• 제목/요약/키워드: Coordination polymers

검색결과 56건 처리시간 0.019초

Synthesis and microphase-separated structures of rod-coil triblock polymers

  • Uchida, Satoshi;Tanimura, Kotaro;Ishizu, Koji
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.326-326
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    • 2006

  • The combination of living anionic and coordination polymerization techniques enabled to synthesize the polystyrene-b-polyisoprene-b-poly (butyl isocyanate) triblock polymers. Their microphase-separated structures were zig-zag structures for high ${\phi}_{PIC}$ samples, and hockey-puck structures were also observed. The phase diagram for PSt-b-PIp-b-PIC rod-coil polymers was different from that for PS-PBd-PMMA triblock polymers, and it was found that ${\phi}_{PIC}$ was the important factor to determine the microphase-separated structures.

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