• Title/Summary/Keyword: Corrosion Damage

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Corrosion Evaluation of Epoxy-Coated Bars by Electrochemical Impedance Spectroscopy

  • Choi, Oan-Chul;Park, Young-Su;Ryu, Hyung-Yun
    • International Journal of Concrete Structures and Materials
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    • v.2 no.2
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    • pp.99-105
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    • 2008
  • Southern exposure test specimens were used to evaluate corrosion performance of epoxy-coated reinforcing bars in chloride contaminated concrete by electrochemical impedance spectroscopy method. The test specimens with conventional bars, epoxy-coated bars and corrosion inhibitors were subjected 48 weekly cycles of ponding with sodium chloride solution and drying. The polarization resistance obtained from the Nyquist plot was the key parameter to characterize the degree of reinforcement corrosion. The impedance spectra of specimens with epoxy-coated bars are mainly governed by the arc of the interfacial film and the resistance against the charge transfer through the coating is an order of magnitude higher than that of the reference steel bars. Test results show good performance of epoxy-coated bars, although the coatings had holes simulating partial damage, and the effectiveness of corrosion-inhibiting additives. The corrosion rate obtained from the impedance spectroscopy method is equivalent to those determined by the linear polarization method for estimating the rate of corrosion of reinforcing steel in concrete structures.

Study on Environment Corrosion Characteristics of Automobile Component Materials (차량용 부품재료의 환경부식 특성 연구)

  • Park, Keyoung-Dong;Shin, Yeong-Jin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.5 no.3
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    • pp.86-91
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    • 2006
  • The compressive residual stress, which is inducing by shot peening process, has the effect of increasing the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, it was not known that the effect of shot peening in corrosion environment. In this study, the influence of shot peening and corrosion condition for corrosion property were investigated on immersed in 3.5% NaCl, 10% HNO3 + 3% HF, 6% $FeCl_3$. The immersion test was performed with two kind of specimen. The immersion periods was performed 150days. Corrosion potential, weight loss were investigated from experimental results. From test results, the effect of shot peening on the corrosion characteristics was evaluated.

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A Study on the Temporal Correlation of Long-term Exposure Test and Accelerated Corrosion Test of Rebar (장기폭로 시험과 철근 부식 촉진시험의 시간적 상관성에 관한 연구)

  • Lee, Min-Woo;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.307-313
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    • 2014
  • Recent interest in the increased structural performance and durability evaluation of this concrete structure in a salt damage environment is increasing. The most secure and reliable method of accelerated corrosion test is a method to carry out the rebar corrosion monitoring can be exposed directly to the marine test site exposure. However, long-term exposure testinghas the disadvantage that a long period is necessary. So, a lot of research on RC of salt damage environment have beenpromoted as alternatives to replace this. However, accelerated corrosion test, in the short term only is appropriate and is but an accelerated test method to evaluate the critical chlorine concentration, there is a difficult problem that you still get the answer. It is one of the correlation problems accelerated test correspond to a certain period of exposure environment. Therefore, in this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived.

Corrosion Characteristics of Corrosion-Resistant Metal with Different Composition Ratios of Acetic Acid and Acetonitrile at High Temperature and Pressure (고온 및 고압조건에서 아세트산과 아세토나이트릴의 성분비에 따른 부식저항성 금속의 부식특성)

  • Hyun-Kyu Hwang;Dong-Ho Shin;Seung-Jun Lee;Seong-Jong Kim
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.154-165
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    • 2024
  • Acetic acid and acetonitrile produced in the chemical process of petrochemical plants are used at high temperatures and pressures. They are exposed to harsh corrosive environments. The present investigation aimed to evaluate corrosion characteristics of metals with excellent corrosion resistance by performing immersion and electrochemical experiments with different composition ratios of acetic acid and acetonitrile in a high-temperature and high-pressure environment. Results of immersion experiment revealed that as acetic acid concentration increased, surface damage and corrosion also increased. In immersion experiments under all conditions, super austenitic stainless steel (UNS N08367) had the best corrosion resistance among various metals. The maximum damage depth under the most severe immersion conditions was observed to be 4.19 ㎛, which was approximately 25.25 ㎛ smaller than that of highly damaged stainless steel (UNS S31804). As a result of electrochemical experiments, electrochemical characteristics of various metals presented some differences with different composition ratios of acetic acid and acetonitrile. However, super austenitic stainless steel (UNS N08367) had the best corrosion resistance at a high pressure condition with a high concentration of acetic acid.

Effect of flow velocity on corrosion rate and corrosion protection current of marine material (해양 금속재료의 부식속도와 방식전류에 미치는 유속의 영향)

  • Lee, Seong Jong;Han, Min Su;Jang, Seok Ki;Kim, Seong Jong
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.226-231
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    • 2015
  • In spite of highly advanced paint coating techniques, corrosion damage of marine metal and alloys increase more and more due to inherent micro-cracks and porosities in coatings formed during the coating process. Furthermore, flowing seawater conditions promote the breakdown of the protective oxide of the materials introducing more oxygen into marine environments, leading to the acceleration of corrosion. Various corrosion protection methods are available to prevent steel from marine corrosion. Cathodic protection is one of the useful corrosion protection methods by which the potential of the corroded metal is intentionally lowered to an immune state having the advantage of providing additional protection barriers to steel exposed to aqueous corrosion or soil corrosion, in addition to the coating. In the present investigation, the effect of flow velocity was examined for the determination of the optimum corrosion protection current density in cathodic protection as well as the corrosion rate of the steel. It is demonstrated from the result that the material corrosion under dynamic flowing conditions seems more prone to corrosion than under static conditions.

Cause Analysis for a Lining Damage in Sea Water System Piping Installed in a Korean Industrial Plant

  • Hwang, K.M.;Park, S.K.
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.1-6
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    • 2021
  • Many Korean industrial plants including nuclear and fossil power plants use seawater as the ultimate heat sink to cool the heat generated by various facilities. Owing to the high corrosivity of seawater, facilities and piping made of metal material in contact with seawater are coated or lined with polymeric materials to avoid direct contact with seawater. However, polymeric materials used as coating and lining have some level of permeability to water and are degraded over time. Korean industrial plants have also experienced a gradual increase in the frequency of damage to pipes in seawater systems due to prolonged operating periods. In the event of a cavitation-like phenomenon, coating or lining inside the piping is likely to be damaged faster than expected. In this paper, the cause of water leakage due to base metal damage caused by the failure of the polyester lining in seawater system piping was assessed and the experience with establishing countermeasures to prevent such damage was described.

Evaluation of Relative Corrosion Rate depending on Local Location and Installation of Structural Member in Steel Water Gate (강재 수문의 부재 위치 및 설치 방향에 따른 상대 부식속도 평가)

  • Ha, Min-Gyun;Jeong, Young Soo;Park, Seung hun;Ahn, Jin-Hee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.16-24
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    • 2019
  • The corrosion amounts of steel structures can be different depending on their installation condition and height. Thus, their corrosion maintenance should be considered depending on installation conditions of local structural members. In this study, an atmospheric exposure test was conducted to evaluate the corrosion amount and the corrosion rate depending on the installation condition and height of a steel water gate using monitoring steel plates and corrosion environment measuring sensors. The mean corrosion depth was evaluated using the weight loss method and the galvanic corrosion current was measured by corrosion environment measuring sensors. Local corrosion rate of local structural member in steel water gate was estimated using measured mean corrosion depths and galvanic corrosion currents. From this measurement results, the corrosion damage in horizontal member of the cross beam was highly evaluated than those of other structural member as skin plate, etc. The relative difference in the corrosion rate of a local structural member could be highly affected by local corrosion environments of steel water gate members. Therefore, an appropriate maintenance method should be considered for local corrosion damages of local structural members determined by local corrosion environments of a steel water gate.

Dual potential capacity model for predicting failure of RC beams damaged by corrosion of tensile reinforcement

  • Sun-Jin Han;Deuckhang Lee;Hyo-Eun Joo;Kang Su Kim
    • Computers and Concrete
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    • v.34 no.4
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    • pp.503-517
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    • 2024
  • This study presents an analysis model to estimate the shear strength of a reinforced concrete (RC) member with corroded tensile reinforcements. The thick-walled cylinder theory was modified to fit the dual potential capacity model to reflect interdependent failure mechanisms, including the degradation effect of bonds in corroded tensile reinforcement. In the proposed model, it is considered that the shear failure of corroded RC members with no proper anchorage detail is primarily dominated by the flexural-bond mechanism, where insufficient bond strength is provided owing to corrosion damage. However, when tensile reinforcements are properly anchored in the end regions using end hooks or mechanical devices, it is assumed that the tied-arch action can be developed as a secondary shear transfer mechanism, even under severe corrosion damage. The proposed model was verified by comparison with shear test results of corroded RC members collected from the literature, and it appeared that the proposed model can estimate their shear strengths with a good level of accuracy, regardless of various anchorage details and corrosion rates in tensile reinforcements.

Corrosion Resistance of SD460 Reinforcing Rod by Ceramic Coating (SD460 철근의 세라믹 코팅에 의한 내식성 향상연구)

  • Park, Ki Y.;Lee, Jong K.;Hong, Seok W.
    • Corrosion Science and Technology
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    • v.8 no.4
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    • pp.157-161
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    • 2009
  • The corrosion resistance of reinforcing bar was studied to endure the marine environment during shipment. The red rust on the surface did not damage the adherence in the concrete structures, especially in highly alkaline environment, but made the consumer doubt of the quality. The passivation process by alkalization of the quenching water in the tempcore process failed to endure the long shipping period. The ceramic coating by sol-gel process improved the corrosion resistance without damaging the mechanical properties and adherence between concrete and reinfiorcing bar. Optimal concentration of the coating solution and coating temperature were tested. No additional energy was necessary for the coating process by spraying during cooling process, resulting simplified process and low cost. Salt spray test, cyclic corrosion test and atmospheric test were employed to confirm the resistance. The corrosion rates were presented by rating number and polarization resistance. The coating layer was examined by FIB, XRD and SEM etc.

Investigation on Electrochemical Corrosion and Stress Corrosion Cracking Characteristics of Anodized 5083-H321 Alloy in Natural Seawater (양극산화된 5083-H321 합금의 천연해수 내 전기화학적 부식 및 응력부식균열 특성에 관한 연구)

  • Hwang, Hyun-kyu;Shin, Dong-Ho;Jung, Kwang-Hu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.19 no.5
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    • pp.259-264
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    • 2020
  • Many studies have been conducted to improve the corrosion resistance and durability of various aluminum alloys through the anodizing technique. It is already used as a unique technique for enhancing the properties of aluminum alloys in various industries. This paper investigated the electrochemical corrosion and stress corrosion cracking characteristics of anodized aluminum 5083-H321 alloy in natural seawater. The corrosion characteristics were assessed by the electrochemical technique and potentiodynamic polarization test. The stress corrosion cracking characteristic was evaluated with a slow strain rate tensile test under 0.005 mm/min rate, which showed that the hard anodizing film had a thickness of about 16.8 ㎛. Although no significant characteristics of stress corrosion cracking were observed in the slow strain rate test, the anodized specimen presented excellent corrosion resistance. The corrosion current density was measured to be approximately 4.2 times lower than that of the base material, and no surface damage was observed in the anodic polarization test.