride environments by electrochemical methods. The electrochemical impedance spectroscopy (EIS) revealed that the conifer cone (CC) extract showed promising inhibition behavior by diminishing the corrosion rate of steel rebar both solutions i.e. with and without chloride. The extract of conifer cone hinders the corrosion reaction between steel rebar and aggressive ions. Further, it can be verified that the up to 1000mg.L-1 of CC extract can able to reduce the corrosion rate of steel rebar in chloride contaminated concrete.

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AN EXPERIMENTAL STUDY ON PHYSICAL PROPERTIES, TARNISH AND CORROSION RESISTANCE OF BO-SUNG DENTAL GOLD ALLOY (보성치과주조용 금합금의 물리적성상과 부식 및 변색에 관한 실험적 연구)

  • Kim, In-Cheol;Park, Yun-Sam
    • The Journal of the Korean dental association
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    • v.13 no.11
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    • pp.1021-1024
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    • 1975
  • Bo-sung dental gold alloy was tested an physical properties, tarnish and corrosion restistance. The results were as follows : 1. No differences beween physical properties of Bo-Sung dental gold alloy and American Dental Association Specification No. 5. 2. Tarnish and Corrosion resistance of Bo-Sung dental gold alloy were favorable of dental uses. 3. Bo-Sung dental gold alloys showed equiaxed grain structure in microstructures.

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