• Title/Summary/Keyword: Corrosion Degradation

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Recommendations of Environmental Reduction Factor of FRP Rebar for Durability Design of Concrete Structure (콘크리트 보강용 FRP 보강근의 내구성 설계를 위한 환경영향계수의 제안)

  • Park Chan-Gi;Won Jong-Pil;Kang Joo-Won
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.529-539
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    • 2004
  • The corrosion of steel rebars has been the major cause of reinforced concrete deterioration. FRP(Fiber-reinforced polymer) rebar has emerged as one of the most promising and affordable solutions to the corrosion problems of steel reinforcement in structural concrete. However, FRP rebar is prone to deteriorate due to other degradation mechanisms than those for steel. The high alkalinity of concrete, for instance, is a possible degradation source. Therefore, the USA, Japan, Canada, UK. etc are using environmental reduction factor. Although difference design guidelines were drawn in many, including USA, Japan, Canada, UK etc, recommendations and coefficients that could take into account the long-term behavior of FRP reinforcement were not well defined. This study focuses on recommendation of environmental reduction factor of FRP rebar. Environment reduction factor were decided using durability test result. FRP rebars were subjected to twelve type of exposure conditions including alkaline solution, acid solution, salt solution and deionized water etc. The water absorption behavior was observed by means of simple gravimetric measurements and durability properties were investigated by performing tensile, compressive and short beam tests. Based on the experimental result, environmental reduction factor of hybrid FRP rebar(A), and (C) and CFRP rebar was decided as 0.85. Also, hybrid FRP rebar(B) and GFRP rebar were decided as 0.7 for the environmental reduction factor

Development of Permanent Reference Electrode for Corrosion Monitoring of Underground Metallic Structures (지중 금속구조물 부식감시를 위한 영구매설용 기준전극 개발)

  • Ha, Y.C.;Bae, J.H.;Ha, T.H.;Lee, H.G.;Lee, J.D.;Kim, D.K.
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.532-534
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    • 2004
  • The advancement of electronics and telecommunication technologies has forced the risk management system for underground metallic structures to evolve into the remote monitoring and control system. Especially, facilities such as gas pipelines, oil pipelines and water distribution lines might make hazardous effect on human safety without continuous monitoring and control. As a result, pipeline engineers have applied cathodic protection system to prevent the degradation of their facilities by corrosion and carried out a periodic monitoring of the pipe-to-soil (P/S) potentials at numberous test boxes along their pipelines. The latter action on a road in downtowns, however, is so much dangerous that the inspectors should be ready to suffer the threatening of their lives and maintenance. In order to minimize these social costs and hazards, a stand-alone type corrosion monitoring equipment which can be installed in test box, store the P/S data for given Belied and send the data by wired/wireless telecommunications is under development. In order to obtain the exact P/S data, however, a reference electrode should be located as close to the pipeline as possible. Actually, the measured potential by a conventional portable reference electrode contain inevitably an IR drop portion caused by the current flow from the cathodic protection rectifier or the subway railroad. To minimize this error, it is recommended that the reference electrode should be buried within 10 cm from the pipeline. In this paper, we describe the design parameters for fabricating the permanent type reference electrode and the characteristics of the developed reference electrode.

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Probabilistic Approach for Predicting Degradation Characteristics of Corrosion Fatigue Crack (환경피로균열 열화특성 예측을 위한 확률론적 접근)

  • Lee, Taehyun;Yoon, Jae Young;Ryu, KyungHa;Park, Jong Won
    • Journal of Applied Reliability
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    • v.18 no.3
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    • pp.271-279
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    • 2018
  • Purpose: Probabilistic safety analysis was performed to enhance the safety and reliability of nuclear power plants because traditional deterministic approach has limitations in predicting the risk of failure by crack growth. The study introduces a probabilistic approach to establish a basis for probabilistic safety assessment of passive components. Methods: For probabilistic modeling of fatigue crack growth rate (FCGR), various FCGR tests were performed either under constant load amplitude or constant ${\Delta}K$ conditions by using heat treated X-750 at low temperature with adequate cathodic polarization. Bayesian inference was employed to update uncertainties of the FCGR model using additional information obtained from constant ${\Delta}K$ tests. Results: Four steps of Bayesian parameter updating were performed using constant ${\Delta}K$ test results. The standard deviation of the final posterior distribution was decreased by a factor of 10 comparing with that of the prior distribution. Conclusion: The method for developing a probabilistic crack growth model has been designed and demonstrated, in the paper. Alloy X-750 has been used for corrosion fatigue crack growth experiments and modeling. The uncertainties of parameters in the FCGR model were successfully reduced using the Bayesian inference whenever the updating was performed.

Effects of Cr Addition on the Magnetic Properties and Corrosion Resistance of Nanocrystalline FeZrN Thin Films (미결정 FeZrN 박막의 자기특성 및 내식성에 미치는 Cr 첨가 효과)

  • 김태영;강남석;송기창;조삼제;안동훈
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.135-141
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    • 1994
  • With the variation of Cr content and $N_2$ flow ratio, the soft magnetic properties, corrosion resistance and reactivity of the sputtered nanocrystalline FeZrCrN thin flims were investigated. In case of FeZrCrN thin films, a saturation magnetization was decreased with increasing $N_2$ flow ratio. In addition, good soft magnetic properties were obtained at the flow ratio of 3% $N_2$. The $Fe_{64.9}Zr_{8.8}Cr_{5.8}N_{20.5}$ nanocrystalline thin film after annealing at $550^{\circ}C$ exhibited the saturation magnetization of 12.5kG, low coercivity of 0.4 Oe and high permeability of 2600 at 5 MHz. Films containing up to 7.5% Cr showed an enhanced corrosion resistance and reduced reactivity with the bonding glass without degradation of soft magnetic properties, although the saturation magnetization was decreased slightly with the Cr addtion.

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Influence of Gas Composition and Treatment Time on the Surface Properties of AISI 316L Austenitic Stainless Steels During Low-Temperature Plasma Nitrocarburizing Treatment (AISI 316L강의 저온 플라즈마침질탄화처리 시 가스조성과 처리시간이 표면특성에 미치는 영향)

  • Lee, In-Sup
    • Korean Journal of Metals and Materials
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    • v.47 no.11
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    • pp.716-721
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    • 2009
  • The major drive for the application of low-temperature plasma treatment in nitrocarburizing of austenitic stainless steels lies in improved surface hardness without degraded corrosion resistance. The low-temperature plasma nitrocarburizing was performed in a gas mixture of $N_{2}$, $H_{2}$, and carbon-containing gas such as $CH_{4}$ at $450^{\circ}C$. The influence of the processing time (5~30 h) and $N_{2}$ gas composition (15~35%) on the surface properties of the nitrocarburized layer was investigated. The resultant nitrocarburized layer was a dual-layer structure, which was comprised of a N-enriched layer (${\gamma}_N$) with a high nitrogen content on top of a C-enriched layer (${\gamma}_C$) with a high carbon content, leading to a significant increase in surface hardness. The surface hardness reached up to about $1050HV_{0.01}$, which is about 4 times higher than that of the untreated sample ($250HV_{0.01}$). The thickness of the hardened layer increased with increasing treatment time and $N_{2}$ gas level in the atmosphere and reached up to about $25{\mu}m$. In addition, the corrosion resistance of the treated samples without containing $Cr_{2}N$ precipitates was enhanced than that of the untreated samples due to a high concentration of N on the surface. However, longer treatment time (25% $N_{2}$, 30 h) and higher $N_{2}$ gas composition (35% $N_{2}$, 20 h) resulted in the formation of $Cr_{2}N$ precipitates in the N-enriched layer, which caused the degradation of corrosion resistance.

Relationship between the Tidal Range in Sea Level and Damage of Domestic Port Facility (해수면 조위차와 항만시설물의 손상과의 관계 분석)

  • Binna Lee;Jong Suk Lee;Sung Jin Lee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.6
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    • pp.55-61
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    • 2023
  • In this study, a basic research was conducted to establish a maintenance plan considering the environmental factors and deterioration characteristics of port facilities. The precise safety diagnosis reports for Incheon and Busan port facilities were referenced to examine the extent of deterioration and damage. The relationship with the degradation environmental assessment presented in the current guidelines was also analyzed. The analysis of the damage level of Incheon and Busan port facilities revealed that Incheon Port exhibited approximately three times higher damage rate compared to Busan Port. In the case of Incheon Port, reinforcement corrosion and external damage showed similar proportions, while in Busan Port, reinforcement corrosion had a higher proportion compared to external damage. On the other hand, when comparing with the degradation environmental assessment presented in the guidelines, it was found that there were some limitations in performing quantitative evaluation based on the guidelines for assessing port facilities. Therefore, an analysis based on tidal range was conducted by referring to existing literature. The analysis of tidal range in Incheon and Busan regions showed that Incheon had approximately five times higher difference compared to Busan. It is considered that this can be utilized as a differentiated item from existing degradation environmental assessment criteria.

Analysis of Degradation Phenomena in Arc-Tube of Ceramic Metal Halide Lamp (세라믹 메탈할라이드 램프의 아크튜브 열화현상 분석)

  • Kim, Woo-Young;Lee, Se-Il;Yang, Jong-Kyung;Jang, Hyeok-Jin;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.996-1001
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    • 2010
  • Recently, the demand of ceramic metal halide lamp has been expanded. Therefore, the lamp with high efficiency and long lifetime are increasing and the evaluation of reliability is needed. In this paper, the degradation phenomena of ceramic metal halide lamp was studied. The lamp was tested for 3000 on/off cycles with each cycle having a duration of 20 minutes on and 20 minutes off based on the accelerated aging experiment based on "Reliability Standards RS C 0085". As result, the corrosion of arc tube and leak was appeared from reaction between inner wall of PCA and chemical elements, and distortion of electrode was resulted from difference of thermal expansion between arc tube of PCA and electrode. Also, the efficiency of lamp was decreased by the change of inner pressure, operation temperature, and driving voltage from wall blackening.

Impact of multiple component deterioration and exposure conditions on seismic vulnerability of concrete bridges

  • Ghosh, Jayadipta;Padgett, Jamie E.
    • Earthquakes and Structures
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    • v.3 no.5
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    • pp.649-673
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    • 2012
  • Recent studies have highlighted the importance of accounting for aging and deterioration of bridges when estimating their seismic vulnerability. Effects of structural degradation of multiple bridge components, variations in bridge geometry, and comparison of different environmental exposure conditions have traditionally been ignored in the development of seismic fragility curves for aging concrete highway bridges. This study focuses on the degradation of multiple bridge components of a geometrically varying bridge class, as opposed to a single bridge sample, to arrive at time-dependent seismic bridge fragility curves. The effects of different exposure conditions are also explored to assess the impact of severity of the environment on bridge seismic vulnerability. The proposed methodology is demonstrated on a representative class of aging multi-span reinforced concrete girder bridges typical of the Central and Southeastern United States. The results reveal the importance of considering multiple deterioration mechanisms, including the significance of degrading elastomeric bearings along with the corroding reinforced concrete columns, in fragility modeling of aging bridge classes. Additionally, assessment of the relative severity of exposure to marine atmospheric, marine sea-splash and deicing salts, and shows 5%, 9% and 44% reduction, respectively, in the median value bridge fragility for the complete damage state relative to the as-built pristine structure.

Effect of Acid Treatment of Graphitized Carbon on Carbon Corrosion in Polymer Electrolyte Membrane Fuel Cells (결정성 탄소의 산처리가 고분자연료전지의 성능과 내구성에 미치는 영향 평가)

  • Oh, Hyung-Suk;Han, Hak-Soo;Kim, Han-Sung
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.181-188
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    • 2009
  • Pt catalyst was adsorbed on Carbon nanofiber (CNF) by modified polyol method after acid treatment of the carbon support with $HNO_3$ and $H_{2}SO_{4}$. As the time for acid treatment increases, more oxygen functional groups on carbon surface were produced which improve the loading amount and dispersion of Pt catalyst on carbon supports. In order to inspect the effect of CNF acid treatment time on electrochemical corrosion, constant potential of 1.4 V was applied to a single cell for 30 min and the amount of $CO_2$ emitted was monitored with on-line mass spectrometry. According to the results of our experiment, more $CO_2$ was produced with Pt/ oxidized-CNF catalyst in compared to that with unoxidized-CNF. Increasing acid treatment time also induces the more $CO_2$ emission. Besides, performance degradation after corrosion test expanded with severer carbon corrosion. From the observed results, it can be concluded that the acid treatment of CNF is beneficial to catalyst loading, but it also is a significant factor declining the fuel cell durability by accelerating electrochemical oxidation of carbon support.

The Corrosion Behavior of Cold-Rolled 304 Stainless Steel In Salt Spray Environments (염분분사환경에서 냉연 304 스테인레스강의 부식거동)

  • Chiang, M.F.;Young, M.C.;Huang, J.Y.
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.2
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    • pp.93-98
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    • 2011
  • Saline corrosion is one of the major degradation mechanisms for stainless steel type 304 (SS304) dry storage cask during the spent fuel interim storage period. Slow strain rate test (SSRT) and neutral salt spray test (NSS) were performed at $85^{\circ}C$ and $200^{\circ}C$ with 0.5 wt% sodium chloride mist sprayed on the cold-rolled SS304 specimens of different degrees of reduction in this study. The weight changes of the NSS specimens tested at $85^{\circ}C$ for 2000 hours differed greatly from those at $200^{\circ}C$. The weight loss of NSS specimens was not significant at $85^{\circ}C$ but the weight gain decreased gradually with increasing the cold-rolled reduction. The yield strength (YS) and ultimate tensile stress (UTS) values obtained from the SSRT tests for lightly cold-rolled specimens in the salt spray environment at $85^{\circ}C$ and $200^{\circ}C$ are slightly lower than in air. But for those with 20% reductions, the specimen strengths were no longer changed by the saline corrosion. The preliminary results demonstrated that the quality and performance of cold-rolled SS304 is acceptable for fabrication of dry storage casks. However, more work on the corrosion behavior of cold-rolled stainless steel in the saline atmosphere is needed to better understand its long-term performance.