• Bulletin of the Korean Chemical Society
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• v.29 no.1
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• pp.33-37
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• 2008

A phenomenological theory of viscosity previously proposed by the present authors8 is applied to the corresponding state theory for the viscosity of liquid. Through the process of the formulation of the corresponding state equation, we can find the simple viscosity equation with no parameters in a reduced form. The liquid viscosities of various substances can be calculated using this equation when we know only the values of the molecular weight and critical constant of substances. A corresponding state equation for the viscosity of liquid from this theory may be applicable to predicting viscosities of various substances under varying temperature and pressure. As a result, this equation may be widely applied to chemical engineering.

• Earthquakes and Structures
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• v.8 no.1
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• pp.101-132
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• 2015

This research formulates a closed-form equation to predict a glass panel cracking failure drift for several curtain wall and storefront systems. An evaluation of the ASCE 7-10 equation for Dclear, which is the drift corresponding to glass-to-frame contact, shows that the kinematic modeling assumed for formulation of the equation is sound. The equation proposed in this paper builds on the ASCE equation and offers a revision of that equation to predict drift corresponding to cracking failure by considering glazing characteristics such as glass type, glass panel configuration, and system type. The formulation of the proposed equation and corresponding analyses with the ASCE equation is based on compiled experimental data of twenty-two different glass systems configurations tested over the past decade. A final comparative analysis between the ASCE equation and the proposed equation shows that the latter can predict the drift corresponding to glass cracking failure more accurately.

• Bulletin of the Korean Chemical Society
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• v.7 no.3
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• pp.204-210
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• 1986

It is shown that the linear stability coincides with the thermodynamic stability in the case of stress tensor evolution for simple dense fluids even if the constitutive (evolution) equation for the stress tensor is nolinear. The domain of coincidence can be defined in the space of parameters appearing in the constitutive equation and we find the domain is confined in an elliptical cone in a three-dimensional parameter space. The corresponding state theory in rheology of simple dense fluids is also further examined. The validity of the idea is strengthened by the examination.

• Journal of the Korean Chemical Society
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• v.48 no.3
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• pp.243-248
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• 2004

Brake theory of viscosity, which can sucessfully calculate the viscosity of real gases, dense gases and liquids, is extended to the binary gas mixture. Adjustable parameters are not involved, but the calculated results are good agreements with the experimental values at high pressure as well as low pressure. Corresponding state equation for viscosity can be obtained by using the Redlich-Kwong equation, so that we hope this equation may be useful for the supercritical fluid in engineering applications at high pressure around the critcal point.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.8
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• pp.823-833
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• 2010

For the study of thermophysical properties of kerosene for the liquid rocket and aviation fuels, the surrogate models are investigated. The density distributions based on the real gas equations of state(Soave modification of Redlich-Kwong and Peng-Robinson equation of state) and NIST SUPERTRAPP(extended corresponding state principle) are compared with the previous experimental results at supercritical conditions. The error range of thermophysical properties analyzed for the surrogate models as well. Peng-Robinson equation of state and extended corresponding state principle are especially accurate for the hydrocarbon fuels but the appropriate surrogate models need to be chosen to the operation conditions such as pressure and temperature.

• Bulletin of the Korean Chemical Society
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• v.9 no.1
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• pp.36-40
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• 1988

The time correlation functions of concentration fluctuations due to the random forces near the steady state are evaluated for a general two-component nonlinear chemical system by solving the corresponding two dimensional Fokker-Planck equation. The approximate method of solving the Fokker-Planck equation is based on the eigenfunction expansion and the corresponding eigenvalues for both the linear and nonlinear Fokker-Planck operators are obtained near the steady state. The general results are applied to the Lotka model near the oscillatory marginal steady state and the comparison is made between linear and nonlinear cases.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.3
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• pp.39-51
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• 2010

Theoritical principles about the real gas equation of state are investigated and comparisons for the thermophysical properties of oxygen, hydrogen, and methane as the propellants of liquid rocket engine are carried out for the various conditions of pressure and temperature including supercritical conditions. The properties obtained using the real gas equation of state(Soave modification of Redlich-Kwong, Peng-Robinson equation of state, and extended corresponding states principle) have been compared with the results of applying the ideal gas equation of state. Differences of thermophysical properties among the models specifically at the liquid phase regime and their error ranges are addressed.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3443-3446
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• 2014

We present the solution of Klein Gordon equation with new generalized Morse-like potential using SUSYQM formalism. We obtained approximately the energy eigenvalues and the corresponding wave function in a closed form for any arbitrary l state. We computed the numerical results for some selected diatomic molecules.

• East Asian mathematical journal
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• v.24 no.4
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• pp.407-414
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• 2008

Finite difference schemes are considered for a $Ca^{2+}$ diffusion equations with damping and convection terms, which describe $Ca^{2+}$ buffering by using stationary and mobile buffers. Stability and $L^{\infty}$ error estimates of approximate solutions for the corresponding schemes are obtained using the extended Lax-Richtmyer equivalence theorem.

• Geomechanics and Engineering
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• v.12 no.6
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• pp.983-1001
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• 2017

The extent by which economy and safety concerns can be addressed in earth retaining structure design depends on the accuracy of the assumed failure surface. Accordingly, this study attempts to investigate and quantify mechanical backfill properties that control failure surface geometry of cohesionless backfills at the active state for translational mode of wall movements. For this purpose, a small scale 1 g physical model study was conducted. The experimental setup simulated the conditions of a backfill behind a laterally translating vertical retaining wall in plane strain conditions. To monitor the influence of dilative behavior on failure surface geometry, model tests were conducted on backfills with different densities corresponding to different dilation angles. Failure surface geometries were identified using particle image velocimetry (PIV) method. Friction and dilation angles of the backfill are calculated as functions of failure stress state and relative density of the backfill using a well-known empirical equation, making it possible to quantify the influence of dilation angle on failure surface geometry. As a result, an empirical equation is proposed to predict active failure surface geometry for cohesionless backfills based on peak dilatancy angle. It is shown that the failure surface geometries calculated using the proposed equation are in good agreement with the identified failure surfaces.