• Title/Summary/Keyword: Controlling of Properties

Search Result 1,020, Processing Time 0.034 seconds

The Changes of the Hydrogenation Properties of Zr0.9Ti0.1Cr0.7Fe1.3 Alloy Upon the Pressure Induced Hydriding-Dehydriding Cycling (수소흡수-방출 사이클에 의한 Zr0.9Ti0.1Cr0.7Fe1.3 합금의 수소화 반응 특성의 변화)

  • Lee, Jon-Ha;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.2 no.1
    • /
    • pp.29-37
    • /
    • 1990
  • The effect of pressure cycling of $Zr_{0.9}Ti_{0.1}Cr_{0.7}Fe_{1.3}$ on the hydrogenation properties was investigated using the P-C-Isotherm curves and hydrogen absorption rate curves in the isotherm condition. The reversible hydrogen absorption capacity was decreased about 45 % after 3300 cycles. In the case of activated sample, the rate controlling steps of hydriding reaction changed from the surface reaction to the hydrogen diffusion process through hydride phase sequentially as reaction proceeded. After 3300 cycles, the sequential change of rate controlling step was same as activated one. However, the hydrogen absorption rate significantly decreased. It is suggested that the degradation of $Zr_{0.9}Ti_{0.1}Cr_{0.7}Fe_{1.3}$ can be interpreted with the formation of $ZrFe_3$ phase at the particle surface.

  • PDF

Controlling size and magnetic properties of Fe3O4 clusters in solvothermal process

  • Madrid, Sergio I. Uribe;Pal, Umapada;Jesus, Felix Sanchez-De
    • Advances in nano research
    • /
    • v.2 no.4
    • /
    • pp.187-198
    • /
    • 2014
  • Magnetite nanoparticles (MNPs) of different sizes were synthesized by solvothermal process maintaining their stoichiometric composition and unique structural phase. Utilizing hydrated ferric (III) chloride as unique iron precursor, it was possible to synthesize sub-micrometric magnetite clusters of sizes in between 208 and 381 nm in controlled manner by controlling the concentration of sodium acetate in the reaction mixture. The sub-micrometer size nanoclusters consist of nanometric primary particles of 19 - 26.3 nm average size. The concentration of sodium acetate in reaction solution seen to control the final size of primary MNPs, and hence the size of sub-micrometric magnetite nanoclusters. All the samples revealed their superparamagnetic behavior with saturation magnetization ($M_s$) values in between 74.3 and 77.4 emu/g. $M_s$. The coercivity of the nanoclusters depends both on the size of the primary particles and impurity present in them. The mechanisms of formation and size control of the MNPs have been discussed.

Thermoelectric properties and microstructures of Mg2Si0.6Sn0.4-based thermoelectric materials (Mg2Si0.6Sn0.4 열전재료의 열전특성과 미세조직)

  • Jang, Jeong-In;Ryu, Byeong-Gi;Lee, Ji-Eun;Park, Su-Dong;Lee, Ho-Seong
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2018.06a
    • /
    • pp.53-53
    • /
    • 2018
  • Thermoelectric materials can convert directly waste heat to electricity and vice versa. The improvement of the thermoelectric efficiency strongly depends on the dimensionless figure of merit, $ZT=S^2{\sigma}T/{\kappa}$, where S is the Seebeck coefficient, ${\sigma}$ is the electrical conductivity, T is the absolute temperature, and ${\kappa}$ is the thermal conductivity. The thermal conductivity consists of the electronic contribution (${\kappa}_e$) and phonon contribution (${\kappa}_{ph}$). It is very challenge to increase the power factor, $S^2{\sigma}$ and to reduce the thermal conductivity simultaneously because the power factor and electronic thermal conductivity are coupled. One strategy is to decrease the phonon thermal conductivity. The phonon thermal conductivity can be decreased by controlling the grain size and structural defects such as dislocations and twinning. In order to achieve enhancements in thermoelectric efficiency, microstructures that can form numerous interfaces have been investigated intensively for controlling the transport of charge carriers and heat carrying phonons. In this presentation, we report the heterogeneous microstructure of $Mg_2Si_{0.6}Sn_{0.4}$ thermoelectric materials and investigation of its influence on thermoelectric properties.

  • PDF

Surface Modification of Functional Titanium Oxide to Improve Corrosion Resistance (내식성 향상을 위한 기능성 타이타늄 표면 개질)

  • Park, Youngju;Jeong, Chanyoung
    • Corrosion Science and Technology
    • /
    • v.20 no.5
    • /
    • pp.256-265
    • /
    • 2021
  • Titanium is applied in various industries due to its valuable properties and abundant reserves. Generally, if a highly uniform oxide structure and a high-density oxide film is formed on the surface through anodization treatment, the utility value such as color appearance and corrosion inhibition efficiency is further increased. The objective of this study was to determine improvement of water-repellent property by controlling titanium oxide parameters such as pore size and inter-pore distance to improve corrosion resistance. Oxide film structures of different shapes were prepared by controlling the anodization processing time and voltage. These oxide structures were then analyzed using a Field Emission Scanning Electron Microscope (FE-SEM). Afterwards, a Self-Assembled Monolayer (SAM) coating was performed for the oxide structure. The contact angle was measured to determine the relationship between the shape of the oxide film and the water-repellency. The smaller the solid fraction of the surface, the higher the water-repellent effect. The surface with excellent hydrophobic properties showed improved corrosion resistance. Such water-repellent surface has various applications. It is not only useful for corrosion prevention, but also useful for self-cleaning. In addition, a hydrophobic titanium may open up a new world of biomaterials to remove bacteria from the surface.

Physical Properties and Dyeability of Fine Count Wool Yarns and Its Fabrics by Drawing Process of Fineness Control (섬도제어 연신공정에 의한 세섬화 양모 소재의 물성 연구)

  • Kim, Mikyung;Jeon, Byeongdae;Jeong, Jaeseok
    • Textile Coloration and Finishing
    • /
    • v.28 no.4
    • /
    • pp.253-270
    • /
    • 2016
  • In the wool textile industry, the necessity for technology development has been steadily raised to create improved fineness and yarn count of existing wool yarns with thick fineness for ensuring higher quality grades of wool yarn. Recently, through controlling fineness of wool yarn for making finer wool in relation with environmentally-friendly and high-sensitivity trend, a differentiated continuous drawing process where the quality of wool can be artificially manipulated has been suggested in the latest textile industry. This study investigated the basic conditions during the continuous drawing process which enable to manufacture wool yarn with fine count by controlling reducing agent treatment, physical drawing and drying after reducing agent treatment, and oxidizing agent post-treatment conditions. Furthermore, this study reviewed the drawing effects by applying the basic conditions for reduction and oxidation reaction in the drawing processes of wool/cashmere, wool/silk, wool/polyester blended yarns as well as such wool yarns. Also, in order to review the practicability, this study examined the physical properties and dyeability of drawn wool yarn applied textile materials in comparison with normal wool yarn applied textile materials.

Technology Trend of surface Wettability Control Using Layer-by-Layer Assembly Technique (다층박막법을 이용한 표면 젖음성 제어 기술 동향)

  • Sung, Chunghyun
    • Journal of Adhesion and Interface
    • /
    • v.18 no.4
    • /
    • pp.171-178
    • /
    • 2017
  • Recently, layer-by-layer (LbL) assembly has emerged as a promising fabrication technique in controlling surface wetting properties. LbL assembly technique is eco-friendly versatile technique to control the hierarchical structure and surface properties in nano- and micro-scale by employing a variety of materials (e.g., polymers, surfactants, nanoparticles, etc.). This article reviews recent progress in controlling the surface wetting using LbL technique. In particular, technical trends and research findings on fabrication and the applications of superhydrophobic, superhydrophilc, and superoleophobic/superhydrophilic LbL surfaces are extensively explained. Additionally, basic principles and fabrication methods in emerging areas such as omniphobic, self-healing, intelligent and responsive LbL surfaces are discussed.

Efficacy of Geru (red ochre) in controlling the bleeding in patients of Adolescent menorrhagia

  • Kotagasti, Tabassum
    • CELLMED
    • /
    • v.5 no.2
    • /
    • pp.12.1-12.3
    • /
    • 2015
  • Adolescent menorrhagia is defined as excessive menstrual bleeding from menarche to adolescents. It is a distressing condition both for the patient as well as for her parents. If it is not managed in time itmay pose significant health problems that may leads to blood transfusion. We determined the efficacy of Geru (Red ochre) in controlling the amount and duration of blood flow in patients of Adolescent menorrhagia. This study included 40 teenage girls, who presented with heavy bleeding during menstruation to Outpatient Department, Sameena Maternity Nursing Home, Hyderabad during the year of 2013. Assessment of each case was done by history and Pictorial Blood loss Assessment Chart (PBAC) score. Geru powder was given for 2 cycles and results were assessed. The data was analyzed statistically. The mean PBAC score before treatment was $497.04{\pm}389.92$ and after trial in $1^{st}$ and $2^{nd}$ it was found to be $471.13{\pm}162.18$ and $310.13{\pm}142.15$ respectively. On basis of results it was concluded that single unani drug Geru is enough in controlling bleeding and was found effective by its astringent and styptic properties.

Rennet-induced gels and their mechanical properties (우유의 렌넷 젤에 대한 기계적 특성)

  • Choi, Jong-Woo
    • Korean Journal of Agricultural Science
    • /
    • v.38 no.4
    • /
    • pp.711-716
    • /
    • 2011
  • Casein micelles are the basic building block of rennet-induced gels. The stiffness of these gels is increased with reaction time. This is probably due to the continuous participation of activated casein micelles into growing network. Dual binding model of casein micelles, which explains assembly of casein and colloidal calcium phosphate, can provides fairly reasonable explanation for the changes in mechanical properties of rennet-induced gels made from different milk pHs and varying colloidal calcium phosphates. The changes in stiffness of these gels would be used for controlling textural properties of cheeses.

The Effect of Pressure on Liquid Segregation in Direct Rheo-Forging Process of Aluminum Alloys (알루미늄 소재의 레오로지 직접단조공정에서 가압력이 액상 편석에 미치는 영향)

  • Oh, S.W.;Bae, J.W.;Kang, C.G.
    • Transactions of Materials Processing
    • /
    • v.16 no.3 s.93
    • /
    • pp.178-186
    • /
    • 2007
  • Rheo-forging process of aluminum alloy is suitable for large parts of net shape without defects and excellent mechanical properties in comparison with conventional die casting and forging process. To control the microstructure of the product with high mechanical properties in rheo-forming, solid fraction is required to prevent porosity and liquid segregation. Therefore, in rheo-forging process, die shape, pressure type and solid fraction are very important parameters. The defects such as porosity, liquid segregation and unfitting phenomena occur during rheo-forging process. To prevent these defects, mechanical properties and microstructure analysis of samples versus the change of pressure are carried out and the problem and its solutions are proposed. Also, the mechanical properties versus various pressures were compared with and without heat treatment. The alloys used for rheo-forming are A356 and 2024 aluminum alloy. The rheology material is fabricated by electromagnetic process with controlling current and stirring time.

Experimental analysis on rheological properties for control of concrete extrudability

  • Lee, Hojae;Kim, Jang-Ho Jay;Moon, Jae-Heum;Kim, Won-Woo;Seo, Eun-A
    • Advances in concrete construction
    • /
    • v.9 no.1
    • /
    • pp.93-102
    • /
    • 2020
  • In this study, we examined the relationship among the rheological properties, workability, and extrudability in the construction of concrete structures using additive manufacturing. We altered the component materials (binder type, water-binder (W/B) ratio, sand ratio) to assess their effect on the rheological properties experimentally. The results indicated that the W/B and sand ratios had the largest effect on the rheological properties. In particular, when the sand ratio increased, it indicated that adjusting the sand ratio would facilitate control over the rheological properties. Additionally, we compared the rheological properties with the results of a traditional workability evaluation, namely the table flow test. This indicated the possibility of inferring the rheological properties by using traditional methods. Finally, we evaluated extrusion quantity according to table flow. The extrusion rate was 350 g/s for a flow of 210 mm and 170 g/s for a flow of 130 mm, indicating that extrusion rate increased as flow increased; however, we concluded that a flow standard of approximately 140-160 mm is suitable for controlling the actual extrusion quantity and rate.