• Title/Summary/Keyword: Core polymer

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A Research Trend on Diaphragm Membranes Alkaline Water Electrolysis System (알칼리 수전해용 격리막 기술 연구동향)

  • Im, Kwang Seop;Son, Tae Yang;Jeong, Ha Neul;Kwon, Dong Jun;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.2
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    • pp.133-144
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    • 2021
  • Alkaline water electrolysis system is the oldest technology among various hydrogen production processes to produce green hydrogen with the least amount of greenhouse gas generated. Alkaline water electrolysis (AWE) system is used in alkaline atmosphere condition. In comparison to polymer electrolyte membrane water electrolysis (PEMWE), this system can utilize stable transition metals such as nickel, cobalt, and silver, as electrode catalysts. AWE is relatively inexpensive, and can easily be scaled up to large scale. The system is a mature technology, as it has been in operation since the beginning of the 20th century in MW-scale for hydrogen generation, and there are currently more than 20 commercial manufacturers. In this review, the basic principles of AWE, along with catalysts, electrodes, and diaphragm membranes, are summarized. Particularly, the research and development trends of the diaphragm membrane unit, which is the core component of an AWE, are discussed in detail.

Introductions for Foreign PEM Systems and It's Field Test Plan Linked to Renewable Energy in Jeju Island (국외 PEM 수전해시스템 도입 및 제주도 재생에너지 연계 실증방안)

  • Sangyup Jang;Jaedong Kim;Dongmin Kim;Jinmo Park;Youngseuk So
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.33-37
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    • 2023
  • Efforts by each country to solve the climate change problem continue, and the transition to eco-friendly fuels is a task for mankind to continue. Recently, Jeju Island, where renewable energy resources are relatively abundant, is preparing to demonstrate the technology to produce green hydrogen linked to renewable energy and this study aims to introduce and apply polymer electrolyte water electrolysis devices of advanced foreign companies after comparing domestic and foreign technologies. This study aims to solve domestic safety regulations for water electrolysis devices manufactured overseas and system introduction process and evaluation method of core components.

Development of Bamboo Zephyr Composite and the Physical and Mechanical Properties

  • SUMARDI, Ihak;ALAMSYAH, Eka Mulya;SUHAYA, Yoyo;DUNGANI, Rudi;SULASTININGSIH, Ignasia Maria;PRAMESTIE, Syahdilla Risandra
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.2
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    • pp.134-147
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    • 2022
  • The objective of this study is to determine the effect of fiber direction arrangement and layer composition of hybrid bamboo laminate boards on the physical and mechanical properties. The raw material used was tali bamboo (Gigantochloa apus (J.A. & J.H. Schultes) Kurs) rope in the form of flat sheets (zephyr) and falcata veneer (Paraserianthes falcataria (L) Nielsen). Zephyr bamboo was arranged in three layers using water-based isocyanate polymer (WBPI) with a glue spread rate of 300 g/m2. There were variations in the substitution of the core layer with falcata veneers (hybrid) as much as two layers and using a glue spread rate of 170 g/m2. The laminated bamboo board was cold-pressed at a pressure of 22.2 kgf/cm2 for 1 h, and the physical and mechanical properties were evaluated. The results showed that the arrangement of the fiber direction significantly affected the dimensional stability, modulus of rupture, modulus of elasticity, shear strength, and screw withdrawal strength. However, the composition of the layers had no significant effect on the physical and mechanical properties. The bonding quality of bamboo laminate boards with WBPI was considered to be quite good, as shown by the absence of delamination in all test samples. The bamboo hybrid laminate board can be an alternative based on the physical and mechanical properties that can meet laminated board standards.

A GMDH-based estimation model for axial load capacity of GFRP-RC circular columns

  • Mohammed Berradia;El Hadj Meziane;Ali Raza;Mohamed Hechmi El Ouni;Faisal Shabbir
    • Steel and Composite Structures
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    • v.49 no.2
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    • pp.161-180
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    • 2023
  • In the previous research, the axial compressive capacity models for the glass fiber-reinforced polymer (GFRP)-reinforced circular concrete compression elements restrained with GFRP helix were put forward based on small and noisy datasets by considering a limited number of parameters portraying less accuracy. Consequently, it is important to recommend an accurate model based on a refined and large testing dataset that considers various parameters of such components. The core objective and novelty of the current research is to suggest a deep learning model for the axial compressive capacity of GFRP-reinforced circular concrete columns restrained with a GFRP helix utilizing various parameters of a large experimental dataset to give the maximum precision of the estimates. To achieve this aim, a test dataset of 61 GFRP-reinforced circular concrete columns restrained with a GFRP helix has been created from prior studies. An assessment of 15 diverse theoretical models is carried out utilizing different statistical coefficients over the created dataset. A novel model utilizing the group method of data handling (GMDH) has been put forward. The recommended model depicted good effectiveness over the created dataset by assuming the axial involvement of GFRP main bars and the confining effectiveness of transverse GFRP helix and depicted the maximum precision with MAE = 195.67, RMSE = 255.41, and R2 = 0.94 as associated with the previously recommended equations. The GMDH model also depicted good effectiveness for the normal distribution of estimates with only a 2.5% discrepancy from unity. The recommended model can accurately calculate the axial compressive capacity of FRP-reinforced concrete compression elements that can be considered for further analysis and design of such components in the field of structural engineering.

Tensile Properties of Hybrid FRP Rods with Glass and Carbon Fibers (유리와 탄소섬유로 제작된 하이브리드 FRP 로드의 인장특성에 관한 실험연구)

  • You, Yong-Jun;Park, Ji-Sun;Park, Young-Hwan;Kim, Keung-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.275-282
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    • 2006
  • Recently, Fiber Reinforced Polymers(FRP) has been emerged as an alternative material to solve the corrosion of steel reinforcement in reinforced concrete structures. FRP exhibits higher specific strength and lower weight compared to steel reinforcement. Moreover, good resistance to corrosion of the FRP may be useful in aggressive environments causing deterioration such as chloride environment. However, causes for higher initial cost of FRP than that of steel, little information on the long-term behavior of FRP, and brittle failure make the efforts to apply FRP in civil structures slow. Glass fiber among the fibers used to manufacture FRP can be seen as the most beneficial material with regard to initial costs. But its low elastic modulus, which attains barely a quarter of steel, nay thus lead to excessive deflections when used as reinforcement for flexural members. This research was carried out on the tensile properties of hybrid rods made with glass and carbon fibers to improve those of FRP rod made with glass fiber. Parameters were resin type and the arrangement of glass and carbon fibers. The tensile properties of hybrid rods were compared with those of rods manufactured with only glass or carbon fibers. The results indicated that the tensile properties of hybrid rod were good when the carbon fiber was arranged in the core.

Development of Surface Coating Technology fey Metallic Bipolar Plate in PEMFC : I. Study on Surface and Corrosion Properties (PEMFCB금속분리판 코팅 기술 개발 : I. 표면 및 부식 특성 평가)

  • Chung, Kyeong-Woo;Kim, Se-Yung;Yang, Yoo-Chang;Ahn, Seung-Gyun;Jeon, Yoo-Taek;Na, Sang-Mook
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.348-351
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    • 2006
  • Bipolar plate, which forms about 50% of the stack cost, is an important core part with polymer electrolyte membrane in PEMFC. Bipolar plates have been commonly fabricated from graphite meterial having high electrical conductivity and corrosion resistance. Lately, many researchers have concentrated their efforts on the development of metallic bipolar plate and stainless steel has been considered as a potential material for metallic bipolar plate because of its high strength, chemical stability, low gas permeability and applicability to mass production. However, it has been reported that its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions and an increase in contact resistance by the growth of passive film therefore, its corrosion resistance as well as contact resistance must be improved for bipolar plate application. In this work, several types of coating were applied to 316L and their electrical conductivity and corrosion resistance were evaluated In the simulated PEMFC environment. Application of coating gave rise to low interfacial contact resistances below $19m{\Omega}cm^2$ under the compress force of $150N/cm^2$. It also made the corrosion potential to shift in the posit ive direct ion by 0.3V or above and decreased the corrosion current from ca. $9{\mu}A/cm^2$ to ca. $0.5{\mu}A/cm^2$ in the mixed solution of $0.1N\;N_2SO_4$ and 2ppm HF A coat ing layer under potentiostatic control of 0.6V and $0.75V_{SCE}$ for 500 hours or longer showed some instabilities, however, no significant change in coat Ing layer were observed from Impedance data. In addition, the corrosion current maintained less than $1{\mu}A/cm^2$ for most of time for potentiostatic tests. It indicates that high electrical conductivity and corrosion resistance can be obtained by application of coatings in the present work.

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Refractometric Glucose Biosensor Incorporating a Vertically Coupled Microring Resonator in Polymeric Waveguides (수직형 폴리머 마이크로링 공진기 기반의 글루코스 바이오 센서)

  • Kim, Gun-Duk;Son, Keun-Sik;Lee, Hak-Soon;Kim, Ki-Do;Lee, Sang-Shin
    • Korean Journal of Optics and Photonics
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    • v.19 no.2
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    • pp.127-131
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    • 2008
  • A refractometric glucose biosensor incorporating a vertically coupled microring resonator in polymers was proposed and realized. The ring was covered with a target analyte of glucose solution with a certain concentration, so that its effective refractive index could be altered and, as a result, the resonance wavelength of the sensor was shifted. Therefore the concentration of the glucose solution can be estimated by observing the shift in the resonance wavelength. Two schemes were exploited for enhancing the sensitivity of the sensor. First, the effective refractive index of the polymeric waveguide used for the resonator sensor was adjusted to approach that of the target analyte as best as possible. Second, the ring waveguide, which serves as a crucial sensing part, was appropriately over-etched to enlarge its contact area with the analyte. The proposed resonator sensor was designed with the beam propagation method. The refractive indices of the core and cladding polymer involved were 1.430 and 1.375 respectively, leading to the waveguide's effective refractive index of ${\sim}1.390$, which is faiirly close to that of the glucose solution of ${\sim}1.333$. The prepared ring resonator with the $400-{\mu}m$ radius exhibited the free spectral range of 0.66 nm, the bandwidth of 0.15 nm, and the quality factor of 10,000. For the sensor operating at 1,550 nm wavelength, the achieved sensitivity was as great as 0.28 pm/(mg/dL), which is equivalent to 200 nm/RIU.

Polyether Ester by Rubber Content and Rubber According to the Type of Dynamic Vulcanized Properties (TPEE) (폴리에스터계 동적가교물의 고무함량 및 고무종류에 따른 물성)

  • Yun, Ju-Ho;Yun, Jung-Hwan;Ha, Seong-Mun;Kim, Il;Sim, Sang-Eun
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.67-75
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    • 2013
  • E-TPE (Engineering Thermoplastic Polyether Ester) was Ester Elastomer with functional groups as recycling and fast processability. In addition, if the car's lightweight enough to highlight eco-friendly materials that help to improve fuel economy has become. Have all the attributes of the rubber and engineering plastics E-TPE the available temperature area is spacious, heat resistance and oil resistance is excellent but getting attention as a new material in the field of auto parts in the field of electrical and electronic domestic depends entirely on imports by the lack of core technology and has been research and development is urgently needed. In this study, the hard segments, polyester (TPEE) as the base soft elastomers of the segments Ethylen-prophylene-Copolymer and CSM (Choloro sulphonated polyethylene Rubber), VAMAC (Ethylene Acrylic Rubber), NBR (Acrylonitrin Butadiene Rubber), 1, 3-Phenylene-bisoxazoline is dealing with Dynamic Vulcanized by content and added rubber properties, thermal variation observed. As a result, the properties of the dynamic vulcanization with NBR compared to other rubber heat resistance and oil resistance is on the increase.

A comparison of chlorhexidine release rate from three polymeric controlled release drug prototypes (제어방출형 소독제의 약물전달 체로 사용된 폴리머 유형에 따른 클로르헥시딘 제어 방출속도 비교)

  • Bok Young-Bin;Lee Doug-Youn;Lee Chang-Young;Kim Kyung-Nam;Kum Kee-Yeon
    • Restorative Dentistry and Endodontics
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    • v.29 no.6
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    • pp.548-552
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    • 2004
  • Intracanal disinfection of infected root canal is one of important treatment procedure. This in vitro study aimed to evaluate whether the surface polymers of controlled release drug (CRD) can effectively control the release rate of chlorhexidine for root canal disinfection. Four CRD prototypes were prepared: Group A (n=12); The core device (absorbent paper point) was loaded with 40% CHX solution as control. Group B (n=12); same as group A, but the device was coated with chitosan. Group C (n=12); same as group A and then coated three times with 5% PMMA. Group D (n=12); same as group A and then coated three times with 3% PLGA. All CRD prototypes were soaked in 3 mL distilled water for experimental periods and the concentrations of released CHX from each CRD prototype were determined using a UV spectrophotometer. Results showed that release rate of CHX were the greatest in the non-coated group (control group), followed by the chitosan-coated group, the PLGA-coated group, and the PMMA-coated group (P < 0.05). This data indicate that surface polymers can control the release rate of CHX from the CRD prototypes.

Immunomodulatory Activities by Difference in Molecular Size of the Proteoglycan Extracted from Ganoderma lucidum IY009 (Ganoderma lucium IY009 유래 단백다당류의 분자량 차이에 따른 면역증강활성)

  • Lee, June-Woo;Baek, Seong-Jin;Bang, Kwang-Woong;Kim, Yong-Seuk;Kim, Kwang-Soo;Chun, Uck-Han
    • The Korean Journal of Mycology
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    • v.29 no.1
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    • pp.15-21
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    • 2001
  • This study was conducted to investigate the immunomodulatory activities of proteoglycan extracted from cultured mycelia of Ganoderma lucidum IY009. The proteoglycan contained two polymer peaks, one was the higher MW peak of 2,000 kD and the other was low peaks of 12kD. To understand the part of strong pharmaceutical activity between two peak, the proteoglycan was separated by ultrafiltration and column chromatography and then examined the various pharmaceutical effects. High molecular weight fraction possesing high content of ${\beta}-linked$ glucan was exhibited high antitumor activity, against sarcoma 180 bearing ICR mouse. And also, anticomplementary activity was highly observed in high molecule fraction than low it fraction. When the raw 264.7 and murine peritoneal macrophage treated with low fraction, high fraction and other stimuli. The activities inducing tumor necrosis factor of the high factions were $2.2{\sim}2.5$ times stronger than that of low fraction.

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