• 한국세라믹학회지
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• 제27권2호
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• pp.161-168
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• 1990

To evaluate the corrosion behavior of reaction bonded silicon carbides, corrosion test was studied for various corrosive environments. Corrosion test for reaction bonded silicon carbides was conducted at 900$^{\circ}C$ under four different gas atmospehres ; air, So2-air, Cl2-O2-Ar, Cl2-N2 and investigated these samples using weight loss, bending strength, XRD, optical micrographs and EDS respectively.

• 한국재료학회지
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• 제16권9호
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• pp.557-563
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• 2006

The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Inconel 713LC, MA 754, X-750 and 718 in the molten salt $LiCl-Li_2O$ under an oxidizing atmosphere was investigated at $650^{\circ}C$ for $72{\sim}216$ hours. Inconel 713LC alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of Inconel 713LC were $Cr_2O_3,\;NiCr_2O_4$ and NiO, and those of Inconel MA 754 were $Cr_2O_3\;and\;Li_2Ni_8O_{10}$ while $Cr_2O_3,\;NiFe_2O_4\;and\;CrNbO_4$ were produced from Inconel 718. Also, corrosion products of Inconel X-750 were found to be $Cr_2O_3,\;NiFe_2O_4\;and\;(Cr,Nb,Ti)O_2$. Inconel 713LC showed local corrosion behavior and Inconel MA 754, 718, X-750 showed uniform corrosion behavior.

• Corrosion Science and Technology
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• 제8권5호
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• pp.188-192
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• 2009

A forced outage due to a steam generator tube leak in a Korean nuclear power plant was reported.1) Primary water stress corrosion cracking has occurred in many tubes in the plant, and they were repaired using sleeves or plugs. In order to develop proper repair criteria, it is necessary to understand the leak behavior of the tubes containing stress corrosion cracks. Stress corrosion cracks were developed in 0.1 M sodium tetrathionate solution at room temperature. Steam generator(SG) tubes with short cracks were successfully fabricated with a restricted solution contact method. The leak rates of the degraded tubes were measured at room temperature. Some tubes with 100 % through wall cracks showed an increase of leak rate with time at a constant pressure.

• 한국해양공학회지
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• 제14권1호
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• pp.60-66
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• 2000

In order to study for corrosion behavior of reinforcing steel with oxidation layer. Experiments were done with various NaCl concentrations and with immersion time in simulated concrete pore solution(SPS) the characteristics of corrosion behavior were measured by polarization resistance method and cyclic potentiodynamic method. reinforcements were coated by epoxy except corrosion without oxidation layer and it also showed two anodic-nose. by the result of potention dynamic test the potential curve shift to low with time and anodic-nose was appeared with 3% NaCl solution after 15 days. By result of cyclic Potentiodynamic test the type of corrosion was different accoding to concentration.

• Corrosion Science and Technology
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• 제9권1호
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• pp.12-15
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• 2010

Ti-13Nb-13Zr (TNZ) alloy has attracted considerable research attention in the last decade as a suitable substitute for the commercially used Ti-6Al-4V (TAV) alloy for orthopedic and dental implant applications. Hence, in the present work, a comparative evaluation has been performed on the electrochemical corrosion behavior of TNZ and TAV alloys in 0.9 wt.% NaCl solution. The result of the study showed that both the alloys had similar electrochemical behavior. The corrosion resistance of TAV alloy is found to be marginally superior to that of TNZ alloy.

• Advances in materials Research
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• 제7권2호
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• pp.105-118
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• 2018

Magnesium and its alloys are attracted towards all engineering applications like automotive, marine, aerospace etc. due to its inherent high strength to weight ratio. But, extensive use of Mg alloys is limited to the current scenario because of low wear and corrosion resistance behavior. However, equal channel angular press is one of the severe plastic deformation technique which has been effective method to improve the wear and corrosion resistance by achieving fine grain structure. In this study, the effect of grain refinement on wear and corrosion resistance of AZ80 Mg alloys were investigated. The wear behavior of the coarse and fine-grained Mg alloys was examined through $L_9$ orthogonal array experiments in order to comprehend the wear behavior under varies control parameters. It was shown that ECAPed alloy increased the wear and corrosion resistance of the Mg alloy through the formation of fine grain and uniform distribution of secondary ${\beta}-phase$. Also, the performance of AZ80 Mg alloy for these changeswas discussed through SEM morphology.

• 수산해양기술연구
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• 제34권1호
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• pp.30-36
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• 1998

Recently, with rapid increase of gas demand, there occurs much interest their security of safety in the gas storage tanks and pressure vessels etc. In order to solve the problems, the occurrence of corrosion fatigue crack and the propagation behavior must be investigated. Especially the occurrence of corrosion fatigue crack and the propagation behavior in the part which has concentrated stress or defects, must be studied more carefully. In this paper, the high-tensile steel of SPV 50 which is much used for building the LPG storage tanks was tested by the use of a plane bending corrosion fatigue tester under the various marine environments and in the air. These experiments were done to investigate the corrosion fatigue crack propagation behavior, the variation of aspect ratio for part through crack and electro-chemical characteristics of the metal. The main results obtained are as follows ; 1. Comparing the same surface crack length with the crack depth, the crack depth toward the thickness of specimen in air propagated faster than that in corrosion environment. 2. The aspect variation of the half elliptical crack can be estimated as following equation; b/a=i-jb/t where a : surface crack length, b : crack depth, t : specimen thickness, i,j : experimental constants but the slope j is decreased as specific resistance decreases. 3. As the specific resistance of corrosion environment decrease or the corrosion fatigue crack propagates, the corrosion potential become less noble.

• Corrosion Science and Technology
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• 제20권6호
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• pp.367-372
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• 2021

The effect of carbon addition on the general corrosion behavior of high-chromium cast iron (HCCI) was studied by a scanning electron microscope with energy dispersive spectroscopy (SEM-EDS) or electron back-scattered diffraction (EBSD), or electrochemical polarization techniques in 0.1 mol dm^-3 H₂SO₄ + 0.05 mol dm^-3 HCl at room temperature. The addition of 2.1-2.8 wt% carbon to HCCI increased the fraction of eutectic austenite and eutectic carbide phases, while that of HCCI decreased the fraction of the primary austenitic phase. Potentiostatic polarization of the HCCI at -0.35 V_SSCE or 0.0 V_SSCE resulted in preferential general corrosion of the primary austenitic or eutectic austenitic phases, respectively. The decrease in corrosion current density and the shift in noble corrosion potential direction with increasing carbon content in the HCCI indicated that the fraction and the chemical composition of austenitic (primary and eutectic) and carbide phases were strongly related to the general corrosion behavior of the HCCI.

• Corrosion Science and Technology
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• 제22권6호
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• pp.478-483
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• 2023

This study examined the corrosion behavior of bimetal materials composed of Fe-Ni alloy and Fe-Ni-Mo alloy, both suitable for use in electromagnetic switches. Electrochemical polarization and weight loss measurements revealed that, in contrast to Fe-Ni alloy, which exhibited pseudo-passivity behavior, Fe-Ni-Mo alloy had higher anodic current density, displaying only active dissolution and greater weight loss. This indicated a lower corrosion resistance in the Fe-Ni-Mo alloy. Equilibrium calculations for the phase fraction of precipitates suggested that the addition of 1 wt% Mo may lead to the formation of second-phase precipitates, such as Laves and M₆C, in the γ matrix. These precipitates might degrade the homogeneity of the passive film formed on the surface, leading to localized attacks during the corrosion process. Therefore, considering the differences in corrosion kinetics between these bimetal materials, the early degradation caused by galvanic corrosion should be prevented by designing a new alloy, optimizing heat treatment, or implementing periodic in-service maintenance.

• Corrosion Science and Technology
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• 제21권3호
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• pp.184-199
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• 2022

Steel was exposed in an atmospheric environment, and atmospheric environmental factors that include chloride, humidity, SO₂, NO₂ etc. induced the corrosion of steel. Corrosivity categories classified by SO₂ and chloride deposition rate were low, but those classified by TOW were high in the Korean Peninsula, and on these environmental categories, the corrosivity of atmospheres classified by corrosion rate in carbon steel was low medium, C2-C3, and medium, C3 for zinc, copper, and aluminum. This work performed the outdoor exposure test for 10 years at 14 areas in Korea and calculated the atmospheric corrosion rate of carbon steel. The atmospheric corrosion behavior of carbon steel is discussed based on the various corrosion factors. When the corrosion product forms on carbon steel by atmospheric corrosion, cracks may also be formed, and through these cracks, the environmental factors can penetrate into the interior of the product, detach some of the corrosion products and finally corrode locally. Thus, the maximum corrosion rate was about 7.3 times greater than the average corrosion rate. The color difference and glossiness of carbon steel by the 10 year-outdoor exposure tests are discussed based on the corrosion rate and the environmental factors.