• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.1
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• pp.67-73
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• 2019

We carried out basic research to evaluate covering material for improving and managing contaminated benthic environments in coastal areas. Changes in nutrient concentration such as phosphate, hydrogen sulfide of contaminated sediment, and pH, Oxidation Reduction Potential (ORP) were investigated through mesocosm experiments for 6 months by covering contaminated sediment with granulated coal ash. Calcium oxide eluted from the granulated coal ash was confirmed to neutralize acidified sediment by increasing pH through hydrolysis. Also, calcium oxide and silica eluted from the granulated coal ash adsorbed and precipitated with phosphate in the sediment. The concentration of phosphate in the sediment investigated decreased by ca. 84.31 %. Similarly, the concentration of hydrogen sulfide decreased by 133.5 mg/L in one month. The hydrogen sulfide is considered to have reacted with substances such as manganese oxide which were eluted from the granulated coal ash and precipitated. Also, it was concluded that the hydrogen sulfide was reduced since anaerobic conditions in the sediment weakened. According to the results of these mesocosm experiments, granulated coal ash was found to be effective to remediate and manage benthic environments by covering the surface layer of sediment.

• Proceedings of KOSOMES biannual meeting
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• 2005.05a
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• pp.119-122
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• 2005

As it is known that the korean coastal fishing areas are getting contaminated by heavy metals from the sediment, the authors conducted the experiments to treat the heavy metals with bioleaching process. As a result, it is found that (1) acidification for the leaching of heavy metals is effectively processed when adding more than $0.3\%$ of sulfur and $0.1\%$ of ferrous sulfate. and (2) copper is rapidly solubilized irrespective of addition of sulfur, while solubilization is not processed even of FeS is added., and (3) bioleaching with sulfur and FeSO4 is possible method to effectively treat the heavy metals form the contaminated sediments.

• Journal of Food Hygiene and Safety
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• v.19 no.3
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• pp.132-139
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• 2004

As measure against the environmental pollution, maximum efforts to improve of the environmental pollution have also been made; removal of the contaminated sediments of the bay and the coastal area, monitoring of several heavy metal levels in fishes, shell fishes, sea water and sediment, and so on. The objective of this research is to investigate how much metals are included in the sea water, sediment, fishes and shell fishes in kyeongnam coastal area. Specifically, we are investigating the relationships between the metal included in fishes and sea water, and shell fishes and sediment, and heavy metals and heavy metals respectively. Heavy metal over the studied component and area, the average concentrations of Pb, Cd, Cr and Hg in sea water were 0.0029 mg/L, 0.005 mg/L, 0.0016 mg/L and ND, those of sediment were 11.9583 mg/kg, 0.2136 mg/kg, 1.9158 mg/kg and Hg 0.0108 mg/kg, those of fishes were 0.4358 mg/kg. 0.0726 mg/kg, 1.1188 mg/kg and Hg 0.0622 mg/kg, and those of shellfishes were Pb 0.6738 mg/kg, Cd 0.2223 mg/kg, Cr 0.5516 mg/kg and Hg 0.0117 mg/kg respectively. In the relationship test, Cd was significant in the relationship between fishes and sea water, and Hg was significant in the relationship between sediment and shellfishes.

• Journal of the Korean Society for Marine Environment & Energy
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• v.15 no.4
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• pp.302-313
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• 2012

Concentrations of selected heavy metals (Al, Fe, Mn, Cr, Cu, Ni, Zn, Pb, As and Cd) in surface sediments from 96 sites in Masan and Jinhae Bay were studied in order to understand metal contamination. Results show that the surface sediments were mainly enriched by Cu (18-294 ppm), Zn (67-568 ppm), Pb (10-120 ppm) and Cd (0.2-3.5 ppm). The coastal zone of Masan Bay was significantly more contaminated than the non-coastal zone, and spatial distribution pattern suggested additional sources of heavy metal input in the coastal area. The enrichment ratio and geoaccumulation index ($I_{geo}$) have been calculated and the relative contamination levels assessed in the study area. The enrichment ratios of Cu, Zn, Pb and Cd in Masan Bay have been observed to be relatively high. $I_{geo}$ results reveal that the study area is not contaminated with respect to Fe, Mn, Cr and Ni; moderately to strongly contaminated with Cu, Zn and Pb; and strongly to strong contaminated with Cd. The high contents of Cu, Zn, Pb and Cd in the study area result from anthropogenic activities in the catchment area. Based on the eight different sediment quality guideline values from USA (ERL, ERM), Canada (TEL, PEL), Australia/New Zealand (ISQG-high, ISQG-low) and Hong Kong (ISQV-low, ISQV-high), sediment quality of Masan and Jinhae Bay was also assessed and characterized.

• Journal of Navigation and Port Research
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• v.38 no.3
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• pp.239-246
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• 2014

A study on the elution characteristics of biostimulating agents (sulfate and nitrate) from biostimulants which are used for in-situ bioremediation for the coastal sediment contaminated with organic matter was performed. The biostimulating agents were mixed with the coastal sediment, and then massed the mixture into ball. Two kinds of ball type biostimulant were prepared by coating the ball surface with two different polymers, cellulose acetate and polysulfone. A granular type biostimulant (GTB) was also prepared by impregnating a granular activated carbon in the biostimulating agent solution. The image of scanning electron microscopy for the biostimulant coated with cellulose acetate (CAB) showed that the inner side of the coating layer consisted of irregular and bigger size of pores, and the surface layer had tight structure like beehive. For the biostimulant coated with polyfulfone (PSB), the whole coating layer had a fine structure without pore. The elution rate of the biostimulating agents for the CAB was higher than that for the PSB, and the elution rate for the GTB was considerably higher than that for the PSB in distilled water as well as in sea water. The elution rate of the biostimulating agents in turbulent water flow was about 3 times higher than that in standing water, and the elution rate of nitrate was higher than that of sulfate from the stimulating agents.

• Journal of Navigation and Port Research
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• v.40 no.6
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• pp.441-450
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• 2016

A pilot scale biostimulation experiment was performed under field conditions to degrade organic pollutants and PAHs (Polycyclic Aromatic Compounds) in contaminated coastal sediment. During the experiment, the seawater temperature around the sediment varied from $16.5^{\circ}C$ to $21^{\circ}C$, while the sediment pH was stable at 8.4-8.5. The experiment was conducted over a one year period with a control group and a sample group with a applied biostimulant composed of acetate, sulfate, and nitrate. Chemical oxygen demand decreased 39% in the control group and 79% in the sample group. Volatile solids were reduced from 15 to 7 g/kg in the control group and 2.5 g/kg in the sample group. Out of the 2-, 3- ,4- ,5-, and 6-rings of the 16 vital PAHs, the compound including naphthalene (2-ring), took 2 months to degrade completely, while the degradation efficiency was 55.6% in the control group during the same period. In the case of the 3-ring and 4-ring PAHs, complete degradation in the sample and 46% - 100% degradation in control was observed after one year of the experiment. The 5-ring and 6-ring PAHs were degraded to about 77%-100% in the sample group and 26%-87% in the control group during the one year of the experiment. The study results show that biostimulation is a very effective method to improve the degradation rate of organic pollutants and PAHs (Polycyclic Aromatic Compounds) in contaminated coastal sediment.

• Journal of the Korean Society for Marine Environment & Energy
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• v.1 no.1
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• pp.39-46
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• 1998

This study presents a numerical model that can simulate changes of particle size distribution (PSD) of PCB-contaminated coastal sediments. The developed model has one spatial dimension including sedimentation and vortical dispersion as well as coagulation. The reason for considering the vortical transport mechanisms is to calculate residence time of the particles. Using the model and Initial PSD data based on actual coastal sediments contaminated with PCBs, this study shows results of model simulations. Within 48 hours of the simulation time, the PSD changed significantly and the particles were removed from water in different rates between different particle sizes. It also shows that coagulation can act an important role in this process. The model may be useful in assessing the range of resuspended sediments that can pollute neighboring areas during environmental remediation projects such as dredging.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.2
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• pp.74-80
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• 2015

To assess environmental characteristics of the aquaculture area in Tongyeong, pH, dissolved oxygen (DO), dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorous (DIP) and chemical oxygen demand (COD), and acid volatile sulfur (AVS) were measured in seawater and sediment samples collected from 10 locations of Tongyeong coastal area from July to December in 2013. The quality of the seawater may be affected by seasonal variation rather than the distance from fish farm. However, sediment was contrary to seawater; the distance from fish farm may be a main factor to affect COD and AVS in sediment than season and other parameters. It is expected that contaminated organic sediments of fishery located in semi-closed bay are rapidly dispersed into surrounding waters due to fast current.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.11 no.1
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• pp.41-49
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• 1999

The horizontal two-dimensional model which can predict the long-term water quality(WQ) change is setup for the environmental management. For the model calibration and verification, we measured the pollutants load at 22 streams and the WQ at 16 stations monthly and/or seasonally in Chinhae . Masan Bay. The pollutants release rate from the sediment was also measured to consider the regionally different sediment pollution level. From the model application results, it is shown that the WQ concentrations in most of the regions adjacent to land and river inflow are considerably high, but rapidly decrease along the seaward direction. In Masan Bay, the particulate inflow-pollutants were substantially deposited and gradually contaminated the bottom sediment on account of the excessive pollutants load and flow stagnancy. Eutrophication in the effluent discharge region was also being slowly progressed by the inefficiently treated wastewater containing amount of Nand P constituents.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.7
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• pp.469-475
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• 2014

The study investigated the physicochemical characteristics and the ecological risk of the Northport sediment in B city and the releasing properties of heavy metals into seawater during the resuspension also studied. The major components of the sediment are fine silt and clay which contains high organic matter and AVS (Acid volatile sulfide) and the ecological risk of the heavy metals in sediment also very high. The release rate of heavy metals into seawater was in order of Pb>>Cu>Cr>>Zn>Cd during the resuspension in a batch experiment, and the heavy metal release mainly attributed to the oxidation of metal sulfides. Heavy metals which came from easily oxidisable metal sulfides rapidly contaminated seawater within about 1.0 h of the sediment resuspension. The sulfide oxidation during the resuspension increased the residual fraction of heavy metals in the sediment, decreased the organic bound fraction, and changed the other fractions of heavy metals in the sediment. The release of heavy metals from the sediment during resuspension was affected by the resuspension time, the oxidation rate of metal sulfides and resuspended concentration of the sediment particle.