• Journal of Korea Water Resources Association
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• v.46 no.4
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• pp.373-387
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• 2013

For the efficient operation and management of the water resources system, coordinated operation of weirs and reservoirs is required. A simulation based, and an optimization based approaches are available to deal with the operation and management problems. The simulation based approach does not guarantee an optimal solution, and the optimization based approach is not so flexible to consider, complex, nonlinear problems we will face when trying to allocate water to different uses, various demand sectors in a basin. Hence, it is important to develop a model that would compensate for the weak points in both models. We will compare and contrast intrinsic and extrinsic properties of two modeling approaches, addressing issues related to setting system operation and control rules that would lead us to more efficient use of water in the basin. As a result, we propose to use CoWMOM(Coordinated weirs and multi-reservoir operating model), a "simulation based" optimization model for a simple simulation of the past periods, and for the real-time simulation process considering uncertain inflow.

• Journal of the Korean Chemical Society
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• v.47 no.4
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• pp.334-338
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• 2003

The crystal structure of $[Co(phen)_2(Cl)(H_2O)] Clㆍ2H_2O$(phen=1,10-phenanthroline) has been determined by X-ray crystallography. It crystallizes in the triclinic system, space group P1, with lattice parameters a=9.662(2), b=11.445(1), c=13.037(2)${\AA}$ ${\alpha}$=64.02(1), ${\beta}$=86.364(9), ${\gamma}=78.58(2)^°$, and Z=2. The coordinated cations contain a six-coordinated cobalt atom chelated by two phen ligands and one chloride anion and one water ligand in cis arrangement. In addition to the chloride coordinated to the cobalt, there are one chloride ion and four water molecules which complete the crystal structure. In the solid state, the title compound forms three dimensional network structure through hydrogen bonds, within which exists the strongest hydrogen bond (O(3)-O(4)=2.33${\AA}$). The intermolecular hydrogen bonds connect the $[Co(phen)_2(Cl)(H_2O)]1+,\;H_2O$ moieties and chloride ion.

• Proceedings of the Korea Water Resources Association Conference
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• 2005.05b
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• pp.289-293
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• 2005

본 연구에서는 일별 저수지군 최적연계운영 모형(CoMOM 4.0 : Coordinated Multireservoir Operating Model version 4.0)을 낙동강 수계 실시간 일별 운영에 CoMOM을 적용할 경우를 상정하여, 불확실성을 고려한 실시간 모의 운영을 수행하였다. 실시간 일 운영 시 며칠 정도의 유입량 예측은 가능할 것으로 예상하여 유입량 예측일수의 정확도 증가에 따른 연계 운영 효과를 산정해 본 결과, 전반적으로 과거 실적치에 비하여는 좋지만, 예측일 수가 늘어남에 따라 수계 내 연간 평균 저수량은 감소하는 대신 평균 발전량은 증가하여, 연계운영 총체적 효과가 기하급수적으로 증가됨을 알 수 있었다. 미래 유입량을 전혀 예측하지 못할 경우에는 일평균 유입량을 예측 유입량으로 하여 실시간 댐군 연계모의운영을 하였고, 그 경우에도 여수로 방류로 인한 수계 외 유출을 연 평균 약 214백만$m^3$ 정도 감소시키는 반면, 수계 내 전체 댐 군의 평균저수량을 55백만$m^3$ 증가 시키며, 연간 평균 발전량은 25GWh (약 22.5억원/년의 추가 발전수입) 증가 시킬 수 있을 것으로 분석되었다.

• Journal of Radiation Protection and Research
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• v.14 no.2
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• pp.37-44
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• 1989

An improved water chemistry technique was studied to reduce radioactivity build-up in reactor coolant system. The technique is convering the current coordinated lithium-boron chemistry regime to the elevated lithium chemistry regime in order to maintain high pH. Correlations between reactor coolant pH and radioactivity build-up were analized by using pH data from domestic PWRs. Consequently, it was founded that high pH chemistry was moer effective for radioactivity build-up reduction than current chemistry regime. This fact had revealed that much portion of reactor coolant corrosion products were nickel ferrite rather than magnetite, and that pH value ranging 7.0-7.4 was appropriate for high-pH chemistry operation.

• Journal of Electrical Engineering and Technology
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• v.11 no.5
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• pp.1116-1127
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• 2016

• Journal of the Korean Chemical Society
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• v.57 no.6
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• pp.721-725
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• 2013

Reaction between 2-pyridinecarboxylic acid (Hpic) and $K_3[Cr(O_2)_4]$ give complex $[Cr(pic)_3].H_2O$ (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two $O-H{\cdots}O$ hydrogen bonds.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.232-238
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• 1990

To study the biological roles of Zn, we investigated simple model systems of $Zn^{++}, coordinated with OH_2 or NH_3,$ or with O=C- in peptide. The geometrical structures and net atomic charges were calculated by the ab initio HF-SCF theory using double zeta basis sets. The ligands of O-H, N-H, and O=C- are very polar due to $Zn^{++}$. Therefore, the carbon atom in peptide becomes so electrophilic that it can be easily attacked by other nucleophiles. In addition, to understand how $Zn^{++}$ is coordinated with ligands in enzyme, a molecular mechanics method is applied to the system of the enzyme of carboxypeptidase A (CPA) with the substrate of glycyltyrosine. From our results, it appears that the Zn ion is coordinated not only by four ligands in enzyme and substrate but also by one water molecule.

• Journal of Environmental Health Sciences
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• v.24 no.3
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• pp.26-34
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• 1998

Diethanolamine Dithiocarbamate containing OH groups which gave water-soluble [Pt(dtc)$_{2}$] (diethanolamine dithiocarbamate) were synthesized from the reaction of CS$_{2}$ with diethanolamine. The complex has been characterized by elemental analysis, electrical conductivity, and spectroscopic results. Diethanolamine dithiocarbamate is effective as rescue and inhibition of cis-[$Pt(NH_{3})_{2}Cl_{2}$] nephrotoxicity in rats. It is suggested that diethanolamine dithiocarbamare removes platinum(II) complex coordinated to -SH groups of protein of kidney tubule cells.

• Journal of The Korean Astronomical Society
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• v.29 no.spc1
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• pp.419-420
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• 1996

The VLBI Space Observatory Program (VSOP) is a worldwide project of one radio telescope in space with many ground radio telescopes. The concerted space VLBI network enables us to reveal high resolution and high quality images of radio sources. The space radio telescope is anticipated to be launched in January/February 1997, and collaborative observations have been coordinated. The basic parameters of the system and present status are given.

• Bulletin of the Korean Chemical Society
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• v.35 no.11
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• pp.3244-3248
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• 2014

Two ethylenediamine cobalt(II) oxalate complexes Co(ox)(en), 1 and $Co(ox)(en){\cdot}2H_2O$, 2 have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR spectrum, TG analysis, and magnetic measurements. In 1, Co atoms are coordinated by two bis-bidentate oxalate ions in transconfiguration to form Co(ox) chains, which are further bridged by ethylenediamine molecules to produce 2D grid layers, Co(ox)(en). In 2, Co atoms are coordinated by bridging oxalate ions in cis-configuration to form Co(ox) chains, and the additional chelation of ethylenediamine to Co atoms completes 1D zigzag chain, Co(en)(ox). Two lattice water molecules stabilize the chains through hydrogen bonding. Magnetic susceptibility measurements indicate that both complexes exhibit weak antiferromagnetic coupling between cobalt(II) ions with the susceptibility maxima at 23 K for 1 and 20 K for 2, respectively. In 1 and 2, the oxalate ligands afford a much shorter and more effective pathway for the magnetic interaction between cobalt ions compared to the ethylenediamine ligands, so the magnetic behaviors of both complexes could be well described with 1D infinite magnetic chain model.