• Title/Summary/Keyword: Corrosion and Anti-corrosion

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Recent applications of lubricant-impregnated nanoporous surface : A Review (윤활액이 담지된 나노다공성 표면의 최신 응용분야)

  • Kyeongwan Han;Kichang Bae;Junghoon Lee
    • Journal of the Korean institute of surface engineering
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    • v.56 no.1
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    • pp.1-11
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    • 2023
  • Lubricant-impregnated nanoporous surfaces (LIS), which is created by impregnating water-immiscible oil into nanoporous surface structure, have been explored considering wide range of application fields. Due to the lubricant impregnated in nanoporous structure, the surface shows extreme de-wetting with a high mobility of water droplets, so that various functionalities can be realized. The lubricant layer inhibits the contact of corrosive media to porous structure as well as metal substrate, thus the surface improves the corrosion resistance. The water on the surface freeze without any contact to solid porous structure, showing a low ice adhesion for de-icing an anti-icing. The extremely high mobility of water droplets on lubricant-impregnated porous surfaces also contributes the enhancement of condensation heat transfer as well as water harvesting from fog and moisture. Moreover, the bacteria adhesion on metal surface forming biofilms causing serious hygiene issues can be inhibited on the lubricantimpregnated surfaces. Despite of such superior functionalities, the lubricant-impregnated porous surface has a limitation of lubricant depletion by external flow of fluids. Therefore, extensive efforts to improve the durability of lubricant-impregnated surface are required for practical applications.

A study on Biodegradability of Vegetable Oil based EP Grease (식물유계 EP그리스의 생분해도 평가에 관한 연구)

  • Nam Kyung-Im;Kim Young-wun;Chung Keunwo;Cho Wonoh;Jeon In-sik;Chung Yong-Mi
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2003.11a
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    • pp.139-148
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    • 2003
  • In this study, biodegradable base Li-greases were prepared by using Li-soap thickener and vegetable oils such as soybean oil, rapeseed oil, castor oil and synthetic ester. Also, EP-greases were formulated by blending base Li-greases, anti-wear additives, EP additives, anti-oxidants and corrosion inhibitor etc. And EP-greases were characterized by analysing physical properties such as worked penetration, dropping point, 4-ball wear, extreme pressure, thermal properties etc. Biodegradability of base Li-greases and EP-greases were evaluated by CEC-L-33-A-93 method using several inoculums of domestic sewage treatment plant. As the results, biodegradability of vegetable oils were shown at the range of 97.1 to $98.4\%$. And biodegradability of base Li-greases and EP-greases were $86.2\%\;\~\;89.3\%\;and\;83.4\%\;\~\;90.0\%$ which were lower value than those o( vegetable oils due to effect of Li-soap thickener, respectively. Therefore, the EP-greases prepared in this study were easily biodegraded by microorgnism.

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Development of Dry Process Caisson Method for Maintenance of Submerged Harbor Structure (수중 항만구조물의 유지보수를 위한 건식 케이슨 공법 개발)

  • Lee Joong-Woo;Oh Dong-Hoon;Kwak Seung-Kyu;Kim Sung-Tae
    • Journal of Navigation and Port Research
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    • v.30 no.6 s.112
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    • pp.447-455
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    • 2006
  • Together with the trend of enhancement in domestic industrial development and economic progress due to import and export, the demand for construction of the roads, bridges, especially port facilities, and several coastal protection and ocean structures is increasing rapidly. MOMAF of Korean Government is driving construction cf 9 new ports and renovation cf the existing fishery ports. Among these structures most of bridge base, wharves, dolphins, quays, and jetties are being newly built cf steel or concrete pile. As the base, supporting bulkheads, and piles are underwater after construction, it is difficult to figure out the status of structures and not enough to get maintenance and strengthen the structures. Every year, moreover, these works suck the government budget due to higher incomplete maintenance expense for protection from corrosions cf structures and increased underwater construction period. For the purpose cf cutting down the expense cf government budget, it is necessary to extend the life cycle of the existing structures. Therefore, we developed a new method for maintenance of submerged structures near the waterline by allowing dry work environment with the floating caisson. The method shows easy to move around the working area and handle. It also showed not only a significant reduction of maintenance expenses and time for anti-corrosion work but also better protection This will be a milestone to reduce the maintenance and construction expenses for the shore and water structures.

Development of Dry Process Caisson Method for Maintenance of Submerged Harbor Structure (수중 항만구조물의 유지보수를 위한 건식 케이슨 공법 개발)

  • Lee Joong-Woo;Oh Dong-Hoon;Kwak Seung-Kyu;Kim Sung-Tae
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2006.06b
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    • pp.163-170
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    • 2006
  • Together with the trend of enhancement in domestic industrial development and economic progress due to import and export, the demand for construction of the roads, bridges, especially port facilities, and several coastal protection and ocean structures is increasing rapidly. MOMAF of Korean Government is driving construction of 9 new ports and renovation of the existing fishery ports. Among these structures most of bridge base, wharves, dolphins, quays, and jetties are being newly built of steel or concrete pile. As the base, supporting bulkheads, and piles are underwater after construction, it is difficult to figure out the status of structures and not enough to get maintenance and strengthen the structures. Every year, moreover, these works suck the government budget due to higher incomplete maintenance expense for protection from corrosions of structures and increased underwater construction period. For the purpose of cutting down the expense of government budget, it is necessary to extend the life cycle of the existing structures. Therefore, we developed a new method for maintenance of submerged structures near the waterline by allowing dry work environment with the floating caisson. The method shows easy to move around the working area and handle. It also showed not only a significant reduction maintenance expenses and time for anti-corrosion work but also better protection. This will be a milestone to reduce the maintenance and construction expenses for the shore and water structures.

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A Study on Predicting Ship Resistance Performance due to Surface Roughness Using CFD (CFD를 이용한 표면 거칠기에 따른 선박의 저항 성능 추정에 관한 연구)

  • Seok, Jun;Park, Jong-Chun;Shin, Myung-Soo;Kim, Sung-Yong
    • Journal of the Society of Naval Architects of Korea
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    • v.53 no.5
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    • pp.400-409
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    • 2016
  • In recent, shipping companies have made an enormous effort to improve the operation of vessel in various approaches, due to recession of shipping market and increasing competition among shipping companies. One of important parameters for improving the efficiency of vessel is the resistance performance that consist of friction and residual resistance. Especially, it is recognized that the friction resistance tends to be affected by conditions of vessel’s surface and occupies approximately 70~90% of the total resistance for slow speed ships. In general, the surface of vessel is covered with various type of paint to reduce fouling and corrosion. As time goes by, however, it is so hull roughness would be increased by fouling over the wetted surface that anti-fouling paints, such as CDP(Controlled Depletion Paint), Tin-Free SPC(Self Polishing Co-polymer) or Foul Release, are applied evenly on the hull surface. Nevertheless, these anti-fouling paints could not prevent fouling absolutely. A fundamental study on evaluating ship resistance performance variation due to hull roughness has been performed using a commercial software, Star-CCM+, which solves the continuity and Navier-Stokes equations for incompressible and viscous flow. The results of present simulation for plate are compared with some experimental data available and the effect of surface roughness to ship resistance performance is discussed.

Characteristics of LDPE resin film depending on RP contents (적인 함유량에 따른 LDPE 수지 film의 특성연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6655-6665
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    • 2015
  • Due to tightened environmental regulations on halogen type flame retardants, the portions of those based on phosphorous compounds that are non-halogen type is rising. When producing functional film, the physical and thermal properties become distinctly different depending on the amount of Red-phosphorus(RP) addition which causes flame resistance. The physical properties of resin fall in big scale when too much flame retardants are added, and it is hard to be applied to functional films such as shrink or anticorrosive film. The purpose of this research is to study the effects on mechanical, physical, and other properties of RP-LDPE films by changing the RP-MB contents. The LDPE film used for this study was produced through blow-type injection molding. The flame resistance was VTM-0, and the tear resistance showed inverse trends of MD and TD. Contraction percentage showed no relationship with the amount of RP content, but the anti-corrosive property showed 0.05 % better result than the national anti-corrosion shrink film reliability standard.

Development and Performance Evaluation of Anti-cavitation Paint with a Lamella Glass-flake (판상형 Glass-flake를 이용한 내캐비테이션 도료 개발 및 성능평가)

  • Park, Hyeyoung;Kim, Sung-gil;Kim, Sang-suk;Choi, I-chan;Kim, Byungwoo;Kim, Seung-jin
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.145-151
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    • 2016
  • In response to the cavitation caused by the partial vacuum caused by the fluid flow, a paint was developed by dispersing the lamella-shaped glass-flake in resin for anti-cavitation. This composite paint was developed by using the inorganic filler (lamella shaped glass-flake) and the NBR (Acrylonitrile-butadiene rubber) which was modified epoxy resin. Especially, the glass-flake was a thin film with a thickness of about 100~200 nm and length of about $20{\sim}30{\mu}m$, the aspect ratio was about 200 to 300 times that of the plate-shaped. So the paint for anti-cavitation have shown excellent performance in corrosion resistance. The results of evaluating anti-cavitation performance was below, tensile strength $4.8{\sim}6N/mm^2$ or more, rupture elongation 30% or higher, abrasive speed $10mm^2/h$ or less. In particular, it showed more than twice the superior performance compared to existing advanced foreign products in anti-cavitation performance evaluation.

Preparation of Hydrophobic Coating Layers Using Organic-Inorganic Hybrid Compounds Through Particle-to-Binder Process (유-무기 하이브리드 화합물과 Particle-Binder 공정을 이용한 소수성 코팅막 제조)

  • Hwang, Seung-Hee;Kim, Hyo-Won;Kim, Juyoung
    • Journal of Adhesion and Interface
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    • v.21 no.4
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    • pp.143-155
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    • 2020
  • Hydrophobic Organic-Inorganic (O-I) hybrid materials prepared by sol-gel process have been widely used at functional coating fields such as coatings for anti-corrosion, anti-icing, self-cleaning, anti-reflection. The key point for fabricating hydrophobic surface is to optimize the surface energy and roughness of the coating films. There are typical processes to control the surface energy and roughness which are 'In situ fabricating', 'Pre-fluorinating/Post-roughening', 'Pre-roughening/ Post-fluorinating'. In this study, particle-binder process was used for in-situ fabrication of hydrophobic coating films. Various O-I hybrid compounds prepared using several kinds of alkoxysilane compounds were used as a binder for silica nanoparticles at particle-binder process. To study effect of fluorine content and weight ratio of particle : binder on the hydrophobicity and surface morphology, Hydrophobic coating films were prepared onto glass substrate at various content of fluorine content of O-I hybrid binder and weight ratio of particle : binder. The coating films prepared using O-I hybrid binder (GPTi-HF10) having 10 wt% of fluorine content showed the highes water contact angle (107.52±1.6°). The coating films prepared at 1:3 weight ratio of GPTi-HF10 : silica nanoparticle exhibited the highest water contact angle (130.84±1.99°).

Effect of Strain Aging on the Tensile Properties of an API X70 Linepipe Steel (API X70 라인파이프강의 인장 특성에 미치는 변형 시효의 영향)

  • Lee, Seung-Wan;Lee, Sang-In;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.524-529
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    • 2017
  • The effect of strain aging on the tensile properties of API X70 linepipe steel was investigated in this study. The API X70 linepipe steel was fabricated by controlled rolling and accelerated cooling processes, and the microstructure was analyzed using optical and scanning electron microscopes and electron backscatter diffraction. Strain aging tests consisting of 1 % pre-strain and thermal aging at $200^{\circ}C$ and $250^{\circ}C$ were conducted to simulate U-forming, O-forming, Expansion(UOE) pipe forming and anti-corrosion coating processes. The API X70 linepipe steel was composed of polygonal ferrite, acicular ferrite, granular bainite, and bainitic ferrite whose volume fraction was dependent on the chemical composition and process conditions. As the thermal aging temperature increased, the steel specimens showed more clearly discontinuous type yielding behavior in the tensile stress-strain curve due to the formation of a Cottrell atmosphere. After pre-strain and thermal aging, the yield and tensile strengths increased and the yield-to-tensile strength ratio decreased because yielding and aging behaviors significantly affected work hardening. On the other hand, uniform and total elongations decreased after pre-strain and thermal aging since dislocation gliding was restricted by increased dislocation density after a 1 % pre-strain.

Anti-Corrosion Properties of TiN-Coated Bolt for Application to Nuclear Power Plants Located Near Coastal Areas (해안에 인접한 원자력발전소에 적용하기 위한 체결볼트의 TiN박막 코팅처리를 한 체결볼트의 방식특성)

  • Lee, Su-Been;Lee, Jin-Woo;Park, Soo-Jeong;Kim, Yun-Hae
    • Journal of Ocean Engineering and Technology
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    • v.30 no.5
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    • pp.356-360
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    • 2016
  • Recently, the lifetime extension of nuclear power plants has been considered. Thus, it is necessary to consider facility safety management and economic management. However, when the bolts in nuclear power plants are replaced and the turbines of nuclear power plant are disassembled, numerous problems are found in relation to stuck bolts in clamping parts. In order to solve these problems, a hybrid vacuum chamber was first designed and manufactured. It can perform arc ion plating and sputtering, which were used to deposit Ti/TiN on an A913 B7 bolt. X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses were conducted to determine the composition and characteristics of the bolt, and tests were conducted to determine how long the bolt could endure under various conditions in a nuclear power plant. The SEM and XRD results clearly showed a continual and even coating layer. When this TiN-coated bolt is used in a nuclear power plant, the lifetime can be extended compared to a conventional bolt, but it is necessary to determine what additional properties are required.