• Title/Summary/Keyword: Corrosion index

Search Result 108, Processing Time 0.024 seconds

The Effects of Polyphosphate Corrosion Inhibitor and Lime Water to Reduce Red Water for Carbon Steel (탄소강의 녹물저감에 대한 인산염부식억제제와 석회수 효과 연구)

  • Park, Young-Bog;Kong, Sung-Ho
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.19 no.2
    • /
    • pp.228-237
    • /
    • 2005
  • The main purpose of this study was to investigate the red water reducing effects of phosphate based inhibitor when it was applied to water distribution system. The effects of pH, alkalinity, calcium concentration in the reduction of the red water also studied. The most finished water in Korea showed relatively high corrosiveness and was required to introduce some types of corrosion reducing methods such as addition of alkalinity. The precipitation of $CaCO_3$ by addition of $Ca(OH)_2$ formed porous film on the surface of the carbon steel pipes and was displaced easily from the surface of the pipes; on the other hand, addition of zinc phosphate (ZOP) formed reliable film on the surface and reduced iron release and color. Although the main function of ZOP was to suppress the release of Pb and Cu, it also reduced iron concentration released from water distribution pipes.

Effect of Corrosion Conditions on the Luster Change of Metallic Yarns and Fabric - Analysis of Changes in Reflection and Transmission -

  • Shin, Hye-Sun;Kim, Jong-Jun;Jeon, Dong-Won
    • Journal of Fashion Business
    • /
    • v.12 no.3
    • /
    • pp.54-61
    • /
    • 2008
  • The glitter of lame fabrics containing the metallic yarns may further be altered by $Na_2CO_3$ aqueous solution at an elevated temperature. In this study, the effect of the corrosion treatment on the yarn luster was evaluated using image analysis. The alkaline solution treatment was found to be more effective on the aluminum-based specimens than on the silver-based specimens. It was found that corrosion percentage measurement based on the transmission analysis may provide reasonable quantitative index, even if the measurement relies on an indirect method. Based on the quantitative results, the alkaline treatment condition for the specific specimen would be optimized for a desired glitter modification.

Critical Pitting Temperature of 2205 Duplex Stainless Steels Using Immersion and Electrochemical Polarization Test Methods (침지시험법 및 전기화학적 분극법에 의한 2205 이상 스테인리스강의 임계공식온도 측정 비교)

  • Shin Jae-Ho;Lee Jae-Bong
    • Journal of the Korean institute of surface engineering
    • /
    • v.39 no.1
    • /
    • pp.18-24
    • /
    • 2006
  • Although stainless steels have the excellent corrosion resistance by passive film, they are susceptible to pitting corrosion in the environment containing halogen elements such as chloride ions. The resistance to pitting corrosion can be evaluated by measuring the critical pitting temperature (CPT). CPT values can be obtained using immersion, potentiodynamic and potentiostatic polarization test methods. Results on duplex 2205 stainless steels showed that CPT values were measured as $50^{\circ}C,\;55^{\circ}C\;and\;61^{\circ}C$, respectively for immersion, potentiodynamic and potentiostatic polarization test methods, depending upon the different test methods, even though the difference between CPT values are not much.

Alloy 600 Components Inspection Prioritization Using the Normalized PWSCC Susceptibility Index (정규화된 PWSCC 민감도 지수를 이용한 Alloy 600 기기 검사 우선순위 선정)

  • Kim, Tae Ryong;Kim, Hyung Jun
    • Transactions of the Korean Society of Pressure Vessels and Piping
    • /
    • v.12 no.1
    • /
    • pp.17-22
    • /
    • 2016
  • Alloy 600 widely used in nuclear power plant is susceptible to primary water stress corrosion cracking (PWSCC). It is important to prioritize the inspection of Alloy 600 components using PWSCC susceptibility index. Plant-specific model for the susceptibility index was reviewed. The normalized PWSCC susceptibility index to a reference value is suggested and applied. The result was found to be reasonable.

Ultimate Strength Based Reliability of Corroded Ship Hulls (부식을 고려한 선각거더의 최종강도 신뢰성)

  • Paik, J.K.;Yang, S.H.;Kim, S.K.
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.33 no.2
    • /
    • pp.96-110
    • /
    • 1996
  • Aging ships can suffer structural damage due to corrosion, fatigue crack etc., and possibility of catastrophic failure of seriously damaged ships is very high. To reduce the risk of loss of ships due to hull collapse, it is essential to evaluate ultimate hull strength of aging ships taking into account various uncertainties associated with structural damages. In this paper, ultimate strength-based reliability analysis of ship structures considering wear of structural members due to corrosion is described. A corrosion rate estimate model for structural members is introduced. An ultimate limit state function of a ship hull is formulated taking into account corrosion effects. The model is applied to an existing oil tanker, and reliability index associated with hull collapse is calculated by using the second-order reliability method (SORM). Discussions on structure safety of corroded ships are made.

  • PDF

Application of fractals to study the corroded reinforced concrete beam

  • Fan, Y.F.;Zhou, J.;Hu, Z.Q.
    • Structural Engineering and Mechanics
    • /
    • v.20 no.3
    • /
    • pp.265-277
    • /
    • 2005
  • This paper is focused on fractal analysis of the surface cracking, a new tool for safety evaluation of corroded reinforced concrete (RC) beams. Comprehensive experimental investigations, including flexural tests, coupon tests on strength evaluation of corroded concrete and rusty rebar, and pullout tests to determine bond strength between concrete and rebar were carried out on nine Corroded Reinforced Concrete Beams (CRCB) exposed to an aggressive environment for more than 10 years. In combination with test results from a previous study on CRCBs fabricated in the laboratory from accelerated methods, it is found that, for both types of beams, the surface cracking distributions are fractal in character at loading and failure stages. Fractal dimension is calculated for all specimens at different corrosion states based on fractal analysis method. Relationships between the fractal dimension and mechanical properties of corroded concrete, rebar corrosion ratio, and ductility of CRCBs are discussed in detail. It is concluded that the fractal dimension can act as a damage index and can be efficiently used to describe the corrosion state of CRCBs.

Corrosion-Fatigue Reliability-Based Life Cycle Cost Analysis of High-Speed Railway Steel Bridges (고속철도 강교량의 부식.피로신뢰성 기반 생애주기비용 분석)

  • Jeon, Hong-Min;Sun, Jong-Wan;Cho, Hyo-Nam
    • Proceedings of the KSR Conference
    • /
    • 2007.11a
    • /
    • pp.1132-1140
    • /
    • 2007
  • As it recently appears that Life Cycle Cost Analysis may be considered as new methodology for economic valuation of infrastructure many researches have been made to assess LCC(Life Cycle Cost) of each facility based on a reasonable methods. In general, LCC is composed of construction cost and expected maintenance repair cost. And especially, maintenance repair cost must be estimated to enhance the reliability through systematic and reasonable methods. However in Korea, because high speed railway steel bridges are recently constructed no direct statistical data are available for the account of the maintenance cost and then their maintenance characteristics are not linear yet. Therefore, the approach proposed in the paper utilizes a theoretical determination and degradation of the corrosion and fatigue of the bridges based on Rahgozar et al.(2006)'s model on fatigue notch factor considering into the corrosion to incorporate the corrosion effect into the fatigue strength reduction model. And then, the corresponding probability of failure is calculated in terms of the reliability index using S-N curve to formulate the fatigue limit state. Therefore, this paper proposes the minimum Life Cycle Cost through optimum maintenance plan analysis of high-speed railway steel bridges under construction. Finally, this paper reviews the proposed model in oder to confirm the applicability and feasibility by appling it to high speed railway steel bridges under construction

  • PDF

Mechanistic Studies on the Hydrogen Evolution and Permeation of Ultra-Strong Automotive Steel in Neutral Chloride Environments (중성의 염화물 환경 내 자동차용 초고강도강의 부식반응에 기인한 수소원자의 발생 및 투과 메커니즘)

  • Hwang, Eun Hye;Ryu, Seung Min;Kim, Sung Jin
    • Korean Journal of Materials Research
    • /
    • v.28 no.7
    • /
    • pp.428-434
    • /
    • 2018
  • Hydrogen evolution on a steel surface and subsequent hydrogen diffusion into the steel matrix are evaluated using an electrochemical permeation test with no applied cathodic current on the hydrogen charging side. In particular, cyclic operation in the permeation test is also conducted to clarify the corrosion-induced hydrogen evolution behavior. In contrast to the conventional perception that the cathodic reduction reaction on the steel in neutral aqueous environments is an oxygen reduction reaction, this study demonstrates that atomic hydrogen may be generated on the steel surface by the corrosion reaction, even in a neutral environment. Although a much lower permeation current density and significant slower diffusion kinetics of hydrogen are observed compared to the results measured in acidic environments, they contribute to the increase in the embrittlement index. This study suggests that the research on hydrogen embrittlement in ultra-strong steels should be approached from the viewpoint of corrosion reactions on the steel surface and subsequent hydrogen evolution/diffusion behavior.

Electrochemical and Cavitation-Erosion Characteristics of Duplex Stainless Steels in Seawater Environment (해수 환경에서 듀플렉스 스테인리스강의 전기화학적 거동 및 캐비테이션 특성)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
    • /
    • v.20 no.6
    • /
    • pp.466-474
    • /
    • 2021
  • A wet type scrubber for merchant vessel uses super austenitic stainless steels with pitting resistance equivalent number (PREN) of 40 or higher for operation in a harsh corrosive environment. However, it is expensive due to a high nickel content. Thus, electrochemical behavior and cavitation erosion characteristics of UNS S32750 as an alternative material were investigated. Microstructure analysis revealed fractions of ferritic and austenitic phases of 48% and 52%, respectively, confirming the existence of ferritic matrix and austenitic island. Potentiodynamic polarization test revealed damage at the interface of the two phases because of galvanic corrosion due to different chemical compositions of ferritic and austenitic phases. After a cavitation test, a compressive residual stress was formed on the material surface due to impact pressure of cavity. Surface hardness was improved by water cavitation peening effect. Hardness value was the highest at 30 ㎛ amplitude. Scanning electron microscopy revealed wave patterns due to plastic deformation caused by impact pressure of the cavity. The depth of surface damage increased with amplitude. Cavitation test revealed larger damage caused by erosion in the ferritic phase due to brittle fracture derived from different strain rate sensitivity index of FCC and BCC structures.

A vibration based acoustic wave propagation technique for assessment of crack and corrosion induced damage in concrete structures

  • Kundu, Rahul Dev;Sasmal, Saptarshi
    • Structural Engineering and Mechanics
    • /
    • v.78 no.5
    • /
    • pp.599-610
    • /
    • 2021
  • Early detection of small concrete crack or reinforcement corrosion is necessary for Structural Health Monitoring (SHM). Global vibration based methods are advantageous over local methods because of simple equipment installation and cost efficiency. Among vibration based techniques, FRF based methods are preferred over modal based methods. In this study, a new coupled method using frequency response function (FRF) and proper orthogonal modes (POM) is proposed by using the dynamic characteristic of a damaged beam. For the numerical simulation, wave finite element (WFE), coupled with traditional finite element (FE) method is used for effectively incorporating the damage related information and faster computation. As reported in literature, hybrid combination of wave function based wave finite element method and shape function based finite element method can addresses the mid frequency modelling difficulty as it utilises the advantages of both the methods. It also reduces the dynamic matrix dimension. The algorithms are implemented on a three-dimensional reinforced concrete beam. Damage is modelled and studied for two scenarios, i.e., crack in concrete and rebar corrosion. Single and multiple damage locations with different damage length are also considered. The proposed methodology is found to be very sensitive to both single- and multiple- damage while being computationally efficient at the same time. It is observed that the detection of damage due to corrosion is more challenging than that of concrete crack. The similarity index obtained from the damage parameters shows that it can be a very effective indicator for appropriately indicating initiation of damage in concrete structure in the form of spread corrosion or invisible crack.