• 한국지구물리탐사학회:학술대회논문집
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• 2001.09a
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• pp.122-140
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• 2001

We have applied the geophysical survey, mainly electric and electromagnetic (EM) methods, to a test site contaminated by hydrocarbon waste disposal and local spill. The multi-frequency, moving source & receiver EM survey along with ground penetrating radar (GPR) showed a fairly good performance in detection of buried metal pipes and objects. Magnetic survey measuring vertical and horizontal gradients were so sensitive to the small metallic objects spread over the surface that it's hard to discriminate the buried pipe. We chose electrical resistivity, EM and GPR survey to examine the soil contamination. Depth slices of resistivity distribution as the results of the inversion of resistivity and EM data coincided each other and closely matched the contaminated area determined by chemical analysis of the soil samples. GPR images did not show the reflection events related with contamination plume since there are no distinct spill in this site. We inferred the contamination using the penetration depth of the GPR energy, which could be used as auxiliary information to the resistivity and EM results. We summarized the applicability of each survey methods based on this results and proposed a desirable survey scheme for the determination of hydrocarbon contaminated site.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.158-161
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• 2004

Chlorinated aliphatic hydrocarbons (CAHs) especially perchlorethylene (PCE) and trichlooethylene (TCE) are common groundwater contaminants in Korea. PCE and TCE were often reductively dechiorinated in an aquifer. Several isolates dechlorinate PCE to TCE or cis-1,2 dichloroethylene (c-DCE) were obtained from contaminated and pristine sites in USA and Europe. However in Korea, no information on indigenous microorganism being involved in reductive dechlorination of PCE and TCE is available and different dechlorinating microorganisms might be reside in Korea, since geochemical, and hydrogeological conditions are different, compared to those in the other sites. So we evaluate that: 1) if reductive dechlorinating microorganisms are present in PCE-contaminated site in Korea, 2) if so, what kinds of microorganisms are present; 3) to what extent PCE is reductively dechlorinated. As a results in some PCE-contaminated aquifers in Korea other dechlorinating microorganisms but Dehalococcoides ethenogenes may be responsible for PCE dechlorination. More detailed molecular works are required to evaluate that different dechlorinating microorganisms would reside in Korea.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1999.10a
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• pp.28-31
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• 1999

The purpose of this study is to see the effect of microbial population and dynamics of the indigeonous microorganisms on hydrocarbon contaminated areas. The microbial structures and activities to determine the microbial capabilities of the contaminated sites are very important for the remedial action technology selection. Throughout microbial studies on different conditions by ETS(Electron Transport System) and microbial activity analysis, it was found that aeration and water contents are the most important factors in this site remediation. According to test results, Burkholderia spp. was dominant species, and acclimation is also an important factor for the accerelated biodegradation.

• Journal of Korea Soil Environment Society
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• v.5 no.1
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• pp.13-23
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• 2000

The effects of operating condition of soil vapor extraction system and the characteristics of site on the remediation of oil contaminated soil were investigated. Thorough investigation showed that the site was contaminated with gasoline leaked from underground storage tank and the maximum concentration of BTEX and TPH were 1,081 ppm and 5,548 ppm respectively. The leaked gasoline were diffused to 6m deep and the area and volume of the polluted soil were assumed to 170$m^2$ and 1,000$\textrm{m}^3$respectively. The site were consisted of three different vertitical layers, the top reclaimed sandy soil between the earth surface and 3~4m deep, middle silty sand between 3~4m and 6m deep, and the bottom bedrock below the 6m deep. The air pemeability of soil was measured to 1.058-1.077$\times$10$^{-6}$ $\textrm{mm}^2$ by vacuum pump tests. The groundwater which level was 3~4m deep was observed in some areas of this site. The soil vapor extraction system which had 7.5 HP vacuum pump and 8 extraction wells was constructed in this site and operated at 8 hrs/day for 100 days. The BTEX was removed with above 90% efficiency where no groundwater and silty sand were observed. On the contrary, the efficiency of BTEX and TPH were dramatically decreased where groundwater and silty sand were observed. The flow rate of soil air induced by soil vapor extraction system was reduced in deeper soil.

• The Korean Journal of Ecology
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• v.23 no.1
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• pp.51-57
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• 2000

Concentrations of cadmium, copper and zinc were determined in three molluscan species including Sacculosiphonaria japonica, Reishia clavigera and Crassostrea gigas to assess heavy metal contamination in the Onsan Bay. The range of cadmium concentrations were 3.83∼39.67 ㎍/g d.w. in S. japonica, 7.47∼103.47 ㎍/g d.w. in R. clavigera, 1.32∼92.17 ㎍/g d.w. in C. gigas. Concentration of cadmium at contaminated site in C. gigas was 70 folds higher than that of reference site. The range of copper concentrations were 22.92∼1287.56 ㎍/g d.w. in S. japonica, 37.53∼656.97 ㎍/g d.w. in R. clavigera, 161.50∼3208.52 ㎍/g d.w. in C. gigas. The concentration of copper at contaminated site in S. japonica was 56 folds higher than that of reference site. The range of zinc concentrations were 93.48∼377.40 ㎍/g d.w. in S. japonica, 423.65∼1075.57 ㎍/g w. in R. clavigera, 2018.13∼22275.00 ㎍/g d.w. in C. gigas. The difference of zinc concentrations between reference site and contaminated site was relatively small than those of cadmium and copper in all the species tested. The largest difference was 11 folds in C. gigas. In the present work, we confirmed that all of these species, S. japonica, R. clavigera and C. gigas, could be used as biological indicators to monitor heavy metal contamination.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.3-10
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• 2003

Soil and groundwater contamination by petroleum hydrocarbon products is only one of many environmental problems in Korea. However, many environmental consulting companies have been targeted their business on this subject because the petroleum-oil-lubricant (POL) products have been widely used product and accidental releases of the products from storages resulted numerous small and large contaminated sites throughout Korea. Therefore, many small and large companies are actively participating in environmental assessment and remediation projects for the POL contaminated sites. Remedial technologies for the POL contaminated sites have been developed for many years by government and private institutions throughout the world. Development of a new decontamination technology for the POL contaminated sites is no longer attractive issue in research community because scientific bases of most cost-effective remedial technologies are well understood and have been used in the field by commercial sector. Numerous sites contaminated by underground tanks at gas stations have been remediated by relatively small companies in this country. We should appreciate their noticeable contributions as a frontier under very difficult market environment in Korea. We heard many successful stories as well as a few failure stories. Soil-groundwater remediation of POL contaminated site is not a simple task as shown in the text books or protocols. Therefore, failure risk is always with us, which requires continuous efforts for improvement of the technologies by the users and developers. In this presentation, author will discuss technical problems encountered and improvement made during implementation of several remedial technologies applied by Samsung Environmental Team. This is not a presentation about research or case study. We want to share our thought and experience with environmental engineers actively engaged in soil and groundwater remediation projects in Korea.

• The Journal of Natural Sciences
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• v.8 no.1
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• pp.87-92
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• 1995

In the Vicinity of the Sindae-dong waste disposal site in Taejon, the average Cu, pb and Zn concentrations in soils are higher than those in other Korean soils but these are not high enough to cause any harmful effect to human and animal through the crop plants. Copper, Pb and Zn are not detected in the groundwater samples and F, Cl, $NO_2$, $NO_3$ and $SO_4$ concentrations in groundwater samples are lower than drinking water standards. However, the pH of groundwater sample in site D is 5.58 which is not suitable for the drinking water. With the electric resistivity method, the water-containg layers are found in contaminated soils and the resistivity values are considerably low because of the dispersion of plume by the leak of leachates. According to the results from the magnetic survey method, the anomalous values of the total geomagnetic fields and their gradients are found in the sampling site of low resistivity and high trace element concentrations.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.27-35
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• 2003

The study site located in an industrial complex has a Precambrian age gneiss as a bedrock. The poorly-developed, disturbed soils in the study site have loamy-textured surface soil (1 to 2 m) and gravelly sand alluvium subsurface (2 to 6 m) on the top of weathered gneiss bedrock. The depth of the groundwater table was about 3.5 m below ground surface and increased toward down-gradient of the site. The hydraulic conductivity of transmitted zone (gravelly coarse sand) was in the range of 5.0${\times}$10$\^$-2/∼1.85${\times}$10$\^$-1/ cm/sec. The fine sand layer was in the range of 1.5${\times}$10$\^$-3/ to 7.6${\times}$10$\^$-3/ cm/sec. and the reclaimed upper soil layer was less than 10$\^$-4/ cm/sec. Toluene, ethylbenzene, and xylene (TEX) was the major contaminant in the soil and groundwater. The average depth of the soil contamination was about 1.5 m in the gravelly sand alluvium layer. At the depth interval 2.4∼4.8 m, the highest contamination in the soil is located approximately 50 to 70 m from the suspected source areas. The concentration of TEX in the groundwater was highest in the suspected source area and a lesser concentration in the center and southwest parts of the site. The TEX distribution in the groundwater is associated with their distribution in the soil. Microbial isolation showed that Pseudomonas flurescence, Burkholderia cepacia, and Acinetobactor lwoffi were the dominant aerobic bacteria in the contaminated soils. The analytical results of the groundwater indicated that the concentrations of dissolved oxygen (DO), nitrate, and sulfate in the contaminated area were significantly lower than their concentrations in the none-contaminated control area. The results also indicated that groundwater at the contaminated area is under anaerobic condition and sulfate reduction is the predominant terminal electron accepting process. The total attenuation rate was 0.0017 day$\^$-1/ and the estimated first-order degradation rate constant (λ) was 0.0008 day$\^$-1/.

• Journal of the Korean Society of Groundwater Environment
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• v.3 no.2
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• pp.60-69
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• 1996

Along with rapid industrial development, toxic chemicals have been discharged extensively into the environment. Many of them have flowed into the soil which is final acceptor of environmental pollutants. As a result, they have deteriorated soil and groundwater environment. Once the soil and groundwater were contaminated by pollutants, these media can not be easily restored without artificial remediation. Foreign countries which accomplished earlier industrialization compared to our country have invested enormous capital for the remediation of contaminated sites and the development of relevant technology. In our country the reserch on the development of remediation technology has been conducted for several years, but it is still in its initial stage. This report represents remediation technologies, their adaptability and clean up procedure etc. which are being used for the managenent of contaminated site in advanced countries.

• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.101-113
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• 2016

To properly manage and remediate groundwater contaminated with chlorinated hydrocarbons such as trichloroethylene (TCE), it is necessary to assess natural attenuation processes of contaminants in the aquifer along with investigation of contamination history and aquifer characterization. This study evaluated natural attenuation processes of TCE at an industrial site in Korea by delineating hydrogeochemical characteristics along the flow path of contaminated groundwater, by calculating reaction rate constants for TCE and its degradation products, and by using geochemical and reactive transport modeling. The monitoring data showed that TCE tended to be transformed to cis-1,2-dichloroethene (cis-1,2-DCE) and further to vinyl chloride (VC) via microbial reductive dechlorination, although the degree was not too significant. According to our modeling results, the temporal and spatial distribution of the TCE plume suggested the dominant role of biodegradation in attenuation processes. This study can provide a useful method for assessing natural attenuation processes in the aquifer contaminated with chlorinated hydrocarbons and can be applied to other sites with similar hydrological, microbiological, and geochemical settings.