• Title/Summary/Keyword: Corrosion current

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The Effect of Alloying Elements and Heat Treatment on the Uniform Corrosion of 440A Martensitic Stainless Steel(I) (440A 강의 균일부식에 미치는 합금원소와 열처리의 영향(I))

  • Kim, Y.C.;Kang, C.Y.;Jung, B.H.
    • Journal of Power System Engineering
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    • v.15 no.2
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    • pp.42-48
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    • 2011
  • 440A martensitic stainless steels which were modified with reduced carbon content(~0.5%) and addition of small amount of nickel, vanadium, tungsten and molybdenum were manufactured. Effects of alloying elements and tempering temperatures on the uniform corrosion in the solution of lN H2S04 were investigated through the electrochemical polarization test. When tempering temperature is constant, corrosion current density in active-passive transition point, Icorr, decreased a little with an increase of austenitizing temperature. In addition to this, when austenitizing temperature is constant, longer holding time showed a little lower Icorr and Ipass, passive current density. And when austenitized at $1050^{\circ}C$ and tempered in a range of $350{\sim}750^{\circ}C$, best anti-corrosion properties were obtained at $350^{\circ}C$ tempering temperature while worst at $450^{\circ}C$ or $550^{\circ}C$. The specimens tempered at below $450^{\circ}C$ and above $550^{\circ}C$, similar and good anti-corrosion characteristics were obtained regardless of alloying elements added, showing anti-corrosion characteristics are influenced more by tempering temperature than by alloying elements.

Electrochemical Study on the Effect of Post-Weld Heat Treatment Affecting to Corrosion Resistance Property of the Weldment of SCM440 Steel (SCM440강 용접부의 내식성에 미치는 용접후 열처리효과에 관한 전기화학적 연구)

  • 김성종;김진경;김종호;김기준;김영식;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.6
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    • pp.78-88
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    • 2000
  • The effect of post-weld heat treatment(PWHT) of SCM440 steel was investigated with parameters such as micro-Vickers hardness, corrosion potential, polarization behaviors, galvanic current, Al anode generating current and Al anode weight loss, etc. Each hardness of three parts(HAZ, BM, WM) by PWHT is lower than each of as-welded parts. However, hardness of WM area was the highest among those three parts in case of both PWHT and as-welded. Corrosion potential of WM part was the highest among those three parts and WM area was also acted as cathode without regard to PWHT. The magnitude of corrosion potential difference among three parts by PWHT was larger than that of three parts of as-welded, and corrosion current by galvanic cell of these three parts by PWHT was also larger compared to as-welded. Therefore, it is suggested that corrosion resistance property of SCM440 steel is decreased by PWHT than as-welded. However, both Al anode generating current and anode weight loss were also increased by PWHT compared to as-welded when SCM400 steel is cathodically protected by Al anode.

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Changes in Corrosion Progress and Ultimate load of Tendon Under 20% and 40% of Ultimate Loading Conditions (파괴하중의 20% 및 40% 인장조건에서 텐던 부식 진행 및 파괴하중 변화)

  • Ryu, Hwa-Sung;An, Gi Hong;Hwang, Chul-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.47-52
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    • 2017
  • PSC (Prestressed Concrete) structures have been used widely for its engineering advantage with using total concrete area as effective compressive section. However tendon inside is exposed to such a high tensile stress that and more attentions should be paid for corrosion control. This work is for changing corrosion current and ultimate strength in tendon with increasing prestressing force in a constant corrosive condition. With increasing prestressing force, corrosion current, corrosion amount, and ultimate load are changed linearly. When prestressing force increases from 20.0 % to 40.0 %, corrosion current increases to 124.4 % and 168.0 % and ultimate load decreases to 87.8 % and 78.4 %, respectively. With inducing constant electrical potential, increasing corrosion current and reduction of strength are evaluated to be linearly related with increasing prestressing load.

A Study on the Corrosion of Al-Alloy Propeller Used for a Coasting Vessel (연안 선박용 Al합금 프로펠러의 부식에 관한 연구)

  • LIM, Uh-Joh;PARK, Hee-Ok;YUN, Byoung-Du
    • Journal of Fisheries and Marine Sciences Education
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    • v.15 no.2
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    • pp.176-183
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    • 2003
  • Recently, with the tendency of lightening, high-strength and high-speed in the marine industries such as marine structures, ships and propellers, it is rapidly enlarged the use of the aluminium alloy. Therefore, there occurs much interest in the study on corrosion characteristics of aluminium alloy. This paper was studied on the corrosion characteristics of Al-Mg alloy propeller used for a coasting vessel. Under the various pH of marine environment, the corrosion test of Al-Mg alloy was carried out. And thus polarization resistance, corrosion potential, and current density behavior of Al-Mg alloy and galvanic corrosion behavior of Al-brass and Al-Mg alloy coupled Al 5086 and SS 400 for hull were investigated. The main results are as following: 1. The corrosion potential of Al-brass propeller is more nobel than materials for hull, but that of Al-Mg alloy propeller is low or similar to materials for hull. Therefore, the galvanic corrosion of hull due to Al-Mg propeller don't occur. 2. The polarization resistance of Al-Mg alloy in sea water of pH 4 is highest, and corrosion current density of Al-Mg propeller is the most controlled. 3. As pH value decreases, potential showed Evans polarization diagram approaches cathodic potential. The corrosion current density of Al-Mg alloy is controlled to anodic reaction rate, therefore, the corrosion reaction of Al-Mg alloy is anodic control.

The Performance of Cathodic Protection with ICCP

  • Oh, Jin-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.8
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    • pp.1286-1290
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    • 2004
  • This paper describes the anti-corrosion system on underwater structures of ships. Metals and alloys have several positions in the series such as immunity, corrosion and passivity. The iron potential has to change from the corrosion position to the anodic protection or cathodic protection for preventing corrosion by providing corrosion protection system such as ICCP(Impressed Current Cathodic Protection). The purpose of ICCP system is to eliminate the rusting or corrosion, which occurs on metal immersed in water. The system includes a power supply unit, which consists of a transformer, a converter. a controller, etc. This paper presents the protection performance of ICCP under dynamic condition such as velocity. The variation of potential and current density with time and environment factors are also described Finally, the experimental results will be explained and analysed.

Study on the Crevice Corrosion Behavior of SS 400 in Marine Environment (해양환경중에서 SS400강재의 간극부식거동에 관한 연구)

  • 임우조;정기철;안석환;윤병두
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2000.11a
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    • pp.1-6
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    • 2000
  • This paper was studied on the crevice corrosion behavior of SS 400 in marine environment. In 0%, 2%, 3.5%, 5% NaCl solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, the current density was low drained. 3) The weight loss rate of SS400 was increased as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of SS400 was decreased.

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Enhanced Corrosion Resistance of WC-Co with an Ion Beam Mixed Silicon Carbide Coating

  • Yeo, Sun-Mok;Park, Jae-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.193-193
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    • 2011
  • Strong adhesion of a silicon carbide (SiC) coating to a WC-Co substrate was achieved through an ion beam mixing technique and the corrosion resistance of the SiC coated WC-Co was investigated by means of a potentiodynamic electrochemical test. In a 1 M NaOH solution, the corrosion current density of SiC-coated WC-Co after heat treatment at 500$^{\circ}C$ was about 50 times lower than that for the as-received WC-Co. In addition, the corrosion resistance systematically increases with increasing the SiC coating thickness. On the other hand, for a 0.5 M H2SO4 solution, the corrosion current density for SiC-coated WC-Co was about 3 times lower than that for the as-received WC-Co. We discuss the physical reasons for the changes in the corrosion current density with the different electrolytes.

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A Preliminary Study on the Electric Corrosion at Electrified Railroad (지하전철구간 전기부식 특성에 관한 기초연구)

  • Lee Cheul-Kyu;Jung Woo-sung;Lee Duck-Hee
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.151-156
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    • 2004
  • Although insulation equipment is installed, it is inevitable to avoid the stray current because rail is the return way of the direct current that is power of electric motor car. In this paper, by the investigation of the present state of underground facilities, and looking into the reason of electric corrosion, and analysis of corrosion accident cases of inside and outside of the country, fundamental data, to reduce of stray current and to prevent electric corrosion, were accumulated to enhance the safety of railway operation service.

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Experimental Study on Corrosion Rate in Concrete

  • Jang, BongSeok;Oh, ByungHwan
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.34-38
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    • 2004
  • The corrosion of reinforcement is a very important factor on the serviceability and safety of reinforced concrete structures. The corrosion rate influences directly the cover failure time of reinforced concrete structures because the corrosion rate is used to estimate the amount of corrosion and thus expansive pressure due to corrosion. In this study, several series of experiments are performed considering the chloride concentration in artificial pore solution. The potentials are measured according to the applied current density and then corrosion current densities are obtained from the Tafel plot for various chloride concentrations. The measured corrosion rates show good correlation with those of other researchers.

Influence of Graphite Epoxy Composite Material on the Electrochemical Galvanic Corrosion of Metals (금속재료의 전기화학적 갈바닉 부식에 미치는 GECM의 영향)

  • Yoo, Y.R.;Son, Y.I.;Shim, G.T.;Kwon, Y.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.27-39
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    • 2009
  • Non metallic composite materials, for example, GECM(graphite epoxy composite material) show high specific strength because of low density. These kinds of non metallic composite materials improved the structural effectiveness and operation economics. However, if these materials contacted several metals, corrosion can be arisen since non metallic composite materials have electrical conductivity. This paper dealt with galvanic corrosion between graphite epoxy composite material and several metals. Base on the electrochemical galvanic corrosion test between GECM and metals, corrosion current of carbon steel and aluminium increased with time but corrosion current of stainless steels and titanium decreased and galvanic potential increased. This behavior shows the galvanic corrosion depends upon the presence of passive film. Also, galvanic effect of GECM coupled with ferrous alloys and non-ferrous alloys was lower than that of 100% graphite, which is attributed to lower exposed area of graphite fiber in the GECM than apparent area of the GECM specimen used for the calculation of galvanic current in this work.