• 제목/요약/키워드: Core Center

검색결과 2,385건 처리시간 0.035초

The electronic structure of the ion-beam-mixed Pt-Cu alloys by XPS and XANES

  • Lim, K.Y.;Lee, Y.S.;Chung, Y.D.;Lee, K.M.;Jeon, Y.;Whang, C.N.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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    • pp.133-133
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    • 1998
  • In the thin film alloy formation of the transition metals ion-beam-mixing technique forms a metastable structure which cannot be found in the arc-melted metal alloys. Sppecifically it is well known that the studies about the electronic structure of ion-beam-mixed alloys pprovide the useful information in understanding the metastable structures in the metal alloy. We studied the electronic change in the ion-beam-mixed ppt-Ct alloys by XppS and XANES. These analysis tools pprovide us information about the charge transfer in the valence band of intermetallic bonding. The multi-layered films were depposited on the SiO2 substrate by the sequential electron beam evapporation at a ppressure of less than 5$\times$10-7 Torr. These compprise of 4 ppairs of ppt and Cu layers where thicknesses of each layer were varied in order to change the alloy compposition. Ion-beam-mixing pprocess was carried out with 80 keV Ae+ ions with a dose of $1.5\times$ 1016 Ar+/cm2 at room tempperature. The core and valence level energy shift in these system were investigated by x-ray pphotoelectron sppectroscoppy(XppS) pphotoelectrons were excited by monochromatized Al K a(1486.6 eV) The ppass energy of the hemisppherical analyzer was 23.5 eV. Core-level binding energies were calibrated with the Fermi level edge. ppt L3-edge and Cu K-edge XANES sppectra were measured with the flourescence mode detector at the 3C1 beam line of the ppLS (ppohang light source). By using the change of White line(WL) area of the each metal sites and the core level shift we can obtain the information about the electrons pparticippating in the intermetallic bonding of the ion-beam-mixed alloys.

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Spark Plasma Sintering and Ultra-Precision Machining Characteristics of SiC

  • Son, Hyeon-Taek;Kim, Dae-Guen;Park, Soon-Sub;Lee, Jong-Hyeon
    • 한국재료학회지
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    • 제20권11호
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    • pp.559-569
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    • 2010
  • The liquid-phase sintering method was used to prepare a glass lens forming core composed of SiC-$Al_2O_3-Y_2O_3$. Spark plasma sintering was used to obtain dense sintered bodies. The sintering characteristics of different SiC sources and compositions of additives were studied. Results revealed that, owing to its initial larger surface area, $\alpha$-SiC offers sinterability that is superior to that of $\beta$-SiC. A maximum density of $3.32\;g/cm^3$ (theoretical density [TD] of 99.7%) was obtained in $\alpha$-SiC-10 wt% ($6Al_2O_3-4Y_2O_3$) sintered at $1850^{\circ}C$ without high-energy ball milling. The maximum hardness and compression stress of the sintered body reached 2870 Hv and 1110 MPa, respectively. The optimum ultra-precision machining parameters were a grinding speed of 1243 m/min, work spindle rotation rate of 100 rpm, feed rate of 0.5 mm/min, and depth of cut of $0.2\;{\mu}m$. The surface roughnesses of the thus prepared final products were Ra = 4.3 nm and Rt = 55.3 nm for the aspheric lens forming core and Ra = 4.4 nm and Rt = 41.9 for the spherical lens forming core. These values were found to be sufficiently low, and the cores showed good compatibility between SiC and the diamond-like carbon (DLC) coating material. Thus, these glass lens forming cores have great potential for application in the lens industry.

코어-쉘 구조의 산화철/그래핀 복합체 제조 및 슈퍼커패시터 응용 (Preparation of Core-Shell Structured Iron Oxide/Graphene Composites for Supercapacitors Application)

  • 이총민;장한권;장희동
    • 한국입자에어로졸학회지
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    • 제14권3호
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    • pp.65-72
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    • 2018
  • Core-shell structured $Fe_3O_4/graphene$ composites were synthesized by aerosol spray drying process from a colloidal mixture of graphene oxides and $Fe_3O_4$ nanoparticles. The structural and electrochemical performance of $Fe_3O_4/graphene$ were characterized by the field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, cyclic voltammetry, and galvanometric discharge-charge method. Core-shell structured $Fe_3O_4/GR$ composites were synthesized in different mass ratios of $Fe_3O_4$ and graphene oxide. The composite particles were around $3{\mu}m$ in size. $Fe_3O_4$ nanoparticles were encapsulated with a graphene. Morphology of the $Fe_3O_4/graphene$ composite particles changed from a spherical ball having a relatively smooth surface to a porous crumpled paper ball as the content of GO increased in the composites. The $Fe_3O_4/GR$ composite fabricated at the weight ratio of 1:4 ($Fe_3O_4:GO$) exhibited higher specific capacitance($203F\;g^{-1}$) and electrical conductivity than as-fabricated $Fe_3O_4/GR$ composite.

Identification of Hepatitis C Virus Core Domain Inducing Suppression of Allostimulatory Capacity of Dendritic Cells

  • Kim, Ho-Sang;Lee, Jae-Kwon;Yang, In-Ho;Ahn, Jeong-Keun;Oh, Yoon-I;Kim, Chul-Joong;Kim, Young-Sang;Lee, Chong-Kil
    • Archives of Pharmacal Research
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    • 제25권3호
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    • pp.364-369
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    • 2002
  • Hepatitis C virus (HCV) is remarkably efficient at establishing chronic infection. One of the reasons for this appears to be the suppression of the accessory cell function of professional antigen presenting cells. In the present study, the immunosuppressive activity of HCV protein was examined on dendritic cells (DCs) generated from mouse bone marrow progenitor cells in vitro. We found that the DCs forced to express HCV protein have defective allostimulatory ability. DCs expressing HCV protein were phenotypically indistinguishable from normal DCs. However, they were unable to produce IL-12 effectively when stimulated with lipopolysaccharide. The functional domain of the HCV protein essential for immunosuppression was determined using a series of ${NH_2}-and$ C-terminal deletion mutants of HCV core protein. We found that amino acid residues residing between the 21 st and the 40th residues from the ${NH_2}-terminus$ of HCV core protein are required for immunosuppression. These findings suggest that HCV core protein suppresses the elicitation of protective Th1 responses by the inhibition of IL-12 production by DCs.

SOFC 음극 제조를 위한 NiO가 코팅된 YSZ 분말의 합성 (Preparation of NiO Coated YSZ Powder for Fabrication of an SOFC Anode)

  • 임광영;한인동;심수만;박준영;이해원;김주선
    • 한국세라믹학회지
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    • 제43권12호
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    • pp.781-787
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    • 2006
  • NiO-coated YSZ powder was prepared using heterogeneous precipitation of Ni hydroxides on YSZ particle surface and high energy milling. The powders were characterized by TG/DTA, XRD, XPS, and SEM. Amorphous Ni precipitate completely decomposed into NiO at $500^{\circ}C$ and the growth of NiO crystallites was constrained by the core particles. Nanocrystalline NiO-coated YSZ core-shell structure powder could be obtained after calcination at $800^{\circ}C$ for 2 h. A core-shell powder compact, due to high sinterability, showed a near theoretical density at $1350^{\circ}C$. After reduction at $900^{\circ}C$, interpenetrating Ni-YSZ microstructure with very uniformly distributed fine Ni and YSZ grains and pores was observed. In contrast, the mechanically mixed oxide sample showed less uniform distribution of pores and larger discontinuous We particles as compared with the core-shell samples.

공학계열 학생 핵심역량 진단도구 개발 및 타당화 연구 (Development and Validation of Core Competency Assessment Tools for Engineering Student)

  • 김윤영;윤지영
    • 공학교육연구
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    • 제24권4호
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    • pp.3-20
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    • 2021
  • As we have become more interested in 'competency' that means ability to do something around the world, the competency of the best performers has also been introduced in the university curriculum as a concept of core competency. Research continues on why this competency-based education is needed compared to existing academic-oriented education, how it can be introduced into existing curricula, and how it can be developed and evaluated in detail. This study develops and validates core competency assessment tools that can diagnose core competencies of engineering students. Therefore, this research paper conducted a literature review related to core competencies and also core competency assessment tools of university students. It seeks to explore the implications of core competency assessment tools for engineering students and then lay the foundation for competency-based teaching and learning at engineering colleges. And also it defines the concepts of core competencies and each core competency of engineering students through prior research analysis of competence, core competence, and core competence of university students. The primary core competency assessment tool consisted of sub-factors and questions of core competencies. It were modified through the expert validation of the primary one and then it was used as a core competency assessment tools for preliminary investigation. The core competency assessment tools for engineering students are consisted of 6 competencies, 22 sub-factors, and 91 questions. There are core competencies as follows: engineering basic competencies, major engineering competencies, self-management competencies, communication competencies, interpersonal competencies, global competencies. The preliminary survey was conducted on 426 engineering students attending the Engineering Education FESTA 2019. The preliminary findings were derived by conducting exploratory factor analysis, confirmatory factor analysis, question characteristics analysis, and reliability analysis for validation. The core competency assessment tools developed through this study can be used to verify the effectiveness of the curriculum and programs for students at engineering colleges. In addition, the developed core competencies, sub-factors, and questions can be utilized in a series of courses that design, conduct, and evaluate engineering curricula and programs as competency-based curriculum. The significance of this study is to lay the groundwork for providing competency-based education engineering students to develop core competencies.

A Comparative Study of Gas Sensing Properties of Au-loaded ZnO and Au@ZnO Core-shell Nanoparticles

  • Majhi, Sanjit Manohar;Dao, Dung Van;Lee, Hu-Jun;Yu, Yeon Tae
    • 센서학회지
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    • 제27권2호
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    • pp.76-81
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    • 2018
  • Au@ZnO core-shell nanoparticles (NPs) were prepared by a simple method followed by heat-treatment for gas sensor applications. The advantage of the core-shell morphology was investigated by comparing the gas sensing performances of Au@ZnO core-shell NPs with pure ZnO NPs and different wt% of Au-loaded ZnO NPs. The crystal structures, shapes, sizes, and morphologies of all sensing materials were characterized by XRD, TEM, and HAADF-STEM. Au@ZnO core-shell NPs were nearly spherical in shape and Au NPs were encapsulated in the center with a 40-45 nm ZnO shell outside. The gas sensing operating temperature for Au@ZnO core-shell NPs was $300^{\circ}C$, whereas it was $350^{\circ}C$ for pure ZnO NPs and Au-loaded ZnO NPs. The maximum response of Au@ZnO core-shell NPs to 1000 ppm CO at $300^{\circ}C$ was 77.3, which was three-fold higher than that of 2 wt% Au-loaded ZnO NPs. Electronic and chemical effects were the primary reasons for the improved sensitivity of Au@ZnO core-shell NPs. It was confirmed that Au@ZnO core-shell NPs had better sensitivity and stability than Au-loaded ZnO NPs.

공유기반 트리 멀티캐스트 라우팅 프로토콜을 위한 후보 코어 선택 방법 (A Method of Selecting Candidate Core for Shared-Based Tree Multicast Routing Protocol)

  • 황순환;윤성대
    • 한국멀티미디어학회논문지
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    • 제7권10호
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    • pp.1436-1442
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    • 2004
  • 코어 기반 트리 멀티캐스트 라우팅 프로토콜, PIM-SM, 코어 관리자 기반 멀티캐스트 라우팅 등에 의해 확립된 공유 기반 트리는 코어 또는 랑데뷰 포인트라는 센터 노드를 루트로 하는 구조이다. 공유 기반 트리에서 코어(또는 랑데뷰 포인트)로부터 멀티캐스트 그룹의 모든 구성원들에 대한 전송 경로는 가장 짧은 거리를 사용한다. 트리의 구성 비용은 코어에 의해 결정되고, 패킷들의 지연은 코어의 위치에 의해 좌우된다. 따라서 코어의 위치 선정은 비용과 성능 측면에 많은 영향을 끼친다. 본 논문에서는 후보 코어 그룹 선택을 위한 세 가지 방법을 제안하고자 한다. 제안한 최소 평균 비용 선택, 최대 차수 선택, 최대 가중치 선택 방법은 각각 임의 선택 방법과 트리 비용, 평균 패킷 지연, 최대 패킷 지연의 세 가지 성능 평가 요소를 통해 비교하였다. 모의실험 결과 후보 코어 그룹 선택에 있어서 제안한 세 가지 방법이 임의 선택방법보다 성능 평가요소인 트리 비용, 평균 패킷 지연, 최대 패킷 지연 측면에서 더 낮은 결과를 보임으로써, 우수함을 입증하였다.

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