• 대기
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• 제28권2호
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• pp.175-185
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• 2018

Characteristics of precipitation response to enhanced aerosols have been investigated during the severe haze events observed in Korea for 2011 to 2016. All 6-years haze events are classified into long-range transported haze (LH: 31%), urban haze (UH: 28%), and yellow sand (YS: 18%) in order. Long-range transported one is mainly discussed in this study. Interestingly, both LH (68%) and YS (87%) appear to be more frequently accompanied with precipitation than UH (48%). We also found out the different timing of precipitation for LH and YS, respectively. The variations of precipitation frequency for the LH event tend to coincide with aerosol variations specifically in terms of temporal covariation, which is in contrast with YS. Increased aerosol loadings following precipitation for the YS event seems to be primarily controlled by large scale synoptic forcing. Meanwhile, aerosols for the LH event may be closely associated with precipitation longevity through changes in cloud microphysics such that enhanced aerosols can increase smaller cloud droplets and further extend light precipitation at weaker rate. Notably, precipitation persisted longer than operational weather forecast not considering detailed aerosol-cloud interactions, but the timescale was limited within a day. This result demonstrates active interactions between aerosols and meteorology such as probable modifications of cloud microphysics and precipitation, synoptic-induced dust transport, and precipitation-scavenging in Korea. Understanding of aerosol potential effect on precipitation will contribute to improving the performance of numerical weather model especially in terms of precipitation timing and location.

• 한국식품저장유통학회지
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• 제3권1호
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• pp.83-92
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• 1996

This study was conducted to estimate the shelf-life of 'Fuji' apples (Malus domestica Borkh) after CA storage. Apples stored In 1%O2+3%CO2, 2%O2+3%CO2 and 3%O2+3%CO2 at 2$^{\circ}C$ and 4$^{\circ}C$ for 8 months were stored in air at 10$^{\circ}C$, 80-85% RH for 16days. As a result of objective analysis, apples stored at 2$^{\circ}C$ wert mort effective in retarding the loss of weight flesh firmness, titratable acidity and peel color than those stored at 4$^{\circ}C$, but not the loss of soluble solid. Among storage atmospheres, 1%O2+3%CO2 at 2$^{\circ}C$ was more effective in retarding the loss of flesh firmness and green color than other atmospheres. Shelf-life of apples kept at 2$^{\circ}C$ estimated above 16 days. The contents of acetaldehyde and ethanol were not observed tn make large difference between storage conditions, but ethanol content of apples stored in 3%O2+3%CO2 at 4$^{\circ}C$ was Increased slightly for 16 days. According to sensory evaluations, apples stored at 2$^{\circ}C$ were significantly harder, juicier and more acid than chose stored at 4$^{\circ}C$. Particularly, high scores of apples stored in 1% and 2%O2+3%CO2 at 2$^{\circ}C$ Persisted for 16 days. Juiciness, hardness acidity and sweetness were related to the flesh firmness and titratable acidity. Overall acceptability was closely related to juiciness and hardness.

• Corrosion Science and Technology
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• 제2권3호
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• pp.141-147
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• 2003

Sputter-deposited Nb-Al-Cr alloys. $3-5{\mu}m$ thick, have been prepared on quartz substrates as oxidation-and sulfidation-resistant materials at high temperatures. The oxidation or the alloys in the $Ar-O_2$ atmosphere of an oxygen partial pressure of 20 kPa follows approximately the parabolic rate law, thus being diffusion controlled. Their oxidation rates are almost the same as or even lower than those ofthc typical chromia-forming alloys. The multi-lavered oxide scales are formed on the ternary alloys. The outermost layer is composed of $Cr_2O_3$, which is"mainly responsible for the high oxidation'resistance of these alloys. In contrast to sputter-deposited Cr-Nb binary alloys reported previously, the inner layer is not porous. TEM observation as well as EDX analysis indicates that the innermost layer is a mixture of $Al_2O_3$ and niobium oxide. The dispersion of $Al_2O_3$ in niobium oxide may be attributable to the prevention of the formation of the porous oxide layer. The sulfidation rates of the present ternary alloys arc higher than those of the sputter-deposited Nb-AI binary alloys, but still several orders of magnitude lower than those of conventional high temperature alloys. Two-layered sulfide scales are formed, consisting of an outer $Al_2S_3$ layer containing chromium and an inner layer composed of $NbS_2$ and a small amount of $Cr_2S_3$. The presence of $Cr_2S_3$ in the inner protective $NbS_2$ layer may be attributed to the increase in the sulfidation rates.

• Corrosion Science and Technology
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• 제15권5호
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• pp.226-236
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• 2016

316L stainless steels have been widely used in many engineering fields, because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion and stress corrosion cracking etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled by methods such as the lowering of carbon content, solution heat treatment. This work focused on the intergranular corrosion mechanism of slightly-sensitized and Ultrasonic Nano-crystal Surface Modification (UNSM)-treated 316L stainless steel. Samples were sensitized for 1, 5, and 48 hours at $650^{\circ}C$ in $N_2$ gas atmosphere. Subsequently UNSM treatments were carried out on the surface of the samples. The results were discussed on the basis of the sensitization by chromium carbide and carbon segregation, the residual stress and grain refinement. Even though chromium carbide was not precipitated, the intergranular corrosion rate of 316L stainless steel was drastically increased with aging time, and it was confirmed that the increased intergranular corrosion rate of slightly-sensitized (not carbide formed) 316L stainless steel was due to the carbon segregation along the grain boundaries. However, UNSM treatment improved the intergranular corrosion resistance of aged stainless steels, and its improvement was due to the reduction of carbon segregation and the grain refinement of the outer surface, including the introduction of compressive residual stress.

• Corrosion Science and Technology
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• 제9권2호
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• pp.81-86
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• 2010

The mechanisms of selective oxidation of intercritically annealed CMnAl TRIP steels in a Continuous Galvanizing Line (GCL) were studied by cross-sectional observation of the surface and sub-surface regions by means of High Resolution Transmission Electron Microscopy (HR-TEM). The selective oxidation and nitriding of an intercritically annealed CMnAl TRIP steel in a controlled dew point 10%$H_2+N_2$ atmosphere resulted in the formation of c-xMnO.$MnO_2$ (1${\leq}$x<3) and c-xMnO.$Al_2O_3$ ($x{\geq}1$) particles on the steel surface. Single crystal c-xMnO.$SiO_2$ ($2{\leq}x{\leq}4$) oxide particles were also observed on the surface. A thin film of crystalline c-xMnO.$SiO_2$ (2${\leq}$x<3) and c-xMnO.$Al_2O_3$ ($x{\geq}1$) was present between these particles. In the sub-surface region, internal oxidation, nitriding and intermetallic compound formation were observed. In the first region, large crystalline c-xMnO.$SiO_2$ ($1{\geq}x{\geq}2$) and c-xMnO.$Al_2O_3$ ($x{\geq}1$) oxides particles were present. In the second region, c-AlN particles were observed, and in a third region, small $MnAl_x$ (x>1) intermetallic compound particles were observed.

• 한국세라믹학회지
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• 제40권3호
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• pp.241-248
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• 2003

고체산화물 연료전지용 음극소재로 사용되는 다공성 NiO-YSZ 소재의 강도를 향상시키기 위하여 $Y_2$O$_3$첨가제의 양 및 기공전구체로 첨가되는 탄소첨가제의 종류를 변화시켰으며, 이에 따른 기계적 강도와 기공율, 전기전도도를 측정하였다. $Y_2$O$_3$첨가제의 양은 8 mol%와 10 mo1%로 각각 변화시켰으며, 기공전구체는 활성탄과 카본블랙의 영향을 고찰하였다. 그 결과 카본블랙을 기공전구체로 사용하였을 경우 활성탄을 사용한 경우에 비해 기계적 강도가 크게 향상되었으며, 상대적으로 고온의 소결온도에서 제조된 10 mo1%의 $Y_2$O$_3$가 첨가된 NiO-YSZ 음극소재가, 8 mol%가 첨가된 소재에 비하여 상대적으로 우수한 강도를 나타내었다. 10 mo1%의 $Y_2$O$_3$와 카본블랙이 첨가된 음극소재는 전기전도도 값에 있어서도 $700^{\circ}C$~100$0^{\circ}C$의 온도범위에서 $10^2$~$10^3$S/cm의 양호한 값을 나타내는 것으로 평가되었다.

• 한국세라믹학회지
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• 제49권6호
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• pp.549-555
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• 2012

Silicon carbide(SiC) exhibits many unique properties, such as high strength, corrosion resistance, and high temperature stability. In this study, a SiC-fiber web was prepared from polycarbosilane(PCS) solution by employing the electrospinning process. Then, the SiC-fiber web was pyrolyzed at $1800^{\circ}C$ in argon atmosphere after it was subjected to a thermal curing. The SiC-fiber web (ground web)/phenolic resin (resol) composite was fabricated by hot pressing after mixing the SiC-fiber web and the phenolic resin. The SiC-fiber web composition was controlled by changing the fraction of filler (filler/binder = 9:1, 8:2, 7:3, 6:4, 5:5). Thermal conductivity measurement indicates that at the filler content of 60%, the thermal conductivity was highest, at 6.6 W/mK, due to the resulting structure formed by the filler and binder being closed-packed. Finally, the microstructure of the composites of SiC-fiber web/resin was investigated by FE-SEM, EDS, and XRD.

• 한국세라믹학회지
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• 제48권5호
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• pp.447-453
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• 2011

The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

• 한국세라믹학회지
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• 제51권6호
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• pp.560-565
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• 2014

Alumina nano-asperites were grown on plate-like alumina particles of which the surface had been covered with a capping agent to control the asperite formation sites on the particles. Utilized alumina source for asperite was nano sized ${\gamma}$-alumina, which was prepared by calcination of $Al(OH)_3$ at $600^{\circ}C$; silica suspension was used as the capping agent. Plate like alumina particles were covered by silica suspension and continuously heat-treated to $900^{\circ}C$ with nano sized ${\gamma}$-alumina, as the source material, under molten-salt atmosphere. Asperite growing site were controlled by the degree of coating of the capping agent; 10-20 nanosize of ${\theta}$-alumina were formed on the particle surface. On the other hand, alumina particles without capping agent were observed to undergo only step-like crystal growth during heat-treatment.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2002년도 Proceedings of International Symposium on Remote Sensing
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• pp.750-750
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• 2002

The Airship PKNU is a roughly 12 m (32 ft) long blimp, filled with helium, whose two-gasoline power(3hp per engine) are independently radio controlled. The motors and propellers can be tilted and are attached to the gondola through an axle and supporting braces. Four stabilizing fins are mounted at the tail of the airship. To fill in the helium, a valve is placed at the bottom of the hull. The inaugural flight was on jul. 31.2002 at the Pusan, S.korea Most environment monitoring system\ problem use satellite image. But, Low resolution satellite image (multi-spectral) : 1km ∼ 250 m ground resolutions is lows. So, detail information acquisition is hard at the complex terrain. High resolution satellite image (black and white) 30m : The ground resolution is high. But it is high price, visit cycle and delivery time is long So. We want make high accuracy airship photogrammetry system. This airship can catch picture Multi. spectral Aerial photographing (visible, Near infrared and thermal infrared), and High resolution (over 6million pixel). It can take atmosphere datum (Temperature (wet bulb, dew point, general), Pressure (static, dynamic), Humidity, wind speed). this airship is very Quickness that aircraft install time is lower than 30 minutes, it is compact and that conveyance is easy. High-capacity save image (628 cut per 1time (over 6million and 4band(R,G,B,NIR)) and this airship can save datum this High accuracy navigatin (position and rotate angle) by DGPS tech. and Gyro system. this airship will do monitor about red-tide, sea surface temperate, and CH-A, SS and etc.