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A Corresponding State Theory for the Viscosity of Liquids

  • Kim, Won-Soo (School of Materials Science and Engineering, Hongik University) ;
  • Lee, Suk-Bae (Department of Chemistry, Korea University)
  • Published : 2008.01.20

Abstract

A phenomenological theory of viscosity previously proposed by the present authors8 is applied to the corresponding state theory for the viscosity of liquid. Through the process of the formulation of the corresponding state equation, we can find the simple viscosity equation with no parameters in a reduced form. The liquid viscosities of various substances can be calculated using this equation when we know only the values of the molecular weight and critical constant of substances. A corresponding state equation for the viscosity of liquid from this theory may be applicable to predicting viscosities of various substances under varying temperature and pressure. As a result, this equation may be widely applied to chemical engineering.

Keywords

References

  1. Chapman, S.; Cowling, T. G. The Mathematical Theory of Nonuniform Gases; Cambridge University Press: 1939; chapter 16
  2. Kirkwood, J. G. J. Chem. Phys. 1946, 14, 180 https://doi.org/10.1063/1.1724117
  3. Born, M.; Green, H. S. A General Kinetic Theory of Liquids; University Press: Cambridge, 1949
  4. Prigogine, I.; Nicolis, G.; Misgusih, J. J. Chem. Phys. 1966, 45, 1086 https://doi.org/10.1063/1.1727719
  5. Berne, B. J.; Boon, J. P.; Rice, S. A. J. Chem. Phys. 1966, 45, 1086 https://doi.org/10.1063/1.1727719
  6. Andrade, E. N. Phil. Mag. 1934, S7 17, 497
  7. Eyring, H. J. Chem. Phys. 1961, 34, 2144 https://doi.org/10.1063/1.1731836
  8. Kim, W.; Chair, T. S. Bull. Korean Chem. Soc. 1988, 9, 214
  9. Chair, T. S.; Kim, W.; Pak, H.; Jhon, M. S. Korean J. of Chem. Eng. 1989, 6, 121 https://doi.org/10.1007/BF02697489
  10. Kim, W.; Chair, T. S. Bull. Korean Chem. Soc. 1990, 11, 447
  11. Kim, W.; Chair, T. S. Korean J. of Chem. Eng. 1993, 10, 124 https://doi.org/10.1007/BF02697404
  12. Kim, W.; Chair, T. S. J. Korean Chem. Soc. 1997, 41, 52
  13. Kim, W.; Chair, T. S. Bull. Korean Chem. Soc. 2002, 23, 1524 https://doi.org/10.5012/bkcs.2002.23.11.1524
  14. Kim, W. J. Korean Chem. Soc. 2004, 48, 243 https://doi.org/10.5012/jkcs.2004.48.3.243
  15. Kim, W.; Chair, T. S. Bull. Korean Chem. Soc. 2001, 22, 43
  16. Bird, R. B. Transport Phenomena; John Wiley & Sons, Inc.: 1960; p 744
  17. Poling, B. E.; Prausnitz, J. M.; O'connell, J. P. The Properties of Gases and Liquids, 5rd ed.; MacGraw-Hill: New York, 2001
  18. Lucas, K. Chem. Ing. Tech. 1981, 53, 959 https://doi.org/10.1002/cite.330531209

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  1. A new fragment contribution-corresponding states method for physicochemical properties prediction of ionic liquids vol.59, pp.4, 2012, https://doi.org/10.1002/aic.13910