• Title/Summary/Keyword: Corrosion Condition

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A Study on the Effect of Corrosion Resistance According to the Composition Variety of C, Cr, N in Duplex Stainless Steel

  • Kim, Hyeong-Jin;Cho, Kye-Hyun;Jung, Jae-young
    • Corrosion Science and Technology
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    • v.3 no.5
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    • pp.179-186
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    • 2004
  • Recently the alloy development of duplex stainless steel has been done. On this study we studied the effect of the corrosion resistance according to the composition variety of C, Cr, N in the alloy elements of duplex stainless steel. materials which have below 0.1[mm/year] corrosion rate enable to use for corrosion-resisting materials, generally. On this experiment we inspected the effect of the composition variety of C, Cr, N in duplex stainless steel and the heat treatment, which the condition was the water quenching after the heat treatment for 1hr. The experiment was done on the basis of the ASTM G48A test, Critical pitting temperature(CPT), and ASTM G-61(Electrochemical tests for cyclic polarization).

Corrosion Resistance of the Roll Formed Steel Bolts with the Various Types of Coating Methods (1) (다양한 코팅 방법에 따른 전조한 강 볼트의 내부식성 (1))

  • Mamatov, S.;Hamrakulov, B.;Son, Y.H.;Kim, I.
    • Transactions of Materials Processing
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    • v.28 no.2
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    • pp.71-76
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    • 2019
  • Corrosion resistance is one of the essential properties required in steel bolts. The various types of coatings are used to improve the corrosion resistance of steel bolts. But, roll formed, subsequently Zn alloy electrodeposited and top coated steel bolt easily takes place the white storage stain or white rust under high humidity condition. To investigate the corrosion resistance of roll formed and subsequently the various types of coated steel bolts, their polarization curves were measured by potentio-dynamic tester in this study. Based on the measured polarization curves, the more times of chromate and top coating on roll formed steel bolt, the higher corrosion resistance was shown. The roll formed steel bolt, which was Zn-Ni electro-deposited, two times chromated, one time inorganic top coated, one time organic top coated and annealed, showed the best corrosion resistance.

Assessment of external corrosion deterioration of large diameter metallic water pipes buried in reclaimed land (간척지대에 매설된 대구경 금속관의 외면 부식손상 평가)

  • Lee, Ho-Min;Choi, Tae-Ho;Kim, Jung-Hyun;Bae, Cheol-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.5
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    • pp.373-383
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    • 2020
  • The purpose of this study was to evaluate the corrosion damage of large diameter metallic pipes buried in reclaimed land due to the corrosion effect by soil, and to propose a method of installing metal pipes in the reclaimed land. The results are as follow. First, the soil of the reclaimed land was gray clay, the soil specific resistance indicating soil corrosiveness was at least 120 Ω-cm, the pH was weakly acidic(5.04 to 5.60), the redox potential was at least 62 mV, the moisture content was at most 48.8%, and chlorine ions and sulfate ions were up to 4,706.1 mg/kg and 420 mg/kg. Therefore, the overall soil corrosivity score was up to 19, and the external corrosion effect seems to be very large. Second, the condition of straight part of pipes was in good condition, but most of KP joints were affected by corrosion at a severe level. The reason for this seems to be that KP joints accelerated corrosion due to stress and crevice corrosion in addition to galvanic corrosion in the same environment. Third, as a result of evaluating correlations of each item that affects the corrosion on the external part, the lower the soil resistivity and redox potential, the greater the effect on the KP joints corrosion, and the moisture content, chloride ion, and sulfate ion, the higher the value, the greater the effect on the corrosion of KP joints. In addition, among soil corrosion items, the coefficient of determination of soil resistivity with corrosion of KP joints was the highest with 0.6439~0.7672. Fourth, when installing metal pipes or other accessories because the soil of the reclaimed land is highly corrosive, it is necessary to apply a corrosion preventive method to extend the life of pipes and prevent leakage accidents caused by corrosion damage to the joint.

The Evaluation of the Stress Corrosion Cracking for Improvement of Reliability in Turbine Operation and Maintenance (터빈 운전 신뢰성 향상을 위한 응력부식균열 평가)

  • Kang, Yong-Ho;Song, Jung-Il
    • 한국태양에너지학회:학술대회논문집
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    • 2008.11a
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    • pp.280-287
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    • 2008
  • In case of low pressure steam turbine used in power plant, it was operated in wet steam and high stress condition. Therefore, it is possible that the corrosion damage of low pressure was induced by this condition. According to previous study, about 30% of total blade failure correspond to corrosion fatigue or SCC(stress corrosion cracking) in low pressure turbine. Especially, LSB(last stage bucket) of low pressure turbine has a higher hardness to prevent erosion damage due to water droplet however, generally this is more dangerous for SCC damage. Therefore, to improve reliability of turbine blade. various methods for SCC evaluation has been developed. In this study, the crack found in LSB during in-service inspection was evaluated using microstructure analysis and stress analysis. From the stress analysis, the optimum size of fillet to remove the crack was proposed. And also, the reliability was evaluated for modified LSB using GOODMAN diagram.

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Effect of Ultrasonic Process of Electroless Ni-P-Al2O3 Composite Coatings

  • Yoon, Jin-Doo;Koo, Bon-Heun;Hwang, Hwan-Il;Seo, Sun-Kyo;Park, Jong-Kyu
    • Journal of the Korean institute of surface engineering
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    • v.54 no.6
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    • pp.315-323
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    • 2021
  • In general, surface treatments of electroless Ni-P coating are extensively applied in the industry due to their excellent properties for considerable wear resistance, hardness, corrosion resistance. This study aims to determine the effect of ultrasonic conditions on the morphology, alumina content, roughness, hardness, and corrosion resistance of electroless Ni-P-Al2O3 composite coatings. The characteristics were analyzed by Energy-dispersive X-ray spectroscopy (EDX), x-ray diffractions (XRD), and atomic force microscopy (AFM), etc. In this study, the effect of ultrasonic condition uniformly distributed alumina within Ni-P solution resulting in a smoother surface, lower surface roughness. Furthermore, the corrosion resistance behavior of the coating was analyzed using tafel polarization curves in a 3.5 wt.% NaCl solution at 25 ℃. Under ultrasonic, Al2O3 content in Ni-P composite solution increased from 0.5 to 5.0 g/L, Al2O3 content at 3.0 g/L was showed a significantly enhanced corrosion resistance. These results suggested that ultrasonic condition was an effective method to improve the properties of the composite coating.

Theoretical Considerations of Numerical Model for Hydrogen Diffusion Behavior of High-Strength Steel Under Combined Action of Tensile Stress and H2S Corrosion (인장응력과 H2S 부식의 복합조건 하에서 고강도 강재의 수소확산 거동 분석을 위한 Numerical 확산모델과 이론적 고찰)

  • Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.18 no.3
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    • pp.102-109
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    • 2019
  • The hydrogen diffusion and trapping model with a numerical finite difference method (FDM) was modified and extended to accommodate $H_2S$ corrosion and scale forming processes of high-strength steel under tensile stress condition. The newly proposed diffusion model makes it possible to clearly understand combined effect of tensile stress and $H_2S$ corrosion process on hydrogen diffusion behaviors. The core concept of this theoretical approach is that overall diffusion behavior is separated into diffusion process through two respective layers: an outer sulfide scale and an inner steel matrix. Diffusion coefficient values determined by curve-fitting permeation data reported previously with the newly proposed diffusion model indicate that the application of tensile stress can contribute to continual increase in the diffusivity in the sulfide scale with a high density of defect. This suggests that the scale with a lower stability under the stress condition can be a key parameter to enhance hydrogen influx in the steel matrix. Consequently, resistance to hydrogen assisted cracking of the steel under tensile stress can be decreased significantly.

Investigation of Optimum Cathodic Protection Potential to Prevent Erosion with a Flow Rate of AA5083-H321 for Marine Vessels (선박용 AA5083-H321의 유속에 의한 침식손상 방지를 위한 최적 음극방식전위 규명)

  • Chong, Sang-Ok;Park, Il-Cho;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.19 no.6
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    • pp.288-295
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    • 2020
  • This study investigated the erosion-corrosion characteristics of 5038-H321 aluminum alloy in a natural seawater solution through various electrochemical experiments and flow rate parameters. Cathodic polarization experiments were conducted at flow rates ranging from 4 to 12 knots. Considering the concentration polarization section representing a relatively low current density, the range of the potentiostatic experiment was determined to be -1.6 to -1.0 V. The potentiostatic experiment was conducted at various potentials for 180 minutes in seawater. After the experiment, the corrosion characteristics were evaluated by observing surface morphology and measuring surface roughness. As a result, as the applied potential was lower, the amount of calcareous deposits increased and the roughness tended to increase. On the other hand, it was confirmed that the roughness was larger in the static condition than the flow rate condition due to the influence of the flow velocity. Variations in the chemical composition with flow rate variations were analyzed by energy-dispersive spectroscopy (EDS). In conclusion, the cathodic potential of AA5083-H321 in seawater was determined to be -1.0 V.

An Electrochemical Method to Predict Corrosion Rates in Soils

  • Dafter, M.R
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.217-225
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    • 2016
  • Linear polarization resistance (LPR) testing of soils has been used extensively by a number of water utilities across Australia for many years now to determine the condition of buried ferrous water mains. The LPR test itself is a relatively simple, inexpensive test that serves as a substitute for actual exhumation and physical inspection of buried water mains to determine corrosion losses. LPR testing results (and the corresponding pit depth estimates) in combination with proprietary pipe failure algorithms can provideauseful predictive tool in determiningthe current and future conditions of an asset. Anumber of LPR tests have been developed on soil by various researchers over the years1), but few have gained widespread commercial use, partly due to the difficulty in replicating the results. This author developed an electrochemical cell that was suitable for LPR soil testing and utilized this cell to test a series of soil samples obtained through an extensive program of field exhumations. The objective of this testing was to examine the relationship between short-term electrochemical testing and long-term in-situ corrosion of buried water mains, utilizing an LPR test that could be robustly replicated. Forty-one soil samples and related corrosion data were obtained from ad hoc condition assessments of buried water mains located throughout the Hunter region of New South Wales, Australia. Each sample was subjected to the electrochemical test developed by the author, and the resulting polarization data were compared with long-term pitting data obtained from each water main. The results of this testing program enabled the author to undertake a comprehensive review of the LPR technique as it is applied to soils and to examine whether correlations can be made between LPR testing results and long-term field corrosion.

Characteristics of Bond Strength as Types of Primer for the Facilities of Anti-corrosion Waterproofing Materials by the Reversed Pressure and Concrete Surface Condition (내부 방수⋅방식재의 프라이머 종류별 역수압 작용 및 콘크리트 표면 상태에 따른 부착강도 특성)

  • Oh, Sang-Keun;Heo, Neung-Hoe;Shin, Hong-Chul;Choi, Sung-Min
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.1
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    • pp.68-74
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    • 2014
  • Recently, concrete facility as advanced water treatment facilities is extending in the water treatment facilities according to raise awareness of pure drinking water and delicious water. For this reason, it is increased to the necessity need to make the standard and the development of waterproofing and anti-corrosion materials for concrete structures applied water treatment tank. So, related research has become active recently. However, as the limit of research focused on durability improvement of top coating material, it is insufficient to study on the adhesion strength between the concrete surface and primer. Therefore, there is to confirm the adhesion of between concrete surface and the three primers used as anti-corrosion waterproofing materials, and to investigate the properties of adhesion strength according to the condition such as dry condition, wet condition, and water pressure condition of the concrete surface in this study.

The Relationship Between Hydrogen Trapping Behavior and SSCC Suceptibility of API X60/65 Grade Steels

  • Lee, Jae Myung;Kim, Jin Suk;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.109-116
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    • 2003
  • It is well known that SSCC (sulfide stress corrosion cracking) is caused by drastic ingression of hydrogen during the service and accumulation of hydrogen near the potential crack initiation site in the material. It is important to characterize the hydrogen trapping behavior to evaluate the service performance of the high strength pipeline steels. In this study. the relationship between the hydrogen trapping behavior and SSCC susceptibility is evaluated in terms of alloy composition, microstructure and carbide behavior. The hydrogen trapping behavior was measured by electrochemical hydrogen permeation test cell (Devanathan cell). The SSCC susceptibility is evaluated by constant extension rate test and constant strain lest method. The hydrogen trapping behavior is affected greatly by microstructure and nature of carbide particles. The fine TiC, and NbC in the matrix of ferritic structure acts as strong irreversible trap sites whereas the bainitic structure acts as reversible trap site. The SSCC susceptibility is closely related to not only the hydrogen trapping behavior but also the loading condition. As the activity of reversible trap site increases, SSCC susceptibility decreases under static loading condition below yield strength, whereas SSCC susceptibility increases under dynamic loading condition or above yield strength. As the activity of irreversible trap site increases. SSCC susceptibility increases regardless of loading condition. It is cased by the mixed effect of dislocation on hydrogen diffusion and trapping behavior.