• Environmental Engineering Research
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• v.19 no.2
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• pp.123-130
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• 2014

Percolation is the important process of extracting the soluble constituents of a fine mesh, porous substance by passage of a liquid through it. In this study, bio-wastes were percolated under various conditions through continuous percolation processes, and the energy potential of percolate was evaluated. The representative bio-wastes from the K composting plant in Darmstadt, Germany were used as the sample for percolation. The central objective of this study was to determine the optimal amount of process water and the optimum duration of percolation through the bio-wastes. For economic reasons, the retention time of the percolation medium should be as long as necessary and as short as possible. For the percolation of the bio-wastes, the optimal percolation time was 2 hr and maximum percolation time was 4 hr. After 2 hr, more than two-thirds of the organic substances from the input material were percolated. In the first percolation process, the highest yields of organic substance were achieved. The best percolation of the bio-wastes was achieved when the process water of 2 L for the first percolation procedure and then the process water of 1.5 L for each further percolation procedure for a total 8 L for all five procedures were used on 1,000 g fresh bio-waste. The gas formation potentials of 0.83 and $0.96Nm^3/ton$ fresh matter (FM) were obtained based on the percolate from 1 hr percolation of 1,000 g bio-waste with the process water of 2 L according to the measurement of the gas formation in 21 days (GB21). This method can potentially contribute to reducing fossil fuel consumption and thus combating climate change.

• Carbon letters
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• v.15 no.2
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• pp.117-124
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• 2014

Conductive polymer composites (CPCs) consist of a polymeric matrix and a conductive filler, for example, carbon black, carbon fibers, graphite or carbon nanotubes (CNTs). The critical amount of the electrically conductive filler necessary to build up a continuous conductive network, and accordingly, to make the material conductive; is referred to as the percolation threshold. From technical and economical viewpoints, it is desirable to decrease the conductive-filler percolation-threshold as much as possible. In this study, we investigated the effect of polymer/conductive-filler interactions, as well as the processing and morphological development of low-percolation-threshold (${\Phi}c$) conductive-polymer composites. The aim of the study was to produce conductive composites containing less multi-walled CNTs (MWCNTs) than required for pure polypropylene (PP) through two approaches: one using various mixing methods and the other using immiscible polymer blends. Variants of the conductive PP composite filled with MWCNT was prepared by dry mixing, melt mixing, mechanofusion, and compression molding. The percolation threshold (${\Phi}c$) of the MWCNT-PP composites was most successfully lowered using the mechanofusion process than with any other mixing method (2-5 wt%). The mechanofusion process was found to enhance formation of a percolation network structure, and to ensure a more uniform state of dispersion in the CPCs. The immiscible-polymer blends were prepared by melt mixing (internal mixer) poly(vinylidene fluoride) (PVDF, PP/PVDF, volume ratio 1:1) filled with MWCNT.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.4
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• pp.310-317
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• 2016

This study aimed to evaluate the nutrient load balance from rice paddy fields with different topographies, alluvial plain and local valley. Continuous monitoring from May to September, 2013 was conducted for water quantification and qualification from alluvial plain in Yeoju region (32 ha) and local valley in Jincheon region (24 ha). The discharge rates of T-N from the alluvial plain were 57.2, 5.84, 22.7, and $5.20kg\;ha^{-1}$ for irrigation, precipitation, drainage, and percolation, respectively. In case of local valley, T-N loads were 34.6, 4.73, 21.1, and $4.15kg\;ha^{-1}$ for irrigation, precipitation, drainage, and percolation, respectively. In contrary, the T-P loads from the alluvial plain were 2.23, 2.22, 2.54, and $0.41kg\;ha^{-1}$ for irrigation, precipitation, drainage, and percolation, respectively. In case of local valley, T-P loads were 1.44, 1.57, 1.82, and $0.34kg\;ha^{-1}$ for irrigation, precipitation, drainage, and percolation, respectively. The nutrient contents in drainage water were influenced by the amount of waters, rainfall, and surface drainage water. The Pearson correlation analysis showed that rainfall was significantly correlated with nutrient loads from July to August due to the amount of runoff in local valley paddy field, and irrigation was related with nutrient loads of drainage from July to August. This study showed that paddy rice farming in alluvial plain and local valley might be beneficial to water quality protection.

• Bulletin of the Korean Chemical Society
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• v.26 no.11
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• pp.1723-1727
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• 2005

A generalized fractional diffusion equation (FDE) is presented, which describes the time-evolution of the spatial distribution of a particle performing continuous time random walk (CTRW) on a fractal lattice. For a case corresponding to the CTRW with waiting time distribution that behaves as $\psi(t) \sim (t) ^{-(\alpha+1)}$, the FDE is solved to give analytic expressions for the Green’s function and the mean squared displacement (MSD). In agreement with the previous work of Blumen et al. [Phys. Rev. Lett. 1984, 53, 1301], the time-dependence of MSD is found to be given as < $r^2(t)$ > ~ $t ^{2\alpha/dw}$, where $d_w$ is the walk dimension of the given fractal. A Monte-Carlo simulation is also performed to evaluate the range of applicability of the proposed FDE.

• Polymer(Korea)
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• v.35 no.6
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• pp.543-547
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• 2011

A study has been done to enhance the mechanical properties and processability of electrically conductive polyaniline(PANI) without the polymer's structural alternation. Functionalized acid doped PANI (PANI-DBSA) was prepared by an emulsion polymerization, and dodecylbenzenesulfonic acid (DBSA) played both roles of surfactant and dopant. Also, PANI-DBSA was solution cast blended with high impact polystyrene (HIPS) to produce PANI-DBSA/HIPS blend film. The structure and electrical properties of the conducting polymer blends were observed through UV-vis and FTIR/ATR spectroscopy. A study of the blend was carried by focusing on observation of mechanical and electrical properties based on dispersibility and changes in polymer morphology. The conductivity of the blends was increased by increasing the content of PANI-DBSA, and the sudden increase of conductivity to $3.5{\times}10^{-4}$ S/cm was observed even under a low content of 9 wt%. There was a strong association of continuous network formation with percolation and conductivity in the conducting polymer blends.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.3
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• pp.164-171
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• 2005

The aim of this study was to evaluate the load of nutrient from paddy fields. Water management practices that can reduce eutrophication and meet water quality requirements will also be addressed. Continuous monitoring from May to September in 2002 and 2003 was conducted for water quantification and qualification at the intensive paddy fields in Icheon, Gyunggi province of Korea. Water balance and concentration variation of nitrogen and phosphorus in the water were independently compared for water quality assessment at each rice cultivation period. Rice land preparation and transplanting periods usually marked the highest water demand when compared to other periods of cultivation. Overall, a greater net irrigation ratio was observed during the transplanting period in 2002 (92.3%) and 2003 (87.2%). The measured total N loads of precipitation, irrigation, drainage, and percolation during the rice cultivation period were 9.9, 41.6, 22.1, and $5.5kg\;ha^{-1}$ for 2002 and 15.8, 55.4, 17.3, and $7.5kg\;ha^{-1}$ for 2003, respectively. The measured total P loads of precipitation, irrigation, drainage, and percolation during the rice cultivation period were 2.1, 13.0, 3.6, and $1.8kg\;ha^{-1}$ for 2002 and 1.6, 15.0, 5.0, and $1.2kg\;ha^{-1}$ for 2003, respectively. Daily nutrient load followed the pattern of surface drainage water, but this pattern was changed by rainfall events. The nutrient load in drainage water depends on rainfall and surface drainage water amount from the paddy fields. Interestingly, the load of total N and total P output was smaller than the input load due to the natural infiltration that Occurred during the rice cultivation period. It is concluded that the paddy fields have a beneficial effect on the ecosystem and can reduce eutrophication in the water.

• Korean Journal of Soil Science and Fertilizer
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• v.23 no.2
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• pp.107-113
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• 1990

In comparision with calcium sulphate, the effect of calcium-carbonate, -silicate and -hydroxide on desalinization of tidal saline soil was investigated in a continuous leaching column experiments after mixing with an equivalent amount of Ca to sodium plus magnessium in the saline soil. One half of liming materials was mixed to the top one-tenth of column soil and the remainder was spread on the surface. Results obtained are as follows ; 1. Gypsum made easy to percolate and desaline (Na) tidal marine soil but accumulated magnessium in subsoil. 2. $Ca(OH)_2$, $CaCO_3$, and $CaSO_3$ precipitated Mg in the soil which limes were mixed, but they washed down magnessium more severely from the immediate bellow the limed soil and less from the subsequent soil layers. This leaching was more severer at the treatment of $Ca(OH)_2$and lowest at the treatment of $CaSiO_3$. 3. The alkalinity of lime in addition to the dissociation of exchangeable Na raised pH of limed leached tidal soil and slowed down the percolation rate which retarded desalining Na from limed saline soils. This effect was most severe in the $Ca(OH)_2$ treated soil. 4. pH of leached soils was correlated possitively with exchangeable Na and negatively with exchangeable Mg giving follwing relationship pH= 7.77+0.489 Na/Mg r = 0.845.