• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3597-3601
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• 2013

The reactions of bis(Y-aryl) chlorothiophosphates (1) with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The Hammett plots for substituent Y variations in the substrates show biphasic concave upwards with a break point at Y = H. The cross-interaction constants (${\rho}_{XY}$) are positive for both electron-donating and electron-withdrawing Y substituents. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorothiophosphates (2). The cross-interaction between Y and Y, due to additional substituent Y, is significant enough to result in the change of the sign of ${\rho}_{XY}$ from negative with 2 to positive with 1. The effect of the cross-interaction between Y and Y on the rate changes from negative role with electron-donating Y substituents to positive role with electron-withdrawing Y substituents, resulting in biphasic concave upward free energy correlation with Y. A stepwise mechanism with a rate-limiting leaving group departure from the intermediate involving a predominant frontside attack hydrogen bonded, four-center-type transition state is proposed based on the positive sign of ${\rho}_{XY}$ and primary normal deuterium kinetic isotope effects.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4304-4308
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• 2011

Kinetic studies of the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-benzylamines have been carried out in dimethyl sulfoxide at $85.0^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}_X$) and Br$\ddot{o}$nsted [log $k_2$ vs $pK_a$(X)] plots for substituent X variations in the nucleophiles are discrete with a break region between 4-Me and H, while the Hammett plots (log $k_2$ vs ${\sigma}_Z$) for substituent Z variations in the leaving groups are linear. The sign of the cross-interaction constant (${\rho}_{XZ}$) is positive for both the strongly and weakly basic nucleophiles. Greater magnitude of ${\rho}_{XZ}$ (= 2.54) value is observed with the weakly basic nucleophiles compared to with the strongly basic nucleophiles (${\rho}_{XZ}$ = 0.17). The deuterium kinetic isotope effects ($k_H/k_D$) involving deuterated benzylamines [$XC_6H_4CH_2ND_2$] are primary normal ($k_H/k_D$ > 1). The proposed mechanism is a stepwise with a rate-limiting leaving group expulsion from the intermediate involving a frontside nucleophilic attack with a hydrogen bonded, four-center-type transition state for both the strongly and weakly basic nucleophiles.

• Journal of the Korean Home Economics Association
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• v.47 no.1
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• pp.1-12
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• 2009

The purpose of this study was to establish the relative influences of individual variables (sex, age, temperament) and mother's psychosocial variables (maternal attitude, parenting stress, marriage satisfaction) on daily stress levels and maladjustment of young children attending at daycare centers. Subjects were 224 pairs of children and their mothers, and 18 teachers from 5 child-care centers in Gwangju City. Children were tested individually using 22-item daily stress inventory with illustrations which described certain stressful situations. Questionnaires were also administered to mothers and teachers. Collected data were subjected to Cronbach's $\alpha$, correlation and multiple regression analysis using SPSS (WIN 14.0) program. The major findings were as follows; Overall average score of children's daily stress was equivalent with the median. 'Blame and attack situation' and 'anxiety and frustrated situation' were perceived as more stressful for children than 'lose self-respect situation'. Overall average score of children's maladjustment was lower than the median. 'Overactivity' was highest among subscores of maladjustment. Age was the only significant influential factor on children's daily stress level. Sex was the most influential factor on 'overactivity', 'aggression', and 'regression' of young children. Activity and maternal stress were the second most influential factor on 'overactivity' and 'aggression', respectively.

• Journal of the Korean Institute of Landscape Architecture
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• v.27 no.2
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• pp.58-68
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• 1999

This study was carried out to verify the distribution patterns of Salix gracilistyla and Phragmites japonica communities known as obligatory riparian species according to physical factors such as micro-landforms, substrates, etc., at Soo-ip stream corridor. Firstly four vegetation types - Salix gracilistyla dominant type, Phragmites japonica dominant type, mixed type of two species, and mixed type of two species to other species, were classified by cluster analysis based on UPGMA-Euclidean distance. Also these vegetation types showed many different distribution patterns in response to the longitudinal and lateral view along the stream corridor and substrate composition. Salix gracilistyla was major component of dominant vegetation types developed at attack point of bending reach and on substrates composed of rock fragments, but contrastly Phragmites japonica was most important component of dominant vegetation types at point bar of bending reach and floodplain, and on substrates composed of soil materials. Secondly the species and environment biplot form CCA strongly supported the vegetation types divided by classification. Namely Salix gracilistyla was closely correlated with rock fragments and steep slope, which is resistant to physical action even though located near running water. But Phragmites japonica showed a high correlation with soil particles sedimented at floodplain by divergent flow.

• Wind and Structures
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• v.1 no.3
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• pp.225-241
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• 1998

The high-rise supporting towers of long-span suspension and cable-stayed bridges commonly comprise a pair of slender prisms of roughly square cross-section with a center-to-centre spacing of from perhaps 2 to 6 widths and connected by one or more cross-ties. The tower columns may have a constant spacing as common for suspension bridges or the spacing may reduce towards the top of the tower. The present paper is concerned with the aerodynamics of such towers and describes an experimental investigation of the overall aerodynamic forces acting on a pair of square cylinders in two-dimensional flow. Wind tunnel pressure measurements were carried out in smooth flow and with a longitudinal intensity of turbulence 0.10. Different angles of attack were considered between $0^{\circ}$ and $90^{\circ}$, and separations between the two columns from twice to 13 times the side width of the column. The mean values of the overall forces proved to be related to the bias introduced in the flow by the interaction between the two cylinders; the overall rms forces are related to the level of coherence between the shedding-induced forces on the two cylinders and to their phase. Plots showing the variation of the force coefficients and Strouhal number as a function of the separation, together with the force coefficients spectra and lift cross-correlation functions are presented in the paper.

• Bulletin of the Korean Chemical Society
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• v.29 no.4
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• pp.767-771
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• 2008

Second-order rate constants have been measured spectrophotometrically for the Michael-type reaction of 1-(Xsubstituted phenyl)-2-propyn-1-ones (2a-f) with amines in $H_2O$ at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. A linear Brønsted-type plot is obtained with ${\beta}_{nuc}$ = 0.25 ${\pm}$ 0.02, a typical $\beta_{nuc}$ value for reactions which proceed through a stepwise mechanism with attack of amine on the electrophilic center being the rate-determining step. Secondary alicyclic amines are found to be more reactive than isobasic primary amines. The Hammett plot for the reactions of 2a-f with morpholine is not linear, i.e., the substrate with a strong electron-donating group (e.g., 4-MeO) exhibits a negative deviation from the Hammett plot. However, the Yukawa-Tsuno plot for the same reactions exhibits an excellent linear correlation with ρ = 0.62 and r = 0.82. Thus, it has been proposed that the nonlinear Hammett plot is not due to a change in the ra te-determining step but due to ground-state stabilization through resonance interactions.

• The Korean Journal of Ecology
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• v.9 no.4
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• pp.231-241
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• 1986

The annual decomposition of cellulose and hemicellulose by microorganism and distribution of soil microbial flora were investigated in the humus horizon of a Pinus rigida stand in Mt. Kwanak. The cellulase activity was the lowest, 142$\mu$g glucose/g/hr from Dec. 1985 to Mar. 1986 and the highest, 760~1, 072$\mu$g glucose/g/hr in Jul. and Aug. 1985. The xylanase activity was 47% higher than the cellulase activity and was the lowest, 211~275$\mu$g xylose /g/hr from Feb. to Mar. 1986 and the highest as 799~1, 322$\mu$g xylose/g/hr from Jun. to Aug. 1986. The vertical distribution of the enzyme activity was decreased with the order of F, H, L, and A1 in both enzymes and the activities were exponentially decreased below L horizon, which suggests that most decomposition be done in F and H horizons with lots of organic matters. The SEM study slowed that the main decomposers of litters were fungi and initial attack into litters was also made by them. The enzyme activities of soil had strong correlations with the temperature and the precipitation. The correlation coefficients were 0.813 and 0.886 in the cellulase, and 0.673 and 0.626 in the xylanase for the temperature and the precipitation, respectively.

• Journal of the Korean Data and Information Science Society
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• v.25 no.6
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• pp.1221-1229
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• 2014

In this paper we choose the best model among several bivariate Poisson models on Korean soccer data. The models considered allow for correlation between the number of goals of two competing teams. We use an R package called bivpois for bivariate Poisson regression models and the data of K-league for season 1983-2012. Finally we conclude that the best fitted model supported by the AIC and BIC is the bivariate Poisson model with constant covariance. The zero and diagonal inflated models did not improve the model fit. The model can be used to examine home-away effect, goodness of fit, attack and defense parameters.

• Journal of the Korea Institute of Information Security & Cryptology
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• v.16 no.3
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• pp.65-76
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• 2006

This paper deals with an effective algerian aimed at improving the port scan detection in an intrusion detection system (IDS). In particular, a detection correlation algerian is proposed to maximize the detection capability in the network-based IDS whereby the 'misuse' is flagged for analysis to establish intrusion profile in relation to the overall port scan detection process. In addition, we establish an appropriate system maintenance policy for port scan detection as preprocessor for improved port scan in IDS, thereby achieving minimum false positive in the misuse detection engine while enhancing the system performance.

• International Journal of Computer Science & Network Security
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• v.23 no.10
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• pp.129-134
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• 2023

The greatest challenge of this century is the protection of stored and transmitted data over the network. This paper provides a new hybrid algorithm designed based on combination algorithms, in the proposed algorithm combined with Hill and the Advanced Encryption Standard Algorithms, to increase the efficiency of color image encryption and increase the sensitivity of the key to protect the RGB image from Keyes attackers. The proposed algorithm has proven its efficiency in encryption of color images with high security and countering attacks. The strength and efficiency of combination the Hill Chipper and Advanced Encryption Standard Algorithms tested by statical analysis for RGB images histogram and correlation of RGB images before and after encryption using hill cipher and proposed algorithm and also analysis of the secret key and key space to protect the RGB image from Brute force attack. The result of combining Hill and Advanced Encryption Standard Algorithm achieved the ability to cope statistically