• 공업화학
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• 제25권3호
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• pp.307-311
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• 2014

본 연구에서는 4종류의 목재 폐기물(밤나무, 소나무, 낙엽송, 아카시아) 중에서 구리 이온 제거 능력이 뛰어난 생물흡착제로서 밤나무를 도출하였으며, 또한, 이 밤나무를 이용하여 수중에 함유된 5, 10, 20, 40 mg/L 구리 이온의 제거 효율에 대하여 고찰하였다. 5 mg/L 구리 이온 제거를 위하여, $43{\sim}63{\mu}m$ 입자 크기의 밤나무 사용이 가장 효과적임을 알 수 있었다. 밤나무 주입 농도를 증가하였을 때, 구리 제거효율이 향상되었다. 또한, 0.8 g/100 mL 밤나무가 30 min 동안 사용되었을 때, 20, 40 mg/L 구리 이온 제거효율은 각각 99, 85% 제거효율을 나타내었다. 그리고 50 mg/L 구리 이온의 제거 능력을 향상시키기 위하여, 밤나무에 1 M 아세트산나트뮴의 화학적 처리가 필요함을 알 수 있었다. 한편, 개질된 밤나무를 재활용하기 위하여 최적의 탈착제로서 93% 구리 탈착 효율을 나타낸 1 M 염산을 선정하였다. 따라서 이러한 실험 결과들은 경제적이고 실용적인 공학 자료로서 구리 제거 공정 개발에 활용될 수 있을 것이다.

• Bulletin of the Korean Chemical Society
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• 제27권10호
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• pp.1572-1576
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• 2006

A dimeric precursor, $[Cu(dmae)(OCOCH_3)(H_2O)]_2$ for the CVD of copper metal films, (dmaeH = N,N-dimethylaminoethanol) was synthesized by the reaction of copper(II) acetate monohydrate ($Cu(OCOCH_3)_2{\cdot}H_2O$) and dmaeH in toluene. The product was characterized by m.p. determination, elemental analysis and X-ray crystallography. Molecular structure of $[Cu(dmae)(OCOCH_3)(H_2O)]_2$ shows that a dimeric unit $[Cu(dmae)(OCOCH_3)(H_2O)]_2$ is linked to another through hydrogen bond and it undergoes facile decomposition at 300 C to deposit granular copper metal film under nitrogen atmosphere. The decomposition temperature, thermal behaviour, kinetic parameters, evolved gas pattern of the complex, morphology, and the composition of the film were also investigated.

• Plant Resources
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• 제5권3호
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• pp.206-209
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• 2002

This study was performed to investigate the effect of Mentha arvensis Herba extract on the treatment of chromaticity and colorfastness. Mentha arvensis Herba has been used as a Korean medicine. It is effective in headache and stress. It is also good as a aphtha and in treating cold. In the long history of Korea, dyeing has been applied for a means representing the grace of natural and inner esthetic consciousness of man. Vegetable dyes give us such great benefits, diversified color, but no pollution. And ramie fabric has distinctive features such as beautiful brilliance, elegance, and strong durability. So, it is regarded as a special product of Korea traditionally. These studies were carried out to treat with acetate iron, dichloride copper and alum with a mordant to ramie fabric. The ramie fabric was died with Mentha arvensis Herba extract. The results of experiment showed as follows: First, the chromophoric degree was the highest in acetate iron but not distinction in another mordants. Second, the light colorfastness was the highest in non treated and dichloride copper, but alum was the lowest. Third, the discoloration was alum and dichloride copper showed first grade in washing colorfastness. Abrasion colorfastness was not significant in this test. According the previous results, Mentha arvensis Herba has an efficiency in removing aphtha and in treating cold. So it is considered that Mentha arvensis Herba can be applied effectively to headache and stress.

• 한국가축번식학회지
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• 제25권2호
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• pp.147-153
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• 2001

본 연구는 Pb중독이 rat의 생리현상에 미치는 영향을 구명 하고자 연속적인 Pb acetate 투여가 정소의 중량, 정자수, 활력, 장기중량 및 조직학적 변화를 조사하였다. 1. Pb acetate 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 정소중량은 정상대조군에 비해 감소하는 경향을 나타냈고 용량이 증가할수록 정소중량은 큰 감소경향을 나타냈다. 2. Pb acetate 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 정자수는 정상대조군에 비해 감소하는 경향을 나타냈고 용량이 증가할수록 정자수는 유의한 감소경향을 나타냈다. 3. Pb acetate 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 정자의 활력은 정상대조군에 비해 점차 감소하는 경향을 나타냈고 용량이 증가할수록 정자활력은 큰 감소경향을 나타냈다. 4. Pb acetate 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 간 및 신장의 중량은 정상대조군에 비해 점차 증감의 경향을 나타냈으며, 투여용량별 간 및 신장의 중량은 유의한 변화를 나타내지 않았다. 5. Pb acetate를 연속적으로 투여했을 때 간의 조직학적 관찰소견은 간세포 중심정맥의 주위성괴사, 호중구의 침윤, 담즙정체 및 간문맥관과 간질 대식세포의 침윤이 관찰되었고, 신장에서는 원위세뇨관 상피의 핵내 함입물과 사구체낭 및 세뇨관내 균질한 초자물질이 충만되어 있었고 림프절에서는 골수의 조혈현상이 관찰되었다.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2679-2682
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• 2012

A simple one-pot synthesis of two derivatives of 1,4-dihydropyridines has been described under reflux conditions using copper iodide nanoparticles (CuI NPs) as a catalyst in high yields. This method demonstrated four-component coupling reactions of aldehydes and ammonium acetate via two pathways. In one route, the reaction was performed using 2 eq ethyl acetoacetate while in the other one 1 eq ethyl acetoacetate and 1 eq malononitrile were used. The CuI NPs was reused and recycled without any loss of activity and product yield. It is noteworthy to state that wide range of the 1,4-dihydropyridines have attracted large interest due to pharmacological and biological activities.

• 한국의류학회지
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• 제27권9_10호
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• pp.1134-1143
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• 2003

The purpose of this study is to investigate surface color change and effects of mordants on the K/S values of silk and wool fabrics dyed with Lac extract, according to the mordanting methods and conditions such as temperature, concentration and time of the mordanting bath. The results were as follow; 1 K/S values of the silk and wool fabrics according to the temperature of the mordanting bath were shown a slight decline beyond 40$^{\circ}C$. 2. Surface color of the silk changed from red to reddish purple and that of the wool showed red tone when mordanted with Aluminum postassium sulfate, Copper acetate and Copper (II) sulfate regardless of the mordanting conditions. 3. The light and dry cleaning fastness of silk and wool fabrics dyed with Lac extract according to the mordanting methods were very good.

• 한국염색가공학회지
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• 제11권4호
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• pp.39-49
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• 1999

In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

• Bulletin of the Korean Chemical Society
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• 제17권8호
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• pp.688-693
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• 1996

Tetradentate Schiff base ligands derived from 2-hydroxy-1-naphthaldehyde and aliphatic diamine have been synthesized. Cu(Ⅱ) complexes of Schiff base ligands have been synthesized from the free ligands and copper acetate. The mole ratio of ligand to copper was identified to be 1:1 by the result of elemental analysis and Cu(Ⅱ) complexes were in a four-coordinated configuration. The electrochemical redox process of Cu(Ⅱ) complexes in a DMF solution has been investigated by cyclic voltammetry, chronoamperometry, differential pulse voltammetry, and controlled potential coulometry. The redox process of Cu(Ⅱ) complexes is one electron transfer process in quasi-reversible and diffusion-controlled reaction. The electrochemical redox potentials and the kinetic parameters of Cu(Ⅱ) complexes are affected by the chelate ring of Schiff base ligands.

• 한국재료학회지
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• 제25권4호
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• pp.171-176
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• 2015

We present the detection characteristics of nitrogen monoxide(NO) gas using p-type copper oxide(CuO) thin film gas sensors. The CuO thin films were fabricated on glass substrates by a sol-gel spin coating method using copper acetate hydrate and diethanolamine as precursors. Structural characterizations revealed that we prepared the pure CuO thin films having a monoclinic crystalline structure without any obvious formation of secondary phase. It was found from the NO gas sensing measurements that the p-type CuO thin film gas sensors exhibited a maximum sensitivity to NO gas in dry air at an operating temperature as low as $100^{\circ}C$. Additionally, these CuO thin film gas sensors were found to show reversible and reliable electrical response to NO gas in a range of operating temperatures from $60^{\circ}C$ to $200^{\circ}C$. It is supposed from these results that the p-type oxide semiconductor CuO thin film could have significant potential for use in future gas sensors and other oxide electronics applications using oxide p-n heterojunction structures.

• 한국토양비료학회지
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• 제22권2호
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• pp.116-121
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• 1989

토양중(土壤中)의 Cu함량(含量) 증가원인(增加原因)에 따른 Cu의 동태(動態)를 구명(究明)하고저, 천연적(天然的)으로 중금속(重金屬) 함량(含量)이 높은 토양(土壤)과 도시하수(都市下水) composted sludge를 경작지(耕作地)에 9년간(年間) 매년(每年) 각각(各各) 22.5, $45.0mg{\cdot}ha^{-1}$로 장기처리(長期處理)함에 의해서 토양중(土壤中)의 Cu증가원인(增加原因)이 된 토양등(土壤等) 6종(種)의 시료(試料)를, 추출용액(抽出溶液) $4M\;HNO_3$, $EDTA-Ca(NO_3)_2$, DTPA-TEA, 0.1M HCl, $1M\;NH_4OAc$등(等)에 의한 Cu의 이동성(移動性)을 분석(分析)한 결과(結果)는 다음과 같다. 1. Sludge처리(處理)를 계속(繼續)한 경작지(耕作地) 토양(土壤)에서는 $45.0mg{\cdot}ha^{-1}{\cdot}yr^{-1}$ 토양(土壤)이, $22.5mg{\cdot}ha^{-1}{\cdot}yr^{-1}$ 토양(土壤)보다 Cu의 함량(含量)이 토양(土壤)의 종류(種類)에 관계(關係)없이 더 높았다. 2. $4M\;HNO_3$에 의해 추출(抽出)된 Cu량(量)을 토양중(土壤中)의 전(全) Cu량(量)으로 하여 이에대한 다른 추출용액(抽出溶液)의 종류(種類) 즉(卽), $EDTA-Ca(NO_3)$, DTPA-TEA, 0.1M HCl, $1M\;NH_4OAc$에 의하여 추출(抽出)되어 나오는 Cu함량(含量)과의 비율(比率)에서 보면 천연적(天然的)으로 Cu를 함유(含有)하고 있는 토양(土壤)에서 보다 sludge 를 장기처리(長期處理)한 토양중(土壤中)의 Cu가 더 많이 추출(抽出)되었다. 3. $4M\;HNO_3$에 의한 Cu량(量)과 $EDTA-Ca(NO_3)_2$, DTPA-TEA, 0.1M HCl, $1M\;NH_4OAc$에 의해 추출(抽出)된 Cu량(量)과 비교(比較)한 비(比)(R)와 CEC 및 OM%와의 곱한 값은 DTPA-TEA, $EDTA-Ca(NO_3)_2$의 경우(境遇) $4M\;HNO_3$ 에 의한 Cu량(量)과 정(正)의 유의성(有意性) 있는 상관관계(相關關係)를 나타내었다.