• Title/Summary/Keyword: Corrosion density

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Fabrication of Nanostructured Ti from Ti and TiH2 by Rapid Sintering and Its Mechanical Properties (급속소결에 의한 Ti와 TiH2로부터 나노구조의 Ti 제조 및 기계적 특성)

  • Kim, Na-Ri;Cho, Sung-Wook;Kim, Won-Baek;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.34-38
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    • 2012
  • Titanium has good deformability, high hardness, high biocompatibility, excellent corrosion resistance and low density. Due to these attractive properties, it has been used in many industrial applications. Dense nanostructured Ti was sintered from mechanically activated Ti and $TiH_2$ powders by high frequency induction heating under pressure of 80 MPa. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition of grain growth. $TiH_2$ powder was decomposed to Ti during sintering. The hardness of Ti increased and the average grain size of Ti decreased with increasing milling time. The average grain sizes of Ti samples sintered from Ti and $TiH_2$ powder milled for 5 hrs were about 26 nm, 44 nm, respectively. The hardness of Ti sintered from Ti and $TiH_2$ powder milled for 5 h was $504kg/mm^2$ and $567kg/mm^2$, respectively.

Investigation on Size Distribution of Tungsten-based Alloy Particles with Solvent Viscosity During Ultrasonic Ball Milling Process (초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동)

  • Ryu, KeunHyuk;So, HyeongSub;Yun, JiSeok;Kim, InHo;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.201-207
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    • 2019
  • Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

A Study on the Efficiency Estimation of Halogen free Fire Resistance Cable (저독성 내화전선 케이블의 성능평가에 관한 연구)

  • 윤헌주;홍진웅;유동일;윤재선;곽동일
    • Fire Science and Engineering
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    • v.16 no.1
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    • pp.18-23
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    • 2002
  • Efficiency estimation of toxicity free resistance cable experiments were conducts to understand toxicity free fire ersistance polyolefin insulation material and smoke density characteristic and combustion gas corrosion analysis. A main cause of fire-growth and generating toxic gas when it burns, should be dealt with great care in life safety design. Similar patterned fire incidents such as, Inchon Live-Hof Pub Restaurant as, Sea-land Children Resort have proven that serious loss of lives were caused by hazardous gas generated fire resistance cable materials. In this paper, Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of 2.5$\pm40.04〔w/$\textrm{cm}^2$〕for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. Also, the fire gases was occurred carbon monoxide and decomposition than in polyolefin due to incomplete combustion of PVC which has high content of carbon in chemical compound.

A Study on Quantitative Thickness Evaluation Using Film Density Variation in Film Radiography (Film Radiography에서 농도차를 이용한 정량적 두께 평가에 관한 연구)

  • Lee, Sung-Sik;Lee, Jeong-Ki;Kim, Young-H.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.5
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    • pp.356-362
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    • 1999
  • Based on the assumption that film density increases exponentially with exposure in the industrial radiographic film. an equation representing the characteristic curves of industrial radiographic films and a new density-thickness relation are suggested. The accuracy and reliability of the suggested relation has been tested using radiographs of a carbon steel step wedge with known thickness variation by polychromatic X-ray and ${\gamma}$-ray ($Ir^{192}$). The experimental results were well agreed to the proposed relation in the range of film densities from 1.0 to 3.5 and it was more accurate than the conventional relation. It is also found that ${\gamma}$-ray is more effective in this purpose than polychromatic X-ray, which results in variation of effective linear absorption coefficient due to beam hardening effect as thickness increases. Therefore using the equation and experimentally determined parameters the quantitative evaluation of thickness variation is possible and it can be used to evaluate the depth of local corrosion of pressure vessels in plants.

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Components in Zn Air Secondary Batteries (Zinc Air 이차전지의 구성요소)

  • Lee, Junghye;Kim, Ketack
    • Journal of the Korean Electrochemical Society
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    • v.16 no.1
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    • pp.9-18
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    • 2013
  • Components of zinc-air battery and their problems are explained. Energy density of zinc air battery is superior to other commercial ones including Li-ion batteries. Cycle life of the zinc air batteries is poor because of irreversible redox reactions on both electrodes. In order to improve the performance of the zinc air battery, catalysts, passivation, and the new structure of electrodes should be developed to optimize several reactions in an electrode. Multidisciplinary efforts, such as mechanics, corrosion science, composite materials are necessary from the beginning of the research to obtain a meaningful product.

A Study on the Development of Cu-based Sintered Friction Materials (동계 소결마찰재 개발에 관한 연구)

  • Lee, Jong-Hyung;Choi, Byung-Ho;Kim, Jeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.1
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    • pp.83-92
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    • 1997
  • In a study on the development of Cu-based sintered friction materials, the specimens pressed with various compacting pressures $(3-6 ton/cm^2/)$ have been evaluated to find the optimum condition of compacting pressure. As compacting pressure increased up to $(5 ton/cm^2/)$, mechanical properties such as density, hardness, bending strength, wear and coefficient of friction, etc. improved remarkably, but up to 6 ton/cm$^{2}$, decreased slightly because of traps of gases and water vapors in specimen. Disk assembly composed of 12 pieces of Cu-based friction materials has been compared with one of asbestos-and nonasbestos-based friction materials. In dynamic and driving tests to find burst spin strength, corrosion area rate and friction properties, etc., Cu-based sintered friction materials showed better properties than the others, especially in severe conditions because oxides such as $Cu_2O; and; SnO_2$ in the friction surface of friction materials were formed.

Electrochemical Properties of Metal Aluminum and Its Application (금속알루미늄의 전기화학적 성질과 응용)

  • Tak, Yongsug;Kang, Jinwook;Choi, Jinsub
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.335-342
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    • 2006
  • Metal aluminum, of which has a low standard reduction potential, participates in the electrochemical oxidation reaction and results in the structural change and accompanying property variation of aluminum and its oxide film. Aluminum was electrochemically etched in acid solution and the surface area was magnified by the formation of high density etch pits. Etched aluminum was covered with a compact and dense dielectric oxide film by anodization and applied to the capacitor electrode. Anodization of aluminum in acid solution at low temperature makes a nanoporous aluminum oxide layer which can be used for the fabrication template of nanostructural materials. Electrochemical characteristics of aluminum turn the metal aluminum into functional materials and it will bring the diverse applications of metal aluminum.

Welding Characteristics of Lap-Joint Hastelloy C-276 Sheet Metal Using Nd:YAG Laser (Nd:YAG 레이저를 이용한 하스텔로이 박판의 겹치기 이음 용접 특성)

  • Kim, Chan Kyu;Jung, Yoon Gyo;Cho, Young Tae
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.8
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    • pp.681-685
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    • 2015
  • Hastelloy C-276 composed of Cr, Mo, and Ni is a versatile, corrosion-resistant alloy with numerous industrial applications including its use in nuclear reactors, general chemical plants, and as a superconducting base material. Of especial significance, it can be used as a thin-sheet type whereby lap-joint welding is occasionally necessary. The main welding problems for thin-sheet metals are deformation and burn-through from an excessive heat input. Laser welding can minimize these problems because it has a high energy density and low heat effect on the base material. In this study, the laser-welding characteristics of lap-joint Hastelloy C-276 sheet metal were determined. The criteria of the laser-welding variables were chosen using a heat-conduction analysis, and the optimal welding parameters were selected by experimenting with an Nd:YAG laser.

Effects of Solidification Modes on the Pit Initiation and Propagation in Austenitic Stainless Steel Weld Metals (오스테나이트계 스테인리스강 용착금속의 응고모드가 공식 생성 및 성장에 미치는 영향 x Effects of Solidification Modes on the Pit Initiation and Propagation in Austenitic Stainless Steel Weld Metals)

  • 최한신;김규영;이창희
    • Journal of Welding and Joining
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    • v.16 no.6
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    • pp.59-68
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    • 1998
  • In this study, effects of solidification modes (primary $\delta$-ferrite, primary ${\gamma}$-austenite) on the pit initiation and propagation in the 304L and 316L austenitic stainless steel weld metals were investigated. The solidification mode of weld metal was controlled by the addition of nitrogen to Ar shielding gas. Through the electrochemical experiments (potentiodynamic anodic polarization and potentiostatic time-current transient test) and metallographic examination (microstructure and elemental distribution), the following results were obtained. The more the volume content of nitrogen in the shielding gas were, the lower critical current density for passivity was observed. In comparison with weldments solidified through the primary $\delta$-ferrite solidification mode and the primary ${\gamma}$-solidification mode, the former showed higher critical pitting potential and a longer incubation time for stable pit initiation than the latter. However, in the pit propagation stage the former exhibited a faster dissolution rate than the latter. These results were believed to ee related to the distribution of alloying elements such as Cr, Mo, Ni and S.

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Prediction of Long-Term behavior of polyethylene pipe buried underground (지중매설 폴리에틸렌 관의 장기거동 예측)

  • Lee, Jae-Ho;Kim, Bin;Yoon, Soo-Hyun;Kim, Eung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.7-12
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    • 2017
  • Most of existing buried pipes are composed of reinforced concrete. Reinforced concrete pipes have many problems such as aging, corrosion, leaking, etc. The polyethylene (PE) pipes have advantages to solve these problems. The plastic pipes buried underground are classified into a flexible pipe. National standard that has limited the long-term vertical deformation of the pipe to 5% for flexible pipes including PE pipe. This study presents a prediction for the long-term behavior of the polyethylene pipe based on ASTM D 5365. This prediction method is presented to estimate by using the statistical method from the initial deflection measurement data. We predict the behavior of long-term performance on the double-wall pipe and multi-wall pipe. As a result, it was found that the PE pipe will be sound enough more than 50 years if the compaction of soil around the pipe is more than 95% of the standard soil compaction density.