• Title/Summary/Keyword: Corrosion in chloride environment

Search Result 204, Processing Time 0.025 seconds

Enhanced Classical Tafel Diagram Model for Corrosion of Steel in Chloride Contaminated Concrete and the Experimental Non-Linear Effect of Temperature

  • Hussain, Raja Rizwan
    • International Journal of Concrete Structures and Materials
    • /
    • v.4 no.2
    • /
    • pp.71-75
    • /
    • 2010
  • The chloride ion attack on the passive iron oxide layer of reinforcement steel embedded in concrete under variable temperature environment is influenced by several parameters and some of them still need to be further investigated in more detail. Different school of thoughts exist between past researchers and the data is limited in the high temperature and high chloride concentration range which is necessary with regards to setting boundary conditions for enhancement of tafel diagram model presented in this research. The objective of this paper is to investigate the detrimental coupled effects of chloride and temperature on corrosion of reinforced concrete structures in the high range by incorporating classical Tafel diagram chloride induced corrosion model and laboratory controlled experimental non-linear effect of temperature on corrosion of rebar embedded in concrete.

Hybrid Corrosion Inhibitor-Based Zwitterions and Phosphate in Reinforced Concrete: Determining Chloride Threshold and Service Life (철근 콘크리트의 Zwitterion 및 인산염 기반 하이브리드 부식 억제제: 염화물 임계값 및 사용 수명 결정)

  • Tran, Duc Thanh;Jeong, Min-Goo;Lee, Han-Seung;Yang, Hyun-Min;Singh, Jitendra Kumar
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2023.05a
    • /
    • pp.33-34
    • /
    • 2023
  • Corrosion of reinforcement steel is a major cause of deterioration in reinforced concrete (RC) structures. In order to protect these structures from corrosion, corrosion inhibitors are added to the concrete mix. In recent years, zwitterionic compounds have shown promising results as corrosion inhibitors in concrete due to their ability to form a protective layer on the surface of the reinforcement steel. The experimental study involves preparing concrete samples with different concentrations of adding the hybrid corrosion inhibitor at a high concentration of chloride ions. This study aims to determine the chloride threshold value and service life of hybrid corrosion inhibitors in reinforced concrete based on zwitterions. The samples are subjected to accelerated corrosion tests in a chloride environment to determine the threshold value and service life of the corrosion inhibitor. The effect of hybrid inhibitor on mechanical properties is guaranteed in allowable range. The chloride threshold concentration and service life of hybrid inhibitor containing samples perform greater than those of plain RC.

  • PDF

Numerical analysis of concrete degradation due to chloride-induced steel corrosion

  • Ayinde, Olawale O.;Zuo, Xiao-Bao;Yin, Guang-Ji
    • Advances in concrete construction
    • /
    • v.7 no.4
    • /
    • pp.203-210
    • /
    • 2019
  • Concrete structures in marine environment are susceptible to chloride attack, where chloride diffusion results in the corrosion of steel bar and further lead to the cracking of concrete cover. This process causes structural deterioration and affects the response of concrete structures to different forms of loading. This paper presents the use of ABAQUS Finite Element Software in simulating the processes involved in concrete's structural degradation from chloride diffusion to steel corrosion and concrete cover cracking. Fick's law was used for the chloride diffusion, while the mass loss from steel corrosion was obtained using Faraday's law. Pressure generated by steel corrosion product at the concrete-steel interface was modeled by applying uniform radial displacements, while concrete smeared cracking alongside the Extended Finite Element Method (XFEM) was used for concrete cover cracking simulation. Results show that, chloride concentration decreases with penetration depth, but increases with exposure time at the concrete-steel interface. Cracks initiate and propagate in the concrete cover as pressure caused by the steel corrosion product increases. Furthermore, the crack width increases with the exposure time on the surface of the concrete.

An experimental study on Influence of Permeability on corrosion of reinforced Concrete (철근콘크리트의 부식에 영향을 미치는 물질 투과성능에 관한 실험적 연구)

  • 김용로;김영덕;조봉석;장종호;권영진;김무한
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2003.11a
    • /
    • pp.62-65
    • /
    • 2003
  • In this study, to confirm corrosion of reinforced concrete affected by carbonation, chloride ion diffusion, absorption ratio, air permeability, measured carbonation velocity coefficient, chloride ion diffusion coefficient, absorption coefficient, air permeability coefficient. Corrosion velocity under environment of complex deterioration. And than compared corrosion velocity with these coefficients. As the results of this study, the correlation coefficient between chloride ion diffusion coefficients and absorption coefficient was revealed that it is very high. As well, an increase in carbonation, chloride ion diffusion also increases corrosion velocity. It showed that corrosion velocity was affected by the carbonation, chloride ion diffusion, absorption ratio, air permeability. Generally, data on the development of these coefficient made with none, organic B, organic A, inorganic B, and inorganic A is shown. It showed that coating of surface prevent steel bar from deteriorating.

  • PDF

The study on Response of the Sensor for monitoring of Chloride Penetration in Concrete (콘크리트내 비래 염소이온 침투 모니터링을 위한 부식센서의 응답성능 평가에 관한 연구)

  • Shin, Sang-Heon;Lee, Hyun-Seok;Ryu, Hwa-Sung;Kim, Bo-Seok;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2014.05a
    • /
    • pp.172-173
    • /
    • 2014
  • The study is used to verify the applicability of the sensor to monitor penetration of chloride into the concrete, like real coastal environment. After manufacturing the specimen adapt corrosion sensor for chloride penetration monitoring, chloride spray experiment was conducted. And then, It was checked the possibility of monitoring of the penetrated chloride by measuring the resistance of the corrosion sensor that was embedded in each depth of the concrete. Experimental results, it is confirmed that the corrosion resistance of the sensor was increased depending on the concentration of chloride. Therefore, it is estimated that the sensor is available for monitoring of chloride penetration.

  • PDF

Evaluate the Concrete mix by Type Accelerated Corrosion Test and Chloride Penetration Analysis with Artificial Seawater Cyclic Wet and Dry Condition (인공해수 건습반복조건에 따른 콘크리트배합별 부식촉진시험법과 염화물 침투해석평가)

  • Park, Sang-Soon;Kim, Min-Wook
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.1 no.3
    • /
    • pp.211-218
    • /
    • 2013
  • Cyclic wet and dry conditions in the marine environment structures corrosion is known to be the fastest rising. For that reason, accelerated corrosion test methods for the reproduction of tidal environment has been actively conducted. However, many studies have estimated threshold value for steel corrosion or concentrated in chloride penetration analysis. In this study, cyclic wet and dry conditions to reproduce the structure of the environment in accelerated corrosion and chloride penetration test analysis was performed. Corrosion was determined by the result of reinforcement corrosion monitoring based on galvanic potential measurement and half-cell potential method. Accelerated corrosion test results for each formulation was different corrosion periods, the order OPC> FA> BS> High-strength concrete. FEM durability interpretation program DuCOM was conducted under the same conditions as in accelerated corrosion test. The experimental RCPT tests demonstrated the validity of the result.

Experimental Study on Corrosion Rate in Concrete

  • Jang, BongSeok;Oh, ByungHwan
    • Corrosion Science and Technology
    • /
    • v.3 no.1
    • /
    • pp.34-38
    • /
    • 2004
  • The corrosion of reinforcement is a very important factor on the serviceability and safety of reinforced concrete structures. The corrosion rate influences directly the cover failure time of reinforced concrete structures because the corrosion rate is used to estimate the amount of corrosion and thus expansive pressure due to corrosion. In this study, several series of experiments are performed considering the chloride concentration in artificial pore solution. The potentials are measured according to the applied current density and then corrosion current densities are obtained from the Tafel plot for various chloride concentrations. The measured corrosion rates show good correlation with those of other researchers.

Air-borne Chloride Content in Domestic Marine Environment (국내 해안의 비래염분량 조사결과)

  • 정해문;안태송;류종현;안성순
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2003.11a
    • /
    • pp.66-69
    • /
    • 2003
  • Chloride ingress into concrete followed by reinforcement corrosion and deterioration of concrete structures is a major problem for many structures under chloride attacks. It is necessary to investigate the environmental conditions of concrete structures exposed to chloride attacks. In this study, the air-borne chloride contents in domestic marine environment were investigated.

  • PDF

A Study on Corrosion Failure of a Weathering Steel Weldment with Various Applied Potentials in Acid-chloride Solution (산-염소이온 분위기의 인자전위에 따른 내후성강 용접부의 부식파괴에 관한 연구)

  • 최윤석;김정구;김종집;이병훈
    • Journal of Welding and Joining
    • /
    • v.18 no.3
    • /
    • pp.97-105
    • /
    • 2000
  • The stress corrosion cracking(SCC) and hydrogen embrittlement cracking(HEC) characteristics of a weathering steel weldment were investigated in aerated acid-chloride solution. The electrochemical properties of weldment were investigated by polarization test and galvanic corrosion test. Weathering steel did not show passive behavior in the acid-chloride solution. Galvanic corrosion between the weld metal and the base metal was not observed because the base metal was anodic to the weld metal. The slow-strain-rate tests(SSRT0 were conducted at a constant strain rate o 7.87×{TEX}$10^{-7}${/TEX}/s at corrosion potential, and at potentiostatically controlled anodic and cathodic potentials. The weldment of weathering steel was susceptible to both anodic dissolution SCC and hydrogen evolution HEC.

  • PDF

Chloride Diffusion Coefficient and Steel Corrosion Properties of Concrete containing Hydrotalcite-based Corrosion Inhibitor (하이드로탈사이트계 방청제를 혼입한 콘크리트의 염화물확산계수 및 철근부식특성)

  • Kang, In-Young;Kim, Gyu-Yong;Yoon, Min-Ho;Hwang, Eui-Chul;Seo, Won-Woo;Son, Min-Jae
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2017.11a
    • /
    • pp.90-91
    • /
    • 2017
  • Concrete can be used semi-permanently unless the steel is corroded. However, the concrete exposed to the marine environment is exposed to sea breeze, so chloride ions penetrate into the concrete and the steel is corroded accordingly. In order to solve these problems, there is a method of increasing the covering depth of the concrete and an application of the epoxy paint to the steel. In this study, the hydrotalcite type corrosion inhibitor was mixed with the concrete and the compressive strength, chloride diffusion coefficient and the corrosion properties of the steel were examined.

  • PDF