• Title/Summary/Keyword: Conversion Factor

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Effect of Self-Assembled Monolayer Treated ZnO on the Photovoltaic Properties of Inverted Polymer Solar Cells

  • Yoo, Seong Il;Do, Thu Trang;Ha, Ye Eun;Jo, Mi Young;Park, Juyun;Kang, Yong-Cheol;Kim, Joo Hyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.569-574
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    • 2014
  • Inverted bulk hetero-junction polymer solar cells (iPSC) composed of P3HT/PC61BM blends on the ZnO modified with benzoic acid derivatives-based self-assembled monolayers (SAM) are fabricated. Compared with the device using the pristine ZnO, the devices with ZnO surface modified SAMs derived from benzoic acid such as 4-(diphenylamino)benzoic acid (DPA-BA) and 4-(9H-carbazol-9-yl)benzoic acid (Cz-BA) as an electron transporting layer show improved the performances. It is mainly attributed to the favorable interface dipole at the interface between ZnO and the active layer, the eective passivation of the ZnO surface traps, decrease of the work function and facilitating transport of electron from PCBM to ITO electrode. The power conversion eciency (PCE) of iPSCs based on DPA-BA and Cz-BA treated ZnO reaches 2.78 and 2.88%, respectively, while the PCE of the device based on untreated ZnO is 2.49%. The open circuit voltage values ($V_{oc}$) of the devices with bare ZnO and SAM treated ZnO are not much different. Whereas, higher the fill factor (FF) and lower the series resistance ($R_s$) are obtained in the devices with SAMs modification.

Optimization of Drive-in Temperature at Doping Process for Mono Crystalline Silicon Solar Cell (단결정 실리콘 태양전지의 도핑 최적화를 위한 확산 온도에 대한 연구)

  • Cho, Sung-Jin;Song, Hee-Eun;Yoo, Kwon-Jong;Yoo, Jin-Soo;Han, Kyu-Min;Kwon, Jun-Young;Lee, Hi-Deok
    • Journal of the Korean Solar Energy Society
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    • v.31 no.1
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    • pp.37-43
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    • 2011
  • In this paper, the optimized doping condition of crystalline silicon solar cells with $156{\times}156\;mm^2$ area was studied. To optimize the drive-in temperature in the doping process, the other conditions except variable drive-in temperature were fixed. These conditions were obtained in previous studies. After etching$7\;{\mu}m$ of the surface to form the pyramidal structure, the silicon nitride deposited by the PECVD had 75~80nm thickness and 2 to 2.1 for a refractive index. The silver and aluminium electrodes for front and back sheet, respectively, were formed by screen-printing method, followed by firing in 400-425-450-550-$850^{\circ}C$ five-zone temperature conditions to make the ohmic contact. Drive-in temperature was changed in range of $830^{\circ}C$ to $890^{\circ}C$to obtain the sheet resistance $30{\sim}70\;{\Omega}/{\box}$ with $10\;\Omega}/{\box}$ intervals. Solar cell made in $890^{\circ}C$ as the drive-in temperature revealed 17.1% conversion efficiency which is best in this study. This solar cells showed $34.4\;mA/cm^2$ of the current density, 627 mV of the open circuit voltage and 79.3% of the fill factor.

A Study on Wind Speed Estimation and Maximum Power Point Tracking scheme for Wind Turbine System (풍력발전기를 위한 신경망 기반의 풍속 추정 및 MPPT 기법에 관한 연구)

  • Moon, Dae-Sun;Kim, Sung-Ho
    • Journal of the Korean Institute of Intelligent Systems
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    • v.20 no.6
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    • pp.852-857
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    • 2010
  • As the wind has become one of the fastest growing renewable energy sources, the key issue of wind energy conversion systems is on how to efficiently operate the wind turbines in a wide range of wind speeds. In general, the wind speed is the main factor that impact on the dynamics of wind turbine system. Wind turbine algorithms are thus required to improve the performance of wind speed measurements. However, the accurate measurement of the effective wind speed using wind gauge and similar sensors is difficult such that control systems are needed for wind speed estimation using various techniques. Therefore, this research suggests the Maximum Power Point Tracking (MPPT) method for tracking the wind speed based on neural networks. Design experiments were carried out in laboratory environment to validate the application of the proposed method.

DEPRESSION: CELLULAR AND PHYSIOLOGICAL CONSEQUENCES OF STRESS (ANTIDEPRESSANT EFFECT OF SEROTONIN N-ACETYLTRANSFERASE INHIBITOR)

  • Kim Kyong-Tai
    • Proceedings of the Korean Society of Food Science and Nutrition Conference
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    • 2001.12a
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    • pp.22-37
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    • 2001
  • Melatonin is secreted during the hours of darkness and is thought to influence the circadian and seasonal timing of a variety of physiological processes. Serotonin N-acetyltransferase (AA-NAT) which is found to be expressed in pineal gland, retina, and various tissues, catalyses the conversion of serotonin to N-acetylserotonin and is known as the rate-limiting enzyme in the biosynthetic pathway of melatonin. The compounds that modulate the activity of AA-NAT can be used to treat serotonin-and melatonin-related diseases such as insomnia, depression and seasonal affective disorders (SAD). Several assay methods have been developed by which to measure AA-NAT activity. We have also developed a simple, rapid and sensitive AA-NAT assay method that takes advantage of differences in the organic solubilities between acetyl CoA and N-acetyltryptamine. We screened modulators of AA-NAT activity from the water extracts of the medicinal plants. We found MNP1005 which strongly inhibited the activity of AA-NAT ($IC_{50}$=2.2$\mu$M). Enzyme inhibitory kinetic studies revealed that MNP1005 exhibited a noncompetitive inhibition toward tryptamine. The antidepressant effect of MNP1005 was investigated on behavioral despair test so called forced swimming test (FST). MNP1005 significantly increased swimming behavior by reducing immobility with treatment of 10 mg/kg when compared to the vehicle-treated control group (P < 0.05). This suggests that MNP1005 possesses antidepressant activity. The influence of chronic MNP1005 treatment on the expression of brain-derived neurotrophic factor (BDNF) was examined by in situ hybridization and Northern blot. Chronic treatment of MNP1005 blocked the downregulation of BDNF mRNA in the frontal cortex and other cortex regions in response to restraint stress.

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Spectroscopic Properties of Quercetin-3-O-rhamnoside and Quercetin-3-O-rutinoside in Aerosol-OT Reverse Micelles

  • Park, Hyoung-Ryun;Liu, Hai-Bo;Shin, Sung-Chul;Park, Jong-Keun;Bark, Ki-Min
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.981-987
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    • 2011
  • The anomalous spectroscopic properties of quercetin-3-O-rhamnoside (QCRM) and quercetin-3-O-rutinoside (QCRT) in AOT reverse micelle were studied. The excited state intramolecular proton transfer (ESIPT) occurs through the strong hydrogen bond between the -OH at position 5 and the carbonyl oxygen. Because the ESIPT can only happens in the $S_1$ state and the Franck-Condon factor involved in the $S_2\;{\rightarrow}\;S_1$ internal conversion is small, the $S_2\;{\rightarrow}\;S_o$ emission alone appears. Because the molecular planarity is improved at the interior of the micelle, the excited state intramolecular charge transfer in the $S_1$ state is extended, and the excited state is more tolerable for any quenching effects in the micelle. Therefore, an $S_1\;{\rightarrow}\;S_o$ emission was newly discovered under this micelle microenvironment. For the $S_2\;{\rightarrow}\;S_o$ emission, the quantum yields increase but the quantum yield of the $S_1\;{\rightarrow}\;S_o$ emission approximately decreases as the water concentration in the micelle increases.

DC Characteristics Analysis of Various AC loads for Hybrid Distribution (하이브리드 급전을 위한 다양한 가정용 교류부하의 직류특성연구)

  • Lee, Young-Jin;Han, Dong-Ha;Choi, Jung-Muk;Jeong, Byong-Hwan;Kim, Dong-Jin;Choe, Gyu-Ha
    • The Transactions of the Korean Institute of Power Electronics
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    • v.15 no.3
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    • pp.207-217
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    • 2010
  • Recently, the use of DC power increased due to the increased use of digital load. Power factor of input current decrease and input current harmonics increase, and conversion loss which is occurred in the AC / DC converter is a problem to provide the proper DC voltage to the device equipped with an internal AC / DC converter. Hybrid system supplies the AC power and DC power to AC load (motor load and the transformer load) and DC loads (computers, TV, LED fluorescent light) at the same time it supplies the renewable energy and utility energy taken power from Utility to user for improving the efficiency and renewable energy improvements in ease of use. This paper studies DC characteristics of traditional AC load for Hybrid distributions.

Association between Prostaglandin-endoperoxide Synthase 2 (PTGS2) Polymorphisms and Blood Pressure in Korean Population

  • Jin, Hyun-Seok;Hong, Kyung-Won;Lim, Ji-Eun;Han, Hye-Ree;Lee, Jong-Young;Park, Hun-Kuk;Oh, Berm-Seok
    • Genomics & Informatics
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    • v.6 no.3
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    • pp.110-116
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    • 2008
  • Blood pressure refers to the force exerted by circulating blood on the walls of blood vessels, and chronical elevation of blood pressure is known as hypertension. Although hypertension is affected by genetic and environmental factors, the genetic background of hypertension is not fully understood. One of the candidate genetic factors, Prostaglandin-endoperoxide synthase 2 (PTGS2), is a membrane-bound enzyme, catalyzing the conversion of arachidonic acid to prostaglandin, and recently SNPs of PTGS2 gene was associated with hypertension in Japanese population. Therefore the association of PTGS2 polymorphisms was investigated with blood pressure in healthy Korean subjects, 470 unrelated individuals randomly selected from Ansung and Ansan cohorts. The 25 SNPs of PTGS2 gene were identified by the sequencing analysis of 24 Korean samples. Among identified polymorphisms, three SNPs (rs689466, -1329A>G; rs5275, +6365T>C; rs4648308, +8806G> A) were selected for further association analysis, and rs689466 located in promoter region was associated with blood pressure as well as triglyceride level in the blood. By in silico analysis, rs689466 locates in v-Myb transcription factor binding site, and the v-Myb site disappears when the SNP is changed from A to G nucleotide. Individuals with A/G and G/G genotype in rs689466 have higher blood pressure than those with A/A genotype, and the regression p-value is 0.008 for systolic and 0.004 for diastolic blood pressure. In summary, the PTGS2 polymorphism (rs689466) is associated with blood pressure in Asian populations based on this and Japanese studies, shedding light on it as a genetic risk marker of hypertension.

Reuse of Hydrogen Sulfide by Ferric Chelate Reaction of Food Waste Anaerobic Digestion Gas, Sulfur Recovery and its Economic Evaluation (킬레이트 착화학반응에 의한 음식물폐기물 혐기소화가스 중 황화수소의 제거와 황회수 및 경제성평가)

  • Park, Young G.;Yang, Youngsun
    • Clean Technology
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    • v.20 no.4
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    • pp.367-374
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    • 2014
  • Several experiments have been done to investigate the removal of hydrogen sulfide ($H_2S$) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1-1 M Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by chelate. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed with minor potential for further pollution. As the Fe-EDTA concentration increased, the conversion rate of hydrogen sulfide increased because of the high stability of Fe-EDTA complex. pH as an important environmental factor was 9.0 for the stability of chemical complex in the oxidation of hydrogen sulfide.

Dynamic Magnetostriction Characteristics of an Fe-Based Nanocrystalline FeCuNbSiB Alloy

  • Chen, Lei;Li, Ping;Wen, Yumei
    • Journal of Magnetics
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    • v.16 no.3
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    • pp.211-215
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    • 2011
  • The dynamic magnetostriction characteristics of an Fe-based nanocrystalline FeCuNbSiB alloy are investigated as a function of the dc bias magnetic field. The experimental results show that the piezomagnetic coefficient of FeCuNbSiB is about 2.1 times higher than that of Terfenol-D at the low dc magnetic bias $H_{dc}$ = 46 Oe. Moreover, FeCuNbSiB has a large resonant dynamic strain coefficient at quite low Hdc due to a high mechanical quality factor, which is 3-5 times greater than that of Terfenol-D at the same low $H_{dc}$. Based on such magnetostriction characteristics, we fabricate a new type of transducer with FeCuNbSiB/PZT-8/FeCuNbSiB. Its maximum resonant magnetoelectric voltage coefficient achieves ~10 V/Oe. The ME output power reaches 331.8 ${\mu}W$ at an optimum load resistance of 7 $k{\Omega}$ under 0.4 Oe ac magnetic field, which is 50 times higher than that of the previous ultrasonic-horn-substrate composite transducer and it decreases the size by nearly 86%. The performance indicate that the FeCuNbSiB/PZT-8/FeCuNbSiB transducer is promising for application in highly efficient magnetoelectric energy conversion.

A Study on the Development of Digital Contents for Land Estimation (토지평가 디지털컨텐츠 개발에 관한 연구)

  • Song Eun-Jee
    • Journal of Digital Contents Society
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    • v.4 no.2
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    • pp.147-155
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    • 2003
  • The problem of the objective adequacy on land estimation has been seriously discussed with the Issue of paradigm conversion on land policy as the economy situation has been worse enough to be confused due to the sale price which could not be predicted in Korea. Especially as the data of the government land value is not recognized as the official one, the separate alternation has been adopted to calculate the value of land compensation or development allotment. Rather it has raised a question in argument that the system of the declared value does not accomplish its basic function properly on the contrary of the original purpose to unify the computation of the government land value. To reconsider the adequacy of government land value, the most crucial factor is to select the items of land estimation reasonably. In addition, it is urgently required to develop the system of digital contents to provide the data of land evaluation which most of people could trust, who are facing of the flood of information through internet.

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