• 제목/요약/키워드: Corrosion behavior

검색결과 1,274건 처리시간 0.026초

GFRP 보강근의 부착응력-미끄럼 모델 (Local Bond Stress-Slip Model of GFRP Rebars)

  • 정연걸;이종구;이정윤
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
    • /
    • pp.133-136
    • /
    • 2008
  • 염해에 노출이 심한 구조물이나 교량의 상판의 보강철근 부식으로 인한 콘크리트 구조물의 구조성능 및 내구성능의 저하가 큰 문제로 대두되고 있다. 이에 최근 활발히 연구가 진행 중인 유리섬유 보강근(Glass Fiber Reinforced Polymer Bar, 이하 GFRP 보강근)은 높은 화학적 내구성, 고강도, 경량성 등에 의하여 철근을 대체할 콘크리트 보강재로 그 가치를 인정받아 미국, 유럽, 캐나다 등에서는 이미 GFRP 보강근의 설계지침서가 발표되었다. 하지만 아직 GFRP 보강근을 이형철근과 같이 높은 신뢰성을 가지는 보강재로 사용하기에는 파악해야할 구조적 문제가 많이 있는데 그 중 하나가 콘크리트와의 부착성능이다. GFRP 보강근의 부착성능은 콘크리트 압축강도에 크게 영향을 받는 이형철근과 달리 섬유종류, 외피 표면 상태 등 여러 가지 요소에 의한 복합적 영향을 받는 부착특성을 보인다. 이에 본 연구에서는 외피 표면 상태, 콘크리트 압축강도 등을 변수로 하는 GFRP 보강근으로 보강된 일 방향 인장-인발 시편의 부착실험을 통하여 GFRP 보강근의 부착특성을 관찰하였다. 또한 이를 통하여 단조하중을 받는 GFRP 보강근의 부착응력-미끄럼 관계를 제안하고자 한다.

  • PDF

치밀층으로 코팅된 다공성 엔지니어링 세라믹스에서의 접촉응력에 의한 균열 거동 (Cracking Behavior Under Contact Stress in Densely Coated Porous Engineering Ceramics)

  • 김상겸;김태우;김도경;이기성
    • 한국세라믹학회지
    • /
    • 제42권8호
    • /
    • pp.554-560
    • /
    • 2005
  • The engineering ceramic needs the properties of high strength, hardness, corrosion-resistance and heat-resistance in order to withstand thermal shock or applied nonuniform stresses without failure. The densely coated porous ceramics can be used for machine component, electromagnetic component, bio-system component and energy-system component by their high-performances from superior coating properties and light-weight characteristics due to the structure including pore by itself. In this study we controlled the porosity of silica and alumina, $8.2\~25.4\%$ and $23.4\~36.0\%$, respectively, by the control of sintering temperature and starting powder size. We made bilayer structures, consisting of a transparent glass coating layer bonded to a thick substrate of different porous ceramics by a thin layer of epoxy adhesive, facilitated observations of crack initiation and propagation. The elastic modulus mismatch could be controlled using different porous ceramics as the substrate layer. Then we applied 150 N force using WC sphere with a radius of 3.18 mm by Hertzian indentation. As a result, the crack initiation in the coating layer was delayed at lower porosity in the substrate layer, and the damage in the coating layer was relatively smaller at the bilayer structure coated on higher elastic substrate.

A Study on the Electrode Characteristics of Hypo-Stoichiometric Zr-based Hydrogen Storage Alloys

  • Lee, Sang-Min;Kim, Seoung-Hoe;Lee, Jai-Young
    • 한국수소및신에너지학회논문집
    • /
    • 제10권4호
    • /
    • pp.197-210
    • /
    • 1999
  • The hydrogen storage performance and electrochemical properties of $Zr_{1-X}Ti_X(Mn_{0.2}V_{0.2}Ni_{0.6})_{1.8}$(X=0.0, 0.2, 0.4, 0.6) alloys are investigated. The relationship between discharge performance and alloy characteristics such as P-C-T characteristics and crystallographic parameters is also discussed. All of these alloys are found to have mainly a C14-type Laves phase structure by X-ray diffraction analysis. As the mole fraction of Ti in the alloy increases, the reversible hydrogen storage capacity decreases while the equilibrium hydrogen pressure of alloy increases. Furthermore, the discharge capacity shows a maxima behavior and the rate-capability is increased, but the cycling durability is rapidly degraded with increasing Ti content in the alloy. In order to analyze the above phenomena, the phase distribution, surface composition, and dissolution amount of alloy constituting elements are examined by S.E.M., A.E.S. and I.C.P. respectively. The decrease of secondary phase amount with increasing Ti content in the alloy explains that the micro-galvanic corrosion by multiphase formation is little related with the degradation of the alloys. The analysis of surface composition shows that the rapid degradation of Ti-substituted Zr base alloy electrode is due to the growth of oxygen penetration layer. After comparing the radii of atoms and ions in the electrolyte, it is clear that the electrode surface becomes more porous, and that is the source of growth of oxygen penetration layer while accelerating the dissolution of alloy constituting elements with increasing Ti content. Consequently, the rapid degradation (fast growth of the oxygen-penetrated layer) with increasing Ti substitution in Zr-based alloy is ascribed to the formation of porous surface oxide through which the oxygen atom and hydroxyl ion with relatively large radius can easily transport into the electrode surface.

  • PDF

생체용 타이타늄 합금의 산화거동 및 세포독성에 관한 연구 (A Study on Oxidation Behavior and Cytotoxicity Test of Ti-10Ta-10Nb Alloy)

  • 조홍규;이도재;이광민;이경구
    • 대한치과기공학회지
    • /
    • 제26권1호
    • /
    • pp.97-104
    • /
    • 2004
  • A new Ti-10Ta-10Nb alloy has designed and examined some possibility of forming more passive oxide film by oxidation treatment which is closely related to corrosion resistance and biocompatibility. Ti-6Al-4V and Ti-10Ta-10Nb alloys were prepared by consumable vacuum arc melting and homogenized at 1050$^{\circ}C$ for 24hours. Alloy specimens were oxidized at the temperature range of 400 to 750$^{\circ}C$ for 30minutes, and the oxide films on Ti alloys were analysed by optical microscope, SEM, XPS and TGA. Cytotoxicity test was performed in MTT assay treated L929 fibroblast cell culture by indirect method. It is found out that the oxide film on Ti-10Ta-10Nb alloy is denser and thinner compared to Ti-6Al-4V alloy. The weight gain during the oxidation was increased rapidly at the temperature above 650$^{\circ}C$ for Ti-6Al-4V alloy and above 700$^{\circ}C$ for Ti-10Ta-10Nb alloy respectively. It was analysed that the passive film of the Ti alloys consisted of TiO2 through X-ray photoelectron spectroscopy (XPS) analysis. It is found out by cytotoxicity test that moderate oxidation treatment lowers cell toxicity, and Ti-10Ta-10Nb alloy showed better result compared to Ti-6Al-4V alloy.

  • PDF

전기화학적 방법에 의한 주조 스테인리스강 CF8M $\sigma$상 열화평가 (Evaluation of the $\sigma$-Phase Degradation for Cast Stainless Steel CF8M by the Electrochemical Method)

  • 권재도;김중형;박중철;변장환;이우호
    • 대한기계학회논문집A
    • /
    • 제23권11호
    • /
    • pp.2014-2021
    • /
    • 1999
  • The present investigation is concerned with the degradation characteristics of cast stainless steel(CF8M), exposed to the $\sigma$-phase degradation at $700^{\circ}C$. In the present paper, the degradation of CF8 M at $700^{\circ}C$ is evaluated by a non-destructive test, DL-EPR(double loop electrochemical potentiokinetic reactivation). The surface of specimens is observed by using scanning electron microscopy after DL-EPR test. Also. chromium contents of matrix, grain boundary and ferrite phase are analyzed by electron probe X-ray micro analyzer. Through the experiments, the following results are obtained 1) The degree of sensitization(DOS) of CF8M aged up to 15hr at $700^{\circ}C$ is increased with acing time while that is decreased with aging time from 15hr to 150hr. 2) The impact energy decreases with increase of $\sigma$-phase while DOS increases with $\sigma$-phase until aging time reaches to 15hr. After the aging time. 15hr, the $\sigma$-phase and the rate of impact energy with respect to aging time decreases. Therefore the degradation behavior of the CF8M can be evaluated by comparing SEM micrographs and the value of DOS.

CFRP Rebar로 보강한 콘크리트 보의 휨 거동 (Flexural Behavior of Concrete Beams Reinforced with CFRP rebars)

  • 이영학;원동민;김민숙;김희철
    • 한국지진공학회논문집
    • /
    • 제14권1호
    • /
    • pp.43-50
    • /
    • 2010
  • 철근의 부식을 해결하기 위해 철근의 대체 재료로 적용 가능한 FRP에 대한 연구의 적용성이 대두되었다. 그러나 취성적인 성질과 탄성계수가 낮은 단점을 가지고 있어, FRP rebar로 보강된 휨 부재의 사용성 평가 즉 처짐에 대한 연구가 필요하다. 본 연구에서는 보강비를 변수로 한, CFRP rebar로 보강된 콘크리트 보의 휨 실험을 수행하였다. 실험 결과, CFRP rebar로 보강된 실험체는 보강비가 증가함에 따라 내력 및 강성이 증가하는 양상을 보였으며, 철근 실험체와 동일한 단면성능을 발휘하기 위해서는 약 1.3배의 보강비가 요구되는 것으로 나타났다. 또한 유효단면2차모멘트에 대한 기존 제안식의 비교 결과, Bischoff & Scanlon이 제안한 식이 가장 정밀해에 가까운 처짐을 예측하였다.

Mechanical and Thermal Analysis of Oxide Fuel Rods

  • Ilsoon Hwang;Lee, Byungho;Lee, Changkun
    • Nuclear Engineering and Technology
    • /
    • 제9권4호
    • /
    • pp.223-236
    • /
    • 1977
  • 가압수형 인자로에 사용되는 이산화우라 핵연료통의 역학적 열적설계 및 성능 분석을 위한 종합적 전산 코드가 개발되었다. PROD 1.0으로 명명된 이 코드에는 연료소자에서 반경 방향으로의 출력 침체, 연료소자의 균열, 고밀화 및 팽창, 핵분열기체의 방출, 피복관의 크립, 냉각수에 의한 열전달 및 부식층의 형성 둥의 제반 현상이 고려되었다. 이 FROD 1.0 코드로써 이차원적 온도 분포, 변형도, 응력 및 피복관 내압 등이 연소시간의 함수로서 적절한 전산 시간이내에 산출된다. 이 코드는 또한 종류가 다른 열중성자로에 쓰이는 산화 연료에도 응용필 수 있다. FROD 1.0의 응용으로서 원자로의 정상가동 상태와 미국 원자력학회 분류의 제 2상태에 해당하는 두 가지의 출력 경로에 더하여, 고리 원자력 발전소 1호기의 초기 노심에 장전된 핵연료봉의 연소특성을 예측하였다. 예측결과는 최종 안전 심사 보고서에 기술된 핵연료봉 설계기준과 비교되었으며 둘 사치의 차이점이 논의되었다.

  • PDF

복합재료 패널로 보강된 철근 콘크리트 보의 휨 실험 (Experiment on Flexural Analysis of RC Beams Strengthened with Composite Material Panel)

  • 김진만;정미루;이재홍;윤광섭
    • 한국공간구조학회논문집
    • /
    • 제10권2호
    • /
    • pp.117-126
    • /
    • 2010
  • 본 논문은 복합재료 패널로 보강된 철근 콘크리트 보의 휨 실험과 해석을 통하여 패널의 보강효과에 대하여 알아보고자 한다. FRP 복합재료 패널은 전통적인 재료인 강재와 콘크리트에 비해 단위 무게당 강도 및 강성이 크고 부식에 대한 높은 저항성, 절연성, 고내구성 및 낮은 열전도성 등 우수한 물성으로 유지관리 측면에서 매우 유리하여 최근 많은 연구가 이루어지고 있다. 따라서 본 연구에서는 범용 유한요소 해석 프로그램인 ABAQUS를 이용하여 복합재료 패널로 보강된 철근 콘크리트 보의 극한 하중을 예측하고 실험을 수행하여 그 보강효과에 대한 고찰하였다. 복합재료 패널은 복합재료 패널 층의 유리섬유직조 형태에 따라 LT, DB, DBT로 구분하고 복합재료 패널의 층 개수에 따라 2ply, 3ply로 구분하였다. 실험을 수행한 결과, 해석과 일치하였으며 복합재료 패널로 보강한 철근 콘크리트 보가 극 한강도 측면에서 효율적이었다는 결론도 얻었다.

  • PDF

가압열충격 사고시 클래드 하부균열 안전성 평가 방법에 관한 연구 (A Study on the Integrity Evaluation Method of Subclad Crack Under Pressurized Thermal Shock)

  • 김영진;김진수;구본걸;최재붕;박윤원
    • 대한기계학회논문집A
    • /
    • 제25권7호
    • /
    • pp.1139-1146
    • /
    • 2001
  • The reactor pressure vessel(RPV) is usually cladded with stainless steel to prevent corrosion and radiation embrittlement, and a number of subclad cracks have been found during an in-service-inspection. These subclad cracks should be assured for a safe operation under normal conditions and faulted conditions such as pressurized thermal shock(PTS). Currently available integrity assessment procedure for an RPV, ASME Code Sec. XI, are built on the basis of linear fracture mechanics (LEFM). In PTS condition, however, thermal stress and mechanical stress give rise to high tensile stress at the cladding and elastic-plastic behavior is expected in this area. Therfore, ASME Code Sec. XI is overly conservative in assessing the structural integrity under PTS condition. In this paper, the fracture parameter (stress intensity factor, K, and RT(sub)NDT) from elastic analysis using ASME Sec. XI and finite element method were validated against 3-D elastic-plastic finite element analyses. The difference between elastic and elastic-plastic analysis became significant with increasing crack depth. Therfore, it is recommended to perform elastic-plastic analysis for the accurate assessment of subclad cracks under TPS which causes plastic deformation at the cladding.

Detection of tension force reduction in a post-tensioning tendon using pulsed-eddy-current measurement

  • Kim, Ji-Min;Lee, Jun;Sohn, Hoon
    • Structural Engineering and Mechanics
    • /
    • 제65권2호
    • /
    • pp.129-139
    • /
    • 2018
  • Post-tensioning (PT) tendons are commonly used for the assembly of modularized concrete members, and tension is applied to the tendons during construction to facilitate the integrated behavior of the members. However, the tension in a PT tendon decreases over time due to steel corrosion and concrete creep, and consequently, the stress on the anchor head that secures the PT tendon also diminishes. This study proposes an automatic detection system to identify tension reduction in a PT tendon using pulsed-eddy-current (PEC) measurement. An eddy-current sensor is installed on the surface of the steel anchor head. The sensor creates a pulsed excitation to the driving coil and measures the resulting PEC response using the pick-up coil. The basic premise is that the tension reduction of a PT tendon results in stress reduction on the anchor head surface and a change in the PEC intensity measured by the pick-up coil. Thus, PEC measurement is used to detect the reduction of the anchor head stress and consequently the reduction of the PT tendon force below a certain threshold value. The advantages of the proposed PEC-based tension-reduction-detection (PTRD) system are (1) a low-cost (< $ 30), low-power (< 2 Watts) sensor, (2) a short inspection time (< 10 seconds), (3) high reliability and (4) the potential for embedded sensing. A 3.3 m long full-scale monostrand PT tendon was used to evaluate the performance of the proposed PTRD system. The PT tendon was tensioned to 180 kN using a custom universal tensile machine, and the tension was decreased to 0 kN at 20 kN intervals. At each tension, the PEC responses were measured, and tension reduction was successfully detected.