• Title/Summary/Keyword: Corrosion behavior

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Three-dimensional finite element simulation and application of high-strength bolts

  • Long, Liji;Yan, Yongsong;Gao, Xinlin;Kang, Haigui
    • Steel and Composite Structures
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    • v.20 no.3
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    • pp.501-512
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    • 2016
  • High-strength structural bolts have been utilized for beam-to-column connections in steel-framed structural buildings. Failure of these components may be caused by the bolt shank fracture or threads stripping-off, documented in the literature. Furthermore, these structural bolts are galvanized for corrosion resistance or quenched-and-tempered in the manufacturing process. This paper adopted the finite element simulation to demonstrate discrete mechanical performance for these bolts under tensile loading conditions, the coated and uncoated numerical model has been built up for two numerical integration methods: explicit and implicit. Experimental testing and numerical methods can fully approach the failure mechanism of these bolts and their ultimate load capacities. Comparison has also been conducted for two numerical integration methods, demonstrating that the explicit integration procedure is also suitable for solving quasi-static problems. Furthermore, by using precise bolt models in T-Stub, more accurately simulate the mechanical behavior of T-Stub, which will lay the foundation of the mechanical properties of steel bolted joints.

Fatigue crack growth characteristics of nitrogen-alloyed type 347 stainless steel under operating conditions of a pressurized water reactor

  • Min, Ki-Deuk;Hong, Seokmin;Kim, Dae-Whan;Lee, Bong-Sang;Kim, Seon-Jin
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.752-759
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    • 2017
  • The fatigue crack growth behavior of Type 347 (S347) and Type 347N (S347N) stainless steel was evaluated under the operating conditions of a pressurized water reactor (PWR). These two materials showed different fatigue crack growth rates (FCGRs) according to the changes in dissolved oxygen content and frequency. Under the simulated PWR conditions for normal operation, the FCGR of S347N was lower than that of S347 and insensitive to the changes in PWR water conditions. The higher yield strength and better corrosion resistance of the nitrogen-alloyed Type 347 stainless steel might be a main cause of slower FCGR and more stable properties against changes in environmental conditions.

A Study on Fatigue Crack Behavior of Metal Matrix Composites for Automobile Engine (자동차엔진용 금속기 복합재료의 피로균열거동에 관한 연구)

  • 박원조;허선철;정재욱;이해우;부명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.5
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    • pp.140-146
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    • 2003
  • Metal matrix composites had generated a lot of interest in recent time because of their high specific strength and stiffness in specific properties. It was also highlighted as the material of frontier industry because strength, heat-resistance, corrosion-resistance and wear-resistance were superiored. In this study, the strength properties of $Al_{18}B_{4}O_{33}$/AC4CH composites were represented mixing the binder of $SiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_{4}O_{33}$/AC4CH was fabricated at the melt temperature of $760^{\circ}C$, the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa. Consequently, fatigue life was observed roughly in the order of AC4CH> nobiner> $SiO_2$, independently on crack propagation direction and stress ratio.

Improvement of Electrochemical Characteristics and Study of Deterioration of Aluminum Foil in Organic Electrolytes for EDLC

  • Lee, Mun-Soo;Kim, Donna H.;Kim, Seung-Cheon
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.9-19
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    • 2018
  • The anodic behavior of aluminum (Al) foils with varying purity, capacitance, and withstand voltage in organic electrolytes was examined for EDLC. The results of cyclic voltammetry (CV) and chronoamperometry (CA) experiments showed that the electrochemical stability improves when Al foil has higher purity, lower capacitance, and higher withstand voltage. To improve the electrochemical stability of EDLC current collectors made of low-purity foil (99.4% Al foil), the foil was modified by chemical etching to reduce its capacitance to $60{\mu}F/cm^2$ and forming to have withstand a voltage of 3 Vf. EDLC cells using the modified Al foil as a current collector were made to 2.7 V with 360 F, and a constant voltage load test was subsequently performed for 2500 hours at high temperature under a rated voltage of 2.7 V. The reliability and stability of the EDLC cell improved when the modified Al foil was used as a current collector. To understand the deterioration process of the Al current collector, standard cells made of conventional Al foil under a constant voltage load test were disassembled, and the surface changes of the foil were measured every 500 hours. The Al foil became increasingly corroded, causing the adhesion between the AC coating layer and the Al foil to weaken, and it was confirmed that partial AC coating layer peeling occurred.

Cavitation Damage Characteristics of Al and Zn Arc Thermal Spray Coating Layers for Hull Structural Steel (선체 구조용 강재에 대한 Al과 Zn 아크용사코팅 층의 캐비테이션 손상 특성)

  • Park, Il-Cho;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.32-39
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    • 2016
  • In this study, Al and Zn arc thermal spray coatings were carried out onto the substrate of SS400 steel to improve corrosion resistance and durability of hull structural steel for ship in marine environment. Therefore cavitation-erosion test was conducted to evaluate the durability of painted and thermal spray coated specimens. And then the damaged surface morphology and weight loss were obtained to compare with each other, respectively. As a result, the painted specimen was the poorest cavitation resistance characteristics because surface damage behavior appeared to be exfoliated in bulk shape during the cavitation experiment. And Zn thermal spray coating layer presented the significant surface damage depth due to relatively low surface hardness and local cavitation damage tendency. On the other hand, as a result of the weight loss analysis, the painting layer presented the poorest cavitation resistance and the Al thermal spray coating layer relatively showed the best results after cavitation experiment.

Experimental Investigations of Mode I Fracture Toughness of a Hybrid Twill Woven Carbon and Aramid Fabric Composite (하이브리드 능직 탄소-아라미드 섬유 복합재의 모드 I 파괴인성에 대한 실험적 연구)

  • Kwon, Woo Deok;Kwon, Oh Heon
    • Journal of the Korean Society of Safety
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    • v.34 no.6
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    • pp.1-6
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    • 2019
  • Carbon fiber has excellent specific strength, corrosion resistance and heat resistance. And p-Aramid fiber has high toughness and heat resistance and high elasticity, and is used in various fields such as industrial protective materials, bulletproof helmets and vests, as well as industrial fields. However, carbon fiber is relatively expensive, and is susceptible to brittle fracture behavior due to its low fracture strain. On the other hand, the aramid fiber tends to decrease in elastic modulus and strength when applied to the epoxy matrix, but it is inexpensive and has higher elongation and fracture toughness than carbon fiber. Thus the twill hybrid carbonaramid fiber reinforced composite laminate composite was investigated for a delamination fracture toughness under Mode I loading by 2 kinds of MBT and MCC deduction. The specimen was fabricated with 20 hybrid fabric plies. The initial crack was made by inserting the teflon tape in the center plane with a0/W=0.5 length. The results show that SERR(Strain Energy Release Rate) as the critical and stable delamination fracture toughness were 0.09 kJ/㎡, 0.386 kJ/㎡ by MBT deduction, and 0.192 kJ/㎡, 0.67 kJ/㎡ by MCC deduction, respectively.

A study on the characteristics of phosphating solution for automobile-aluminum-body sheets (차체용 알루미늄합금의 인산염피막 처리액의 특성 관한 연구)

  • Lee, K. H.;Ro, B. H.;Kim, M.
    • Journal of the Korean institute of surface engineering
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    • v.27 no.4
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    • pp.207-214
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    • 1994
  • In consideration of global environmental protection and fuel saving, aluminum alloy sheets for auto body panels such as hood, fender etc., are expected one of the most promising materials for weight saving of cars. The chemical conversion coating is required to prevent the filiform corrosion occurring on painted aluminum. However the conventional process for the composited material mixed with aluminum and steel is complexs; aluminum part is chromated and assembled to the body, and then the steel body undergoes Zn phosphating. In order to overcome the low productivity due to the complex process and the environmental problem with a conventional process, a simultaneous zinc phosphating process for alsuminum and steel in an assembled condition is demanded. Newly developed phosphate solution has been investigated to characterize the phosphating behavior under various conditions. The optimum conditions of the phosphating solution for the application of the paint treatment derived as follows : about 0.3 for the ratio of Zn to $PO_4$, , 200~500 ppm for the concentration of fluoride ion, and 2.5~4.0 for pH. The concentration of dissolved aluminum ion must be kept below 2--ppm and suitable accelerator is found to be a mixture of 1g/$\ell$ $NO_2\;^-$, and 6g/$\ell$ $NO_3\;^-$.

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Polishing Behavior and Characterization of Cu Surface in Citric Acid based Slurry with Corrosion Inhibitor (BTA) (부식방지제(BTA)가 첨가된 Cu CMP 슬러리에서의 연마거동과)

  • Kim, In-Kwon;Kang, Young-Jae;Hong, Yi-Kwan;Kim, Tae-Gon;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.42-43
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    • 2005
  • 본 연구에서는 Cu 슬러리에 부식방지제인 BTA를 첨가하여 슬러리내의 과수의 농도, pH 의 변화, 연마입자의 종류에 따라 연마거동에 미치는 영향과 각 chemical 변화에 따른 Cu surface의 변화를 살펴보았다. BTA (Benzotriazole, $C_6H_4C_3H$)를 첨가함으로써 본 연구에서 시행된 pH 와 과수의 변화에 상관없이 Cu-BTA film을 형성하여 Cu의 dissolution을 최대한 억제하는 것을 확인할 수 있었다. 또 그로인해 BTA를 첨가하지 않았을 때보다 얇은 passivation layer를 형성함을 알 수 있었고 contact angle도 더 높았다. 연마율의 경우에도 BTA가 첨가됨으로써 감소됨을 확인할 수 있었고 연마입자로 alumina particle을 사용한 경우에는 pH6, 과수 10vol%이상에서는 오히려 연마율이 증가하였다. fumed silica의 경우에는 hardness가 작아 mechanical적인 제거력이 낮아 BTA가 첨가되어도 연마율에는 큰 영향이 없었다.

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Dynamic Material Characteristics of Superalloy INCONEL 718 with the Variation of Strain Rates (변형률속도 변화에 따른 INCONEL 718 초내열합금의 동적 물성특성)

  • Song J. H.;Huh H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.275-278
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    • 2005
  • INCONEL 718, nickel based superalloy, has good formability, high strength, excellent corrosion resistance and mechanical properties at high temperature. Owing to theses attractive properties, it finds use in applications such as combustion system, turbine engines and nuclear reactors. In such applications, components are typically required to be tolerant of high stress impact loading. This may cause material degradation and lead to catastrophic failure during service operation. In order to design optimal structural parts made of INCONEL 718, accurate understanding of material's mechanical properties, dynamic behavior and fracture characteristic as a function of strain rates are required. This paper concerned with the dynamic material properties of the INCONEL 718 for the various strain rates. The dynamic response of the INCONEL 718 at intermediate strain rate is obtained from the high speed tensile test machine test and at the high strain rate is from the split Hopkinson pressure bar test. Based on the experimental results, the effects of strain rate on dynamic flow stress, work hardening characteristics, strain rate sensitivity and elongation to the failure are evaluated. Experimental results from both quasi-static and high strain rate up to the 5000/sec are interpolated in order to construct the Johnson-Cook model as the constitutive relation that should be applied to simulate and design the structural parts made of INCONEL 718.

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The Effect of F-treatment on the Degradation Behavior of the $CaNi_{5}$ and MG-$CaNi_{5}$ Electrodes ($CaNi_{5}$ 및 MG-$CaNi_{5}$ 전극의 퇴화거동에 미치는 불화처리의 영향)

  • Lee, C.R.;Oh, S.J.;Kang, S.G.
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.622-629
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    • 1999
  • Effects of the fluorination in the $K_2$TiF\ulcorner solution and in-situ KF+ KOH electrolyte on the electrochemical charge-discharge properties of CaNi\ulcorner and the Mg-CaNi\ulcorner electrodes were investigated. In-situ fluorination in the KF+ KOH electrolyte compared with pre-fluorination in the$ K_2$TiF\ulcorner solution could improve the electrochemical cycling durability of CaNi\ulcorner and MG-CaN\ulcorner electrodes. The fluorinated layer on the alloy surface by pre-fluorination to improve the activity and anti-corrosion of the electrodes was dissolved in the pure KOH electrolyte during the cycling. The fluorinated layer was formed continuously on the surface of the electrode by thee2N KF addition in the 6N KOH electrolyte. The excess F\ulcorner ion addition in KOH electrolyte could improve the electrochemical cycling durability of CaNi\ulcorner and Mg-CaNi\ulcorner electrode. But, in case of MG-CaNi\ulcorner electrode, the discharge capacity of the electrode was reduced and the poor cycling property was shown with increasing of the MG process times.

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