• Title/Summary/Keyword: Control Transition

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A Semi-Interpenetrating Network for Temperature-Sensitive Polymer System

  • Yuk, Soon-Hong;Cho, Sun-Hang
    • Macromolecular Research
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    • v.8 no.2
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    • pp.89-94
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    • 2000
  • A semi-interpenetrating network (IPN) was prepared for a temperature-sensitive polymer system composed of sodium alginate and poly (N, N-dimethylaminoethyl methacrylate (DMAEMA)-co-ethyl acrylamide (EAAm)). The role of sodium alginate is to provide crosslinked network and that of poly(DMAEMA-co-EAAm) is to provide temperature responsiveness to the polymer system. Semi-IPN gel shows temperature-induced swelling transition at the same temperature of the lower critical solution temperature of poly(DMAEMA-co-EAAm) and its swelling kinetics is manipulated by the control of crosslinking densitv.

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Phase Transition and Relaxation Properties of Nonlinear-Optical KTP Single Crystal (비선형광학 단결정 KTP의 상전이 및 완화특성에 관한 연구)

  • Choi, Byung-Chun
    • Journal of Sensor Science and Technology
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    • v.7 no.6
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    • pp.386-393
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    • 1998
  • We have carried out the measurements of complex dielectric constants with impedance/gain-phase analyzer using capacitor method and the experiments of high temperature X-ray powder diffraction with X-ray diffractometer using ${\theta}-2{\theta}$ scan method for the KTP single crystal which has the premium nonlinear optical properties. From the results of high temperature X-ray powder diffraction experiments, we have found that KTP does not undergo structural phase transition below $900^{\circ}C$. It is clear that KTP undergoes structural phase transition around $900^{\circ}C$ and belongs to orthorhombic above $900^{\circ}C$ still. However, we have applied phenomenological relation of dielectric relaxation to the results of complex dielectric measurement and have found that relaxation mechanism of KTP well satisfies the Cole-Cole relation over the temperature range from $-78^{\circ}C$ to $200^{\circ}C$. And also the relaxation time well satisfies the Vogel-Fulcher relation. It is regarded that the hopping and thermally activated diffusion mechanism may control the conduction behavior of KTP above $200^{\circ}C$.

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Control of Working Temperature of Isothermal Magnetic Entropy Change in La0.8Nd0.2(Fe0.88Si0.12)13 by Hydrogen Absorption for Magnetic Refrigerants

  • Fujieda, S.;Fujita, A.;Fukamichi, K.;Suzuki, S.
    • Journal of Magnetics
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    • v.18 no.2
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    • pp.150-154
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    • 2013
  • $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ and their hydrides were investigated to obtain large magnetocaloric effects (MCEs) in a wide temperature range, including room temperature, for applications in magnetic refrigents. Since the magnetization change due to the itinerant-electron metamagentic (IEM) transition for $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ becomes larger with increasing z, the isothermal magnetic entropy change ${\Delta}S_m$ and the relative cooling power (RCP) are enhanced. In addition, the Curie temperatrue $T_C$ of $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}$ is increased from 193 to 319 K by hydrogen absorption, with the IEM transition. The maximum value of $-{\Delta}S_m$, $-{\Delta}S{_m}^{max}$, in a magnetic field change of 2 T for $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}H_{1.1}$ is about 23 J/kg K at $T_C$ = 288 K, which is larger than that of 19 J/kg K at $T_C$ = 276 K for $La(Fe_{0.88}Si_{0.12})_{13}H_{1.0}$. The value of RCP = 179 J/kg of the former is also larger than 160 J/kg of the latter. It is concluded that the partial substitution of Nd improves MCEs in a wide temperautre range, including room temperature.

Thermo-Sensitive Polyurethane Membrane with Controllable Water Vapor Permeation for Food Packaging

  • Zhou, Hu;Shit, Huanhuan;Fan, Haojun;Zhou, Jian;Yuan, Jixin
    • Macromolecular Research
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    • v.17 no.7
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    • pp.528-532
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    • 2009
  • The size and shape of free volume (FV) holes available in membrane materials control the rate of gas diffusion and its permeability. Based on this principle, a segmented, thermo-sensitive polyurethane (TSPU) membrane with functional gate, i.e., the ability to sense and respond to external thermo-stimuli, was synthesized. This smart membrane exhibited close-open characteristics to the size of the FV hole and water vapor permeation and thus can be used as smart food packaging materials. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), positron annihilation lifetimes (PAL) and water vapor permeability (WVP) were used to evaluate how the morphological structure of TSPU and the temperature influence the FV holes size. In DSC and DMA studies, TSPU with a crystalline transition reversible phase showed an obvious phase-separated structure and a phase transition temperature at $53^{\circ}C$ (defined as the switch temperature and used as a functional gate). Moreover, the switch temperature ($T_s$) and the thermal-sensitivity of TSPU remained available after two or three thermal cyclic processes. The PAL study indicated that the FV hole size of TSPU is closely related to the $T_s$. When the temperature varied cyclically from $T_s-10{\circ}C$ to $T_s+10^{\circ}C$, the average radius (R) of the FV holes of the TSPU membrane also shifted cyclically from 0.23 to 0.467 nm, exhibiting an "open-close" feature. As a result, the WVP of the TSPU membrane also shifted cyclically from 4.30 to $8.58\;kg/m^2{\cdot}d$, which produced an "increase-decrease" response to the thermo-stimuli. This phase transition accompanying significant changes in the FV hole size and WVP can be used to develop "smart materials" with functional gates and controllable water vapor permeation, which support the possible applications of TSPU for food packaging.

A Research for China's Corruption Problem and the Government's Counter Measures (중국의 부패상과 정부의 대응에 관한 연구)

  • Chun, Ka-Lim
    • International Area Studies Review
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    • v.12 no.2
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    • pp.351-377
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    • 2008
  • Corruption in China became increasingly serious during the early period of its social transition, resulting in severe economic losses and huge challenges to China's government institution, as well as gradually becoming socially widespread. Recently. China's political corruption is an outcome of the attenuated political control, which has been caused by a systemic change from planned economy to market economy since 1978, and the lack of institutionalization to relieve such transition. Besides, the immature market system and state's intervention in the economy are other factors for the corruption. In short, current China's corruption can be regarded as a structuralized phenomenon. This article identified such circumstance by analyzing the scope, degree, and scale of the corruption. Overall assessment of the some factors suggests that present economic modernization is a principal cause for Chinese corruption while the other factors-monopoly power system in the Chinese Communist Party and the transformation of connection-are important but secondary.

Research Trends on Interface-type Resistive Switching Characteristics in Transition Metal Oxide (전이 금속 산화물 기반 Interface-type 저항 변화 특성 향상 연구 동향)

  • Dong-eun Kim;Geonwoo Kim;Hyung Nam Kim;Hyung-Ho Park
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.4
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    • pp.32-43
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    • 2023
  • Resistive Random Access Memory (RRAM), based on resistive switching characteristics, is emerging as a next-generation memory device capable of efficiently processing large amounts of data through its fast operation speed, simple device structure, and high-density implementation. Interface type resistive switching offer the advantage of low operation currents without the need for a forming process. Especially, for RRAM devices based on transition metal oxides, various studies are underway to enhance the memory characteristics, including precise material composition control and improving the reliability and stability of the device. In this paper, we introduce various methods, such as doping of heterogeneous elements, formation of multilayer films, chemical composition adjustment, and surface treatment to prevent degradation of interface type resistive switching properties and enhance the device characteristics. Through these approaches, we propose the feasibility of implementing high-efficient next-generation non-volatile memory devices based on improved resistive switching properties.

Wide-bandwidth SQUID Current Amplifier and Control Electronics for X-ray Microcalorimeter (X-선 미소열량계 신호 검출을 위한 광대역 SQUID 전류증폭기와 조절 회로)

  • 김진목;이용호;권혁찬;김기웅;박용기
    • Progress in Superconductivity
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    • v.5 no.1
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    • pp.31-37
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    • 2003
  • Wide-bandwidth SQUID current amplifier and its control electronics have been constructed for detecting pulse outputs of a superconducting microcalorimeter. The current amplifier made of a double relaxation oscillation SQUID (DROS) has a bandwidth of 1.2 MHz and typical white noise level of about 6 pA/(equation omitted) Hz. To increase the dynamic range of the current amplifier, the flux-locked loop (FLL) has additional circuits to reset the integrator and to count reset numbers which present the number of passed flux quanta. In this system, dynamic range covers from -65 mA to +65 mA. SQUID electronics are controlled by software to get the optimum FLL condition, and to control the current to bias the transition edge sensor (TES). The electronics are shielded from the outside electromagnetic noises by using an aluminum case of 66 mm ${\times}$ 25 mm ${\times}$ 100 mm, and consist of 2 separate printed-circuit-boards for the current amplifier and the control electronics, respectively. The SQUID current amplifier and its control electronics will be used in TESs for detecting photons such as UV and X-ray with high energy resolution.

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Analysis of Dynamic Characteristics of Fluidic Thrust Vector Control for the Over-expanded Supersonic Jet (과팽창 초음속제트의 방향 제어를 위한 유체역학적 제어의 동특성 연구)

  • Heo, Jun-Young;Yoo, Kwang-Hee;Cho, Min-Kyung;Sung, Hong-Gye;Lee, Yeol;Jeon, Young-Jin;Cho, Seung-Hwan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.123-127
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    • 2009
  • The purpose of this research is to investigate the dynamic characteristics of fluidic thrust vector control using the co-flow injection. In previous research, both numerical and experimental approaches for steady state were conducted to investigate operation-parameters and detail flow structure of the fluidic thrust vector control system. Based upon the previous results, numerical unsteady calculation was conducted to analyze the dynamic characteristics of jet up- and down-ward vectoring so that the transition time and the pressure distribution along the wall, and so on were investigated.

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A Study on the Start-Up Scheme of Direct Vector Controlled Induction Motor System (유도전동기의 직접 벡터제어 시스템에서 기동기법에 관한 연구)

  • 전태원;최명규;유우종
    • The Transactions of the Korean Institute of Power Electronics
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    • v.5 no.5
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    • pp.427-434
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    • 2000
  • The paper proposes a zero speed start-up scheme of direct rector controlled induction motor drive without any torque jerk. At standstill condition, a method is derived to calculate a stator flux with only stator current. The programmable 3-stage low pass filters with programmable time constants is used in order to solute the problem of integration for stator flux estimation in the direct vector control mode. Due to the time delay of 3-stage low pass filter, the status flux decreases rapidly and also the torque jerk occurs during the transition from standstill mode to the direct rector control mode. A feedforward control strategy of the stator flux is suggested to prevent the torque jerk at start-up. Through results of simulation and experiment with 32 bit DSP, the performance of the start-up scheme is verified.

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