• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.12
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• pp.1557-1566
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• 2004

A flame extinction phenomenon is a typical unsteady process in combustion. Flame extinction is characterized by various physical phenomena, such as convection, diffusion, and the production of heat and mass. Flame extinction can be achieved by either increasing the strain rate or curvature, by diluting an inert gas or inhibitor, or by increasing the thermal or radiant energy loss. Though the extinction is an inherently transient process, steady and quasi-steady approaches have been used as useful tools for understanding the flame extinction phenomenon. Recently, unsteady characteristics of flames have been studied by many researchers, and various attempts have been made to understand unsteady flame behavior, by using various extinction processes. Representative parameters for describing flame, such as flame temperature, important species related to reactions, and chemi-luminescence of the flame have been used as criterions of flame extinction. In these works, verification of each parameter and establishing the proper criterions of the extinction has been very important. In this study, a time-dependent flame temperature and an OH radical concentration were measured using optical methods, and the instantaneous change of the flame luminosity was also measured using a high-speed ICCD (HICCD) camera. We compare the unsteady extinction points obtained by three different methods, and we discuss transient characteristics of maximum flame temperature and OH radical distribution near the extinction limit.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.467-476
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• 1999

This paper analyzed the behavior of fixed-bed catalytic reactor (FBCR) which synthesizing maleic anhydride(MA) from the selective oxidation of n-butane. The behavior of FBCR describing convection-diffusion-reaction mechanism is examined by using two-dimensional pseudohomogeneous plug-flow transient model, with the kinetics of Langmuir-Hinshelwood type. Prediction model is composed by optimum parameter estimation from temperature profile, yield and conversion of single FBCR on operating condition variations of Sharma's pilot-plant experiment. A double FBCR with same yield and conversion for single FBCR generated a $8.96^{\circ}C$ lower hot spot temperature than a single FBCR. We could predict parametric sensitivity according to the variation of possible operating condition (temperature, concentration, volumetric flow of feed reactant and coolant flow rate) of single and double FBCR. Double FBCR showed the behavior of more operating range than single FBCR. Double FBCR with nonuniform activities could assure safety operation condition for the possible variation of operating condition. Also, double FBCR had slightly higher than the single FBCR in conversion and yield.

• International Journal of Concrete Structures and Materials
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• v.11 no.2
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• pp.199-213
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• 2017

Chloride penetration is among the main causes of corrosion initiation in reinforced concrete (RC) structures producing premature degradations. Weather and exposure conditions directly affect chloride ingress mechanisms and therefore the operational service life and safety of RC structures. Consequently, comprehensive chloride ingress models are useful tools to estimate corrosion initiation risks and minimize maintenance costs for RC structures placed under chloride-contaminated environments. This paper first presents a coupled thermo-hydro-chemical model for predicting chloride penetration into concrete that accounts for realistic weather conditions. This complete numerical model takes into account multiple factors affecting chloride ingress such as diffusion, convection, chloride binding, ionic interaction, and concrete aging. Since the complete model could be computationally expensive for long-term assessment, this study also proposes model simplifications in order to reduce the computational cost. Long-term chloride assessments of complete and reduced models are compared for three locations in France (Brest, Strasbourg and Nice) characterized by different weather and exposure conditions (tidal zone, de-icing salts and salt spray). The comparative study indicates that the reduced model is computationally efficient and accurate for long-term chloride ingress modeling in comparison to the complete one. Given that long-term assessment requires larger climate databases, this research also studies how climate models may affect chloride ingress assessment. The results indicate that the selection of climate models as well as the considered training periods introduce significant errors for mid- and long- term chloride ingress assessment.

• Composites Research
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• v.13 no.4
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• pp.33-41
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• 2000

In this research, the mathematical modeling of the formation of SiC layer on the activated carbon was studied to improve the durability and the oxidation resistance of catalyst supports. SiC layer on the activated carbon was formed by permeating SiC from dichlorodimethylsilane(DDS) into pores and depositing while the porous structure was kept. The best conditions of manufacturing the support were found by studying the characteristics of SiC/C which was modelled under various deposition conditions. Changes of the amount of deposition, the pore diameter, the surface area with time were obtained by simulating convection, diffusion and reaction in an isothermal reactor at a steady state. The uniform deposition in the pores of samples was obtained at a lower concentration of the reactant and a lower pressure. Additionally, it was observed that the pore diameter and the surface area have points of inflection at certain times of deposition, because deposition occurred on the inside surface of the pore at first and then on the outside surface of the particle.

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.2
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• pp.253-261
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• 1987

Thermoacoustic oscillation of an air column induced by heated wires is investigated analytically and experimentally. Acoustic power generation from a single heater wire is estimated based on the result of heat transfer analysis and expressed in terms of the efficiency factor indicating the conversion efficiency from heat to acoustic energy. It is shown that the efficiency factor becomes maximum when the wire radius is the order of the coustic boundary layer thickness and the flow velocity is close to the thermal diffusion velocity. Onset condition of the column oscillation is obtained by equating the acoustic power generation at the heater to the power loss due to thermoviscous dissipation at the tube wall and the convection and radiationloss at the open ends of the tube. In estimating the acoustic power generation, the heater is treated as a stretched single wire by correcting the flow velocity to take into account the interactions between adjacent heater wires. Experiment is performed by using a spiral heater of 1mm diameter in an air column of 37mm diameter. The heat input to drive the oscillation is measured and compared with the theoretical prediction. A good agreement is found between the theory and experiment, which is regarded as a substantial verification of the present analysis.

• Journal of the Korean Geotechnical Society
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• v.37 no.12
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• pp.25-31
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• 2021

Boundary conditions for thermal-hydraulic problems of soils play an essential role in the numerical accuracy. This study presents a boundary condition considering the thermo-hydraulic interaction between the ground and the atmosphere. Ground surface energy balance consists of solar radiation, ground radiation, wind convection, latent heat from water evaporation, and heat conduction to the ground. Equations for each heat flux are presented, and numerical analyses are performed in conjunction with the FEM program for the thermal-hydraulic phenomenon of unsaturated soils. Numerical results using the weather data at the Ulsan Meteorological Observatory are similar to the measured surface temperature. Latent heat caused by water evaporation during the daytime lowers the surface temperature of the bare soil, and a thermal equilibrium is reached at nighttime when the effect of the ground condition is significantly reduced. The temperature change of the surface ground is diminished at the deeper ground due to its thermal diffusion. Numerical analysis where the surface ground temperature is the primary concern requires considering the thermo-hydraulic interaction between the ground and the atmosphere.