• Title/Summary/Keyword: Contact potential

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Study of Equilibrium, Kinetic and Thermodynamic Parameters about Fluorescein Dye Adsorbed onto Activated Carbon (활성탄을 이용한 플루오레세인 염료 흡착에 대한 평형, 동력학 및 열역학 파라미터의 연구)

  • Lee, Jong-Jib;Um, Myeong Heon
    • Applied Chemistry for Engineering
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    • v.23 no.5
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    • pp.450-455
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    • 2012
  • The paper includes the utlization of an activated carbon as a potential adsorbent to remove a hazardous fluorescein dye from an aqueous solution. Batch adsorption experiments were carried out for the removal of fluorescein dyes using a granular activated carbon as an adsorbent. The effects of various parameters such as pH, amount of adsorbent, contact time, initial concentration and temperature of the adsoprtion system were investigated. The experimental results revealed that activated carbon exhibit high efficiencies to remove fluorescein dyes from the aqueous solution. The equilibrium process can be well described by Freundlich isotherm in the temperature range from 298 K to 318 K. From adsorption kinetic experiments, the adsorption process followed a pseudo second order kinetic model, and the adsorption rate constant ($k_2$) decreased with increasing the initial concentration of fluorescein. The free energy of adsorption ${\Delta}G^0$), enthalpy ${\Delta}H^0$), and entropy (${\Delta}S^0$) change were calculated to predict the nature adsorption. The estimated values for ${\Delta}G^0$ were -17.11~-20.50 kJ/mol over an activated carbon at 250 mg/L, indicated toward a spontaneous process. The positve value for ${\Delta}H^0$, 33.2 kJ/mol, indicates that the adsorption of fluorescein dyes on an activated carbon is an endothermic process.

Nanotube-based Dye-sensitized Solar Cells

  • Kim, Jae-Yup;Park, Sun-Ha;Choi, Jung-Woo;Shin, Jun-Young;Sung, Yung-Eun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.71-71
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    • 2011
  • Dye-sensitized solar cells (DSCs) have drawn great academic attention due to their potential as low-cost renewable energy sources. DSCs contain a nanostructured TiO2 photoanode, which is a key-component for high conversion efficiency. Particularly, one-dimensional (1-D) nanostructured photoanodes can enhance the electron transport for the efficient collection to the conducting substrate in competition with the recombination processes. This is because photoelectron colletion is determined by trapping/detrapping events along the site of the electron traps (defects, surface states, grain boundaries, and self-trapping). Therefore, 1-D nanostructured photoanodes are advantageous for the fast electron transport due to their desirable features of greatly reduced intercrystalline contacts with specified directionality. In particular, anodic TiO2 nanotube (NT) electrodes recently have been intensively explored owing to their ideal structure for application in DSCs. Besides the enhanced electron transport properties resulted from the 1-D structure, highly ordered and vertically oriented nanostructure of anodic TiO2 NT can contribute additional merits, such as enhanced electrolyte diffusion, better interfacial contact with viscous electrolytes. First, to confirm the advantages of 1-D nanostructured material for the photoelectron collection, we compared the electron transport and charge recombination characteristics between nanoparticle (NP)- and nanorod (NR)-based photoanodes in DSCs by the stepped light-induced transient measurements of photocurrent and voltage (SLIM-PCV). We confirmed that the electron lifetime of the NR-based photoanode was much longer than that of the NP-based photoanode. In addition, highly ordered and vertically oriented TiO2 NT photoanodes were prepared by electrochemical anodization method. We compared the photovoltaic properties of DSCs utilizing TiO2 NT photoanodes prepared by one-step anodization and two-step anodization. And, to reduce the charge recombination rate, energy barrier layer (ZnO, Al2O3)-coated TiO2 NTs also applied in DSC. Furthermore, we applied the TiO2 NT photoanode in DSCs using a viscous electrolyte, i.e., cobalt bipyridyl redox electrolyte, and confirmed that the pore structure of NT array can enhance the performances of this viscous electrolyte.

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A Study on Ceramic Restoration Methods with Full Color 3D Printing (풀 컬러 3D 프린팅을 이용한 도자기 복원 방법 연구)

  • Shin, Woo Cheol;Wi, Koang Chul
    • Journal of Conservation Science
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    • v.36 no.5
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    • pp.306-314
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    • 2020
  • The use of synthetic resins in ceramic restoration poses several challenges, including aging and potential damage to artifacts, which has raised the need to investigate new materials and restoration methods. This study set out to incorporate full color 3D printing into the 3D digital technology-based restoration method, an emerging approach currently being researched, and to print out missing parts with color information. After examining material physical properties with an experiment, the investigator printed out missing parts from a white porcelain vessel and grayish-blue-powdered celadon plate and compared them in chromaticity and brilliance. The experimental results show that the outputs had comparable tensile strength to the original restoration materials, whereas the recorded compressive strength was approximately 1.4~2 times higher than that of the original restoration materials. According to the NIST table of color difference values, the white porcelain vessel was visible at ΔE*ab 1.55, and the grayish-blue-powdered celadon plate was perceivable at 3.34. Even though it was impossible to express the colors accurately owing to printer limitations, this non-contact approach reduced the possibility of damage to the minimum. In conclusion, it can be applied to objects with a high chance of damage or generate display effects through purposeful color differentiation in missing parts.

A Comparison of Laser Flash and the Divided-bar Methods of Measuring Thermal Conductivity of Rocks (암석 열전도도 측정을 위한 Laser Flash Method와 Divided-bar Method 비교)

  • Oh, Jae-Ho;Kim, Hyoung-Chan;Park, Jeong-Min
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.387-397
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    • 2011
  • In this study, we conducted the study of the merits and demerits of the laser flash and the divided-bar methods for measuring the thermal conductivity of rocks and investigated applicability of the divided-bar apparatus which was developed by KIGAM. The laser flash method can measure thermal diffusivity, specific heat capacity, and thermal conductivity of rocks with even small thickness (< ~3 mm) in the high temperature range($25-200^{\circ}C$) in non-contact mode. For the laser flash method, samples must be uniform and homogeneous. In the case of the divided-bar method, the apparatus measures only thermal conductivity of rock samples at the room temperature. We measured thermal conductivities of 12 rock samples with low density and high porosity using two methods. In the laser flash method, there exist potential errors caused by the effect of pulse dispersion and reflection by various minerals and porosity in rock samples; the difference in thermal conductivity values measured on the front surface and the opposite surface ranges from 0.001 to 0.140 W/mK with the standard deviation of 0.003~0.089 W/mK, which seems to be caused by heterogeneity of rock samples. On the contrary, the divided-bar apparatus shows stable thermal conductivity measurements and relatively small measurement errors; the difference in thermal conductivity values, just as we applied to the laser frash method, is 0.001~0.016 W/mK with the standard deviation 0.001~0.034 W/mK. In turn, the divided-bar method can be applied to more thick samples that are more representative of bulk thermal conductivity.

Evaluation on Skin Irritation and Sensitization of Oxyresveratrol and Oxyresveratrol-3-O-glucoside Produced by Biotransformation of Morus alba Extract (상백피 추출물을 효소전환 하여 생성한 oxyresveratrol 및 oxyresveratrol-3-O-glucoside의 피부 자극성 및 감작성 평가)

  • Park, Keun-Tae;Kim, Jeong-Keun;Lim, Young-Hee
    • Korean Journal of Food Science and Technology
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    • v.44 no.2
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    • pp.251-256
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    • 2012
  • Stilbenes are known as antioxidants and some of them demonstrate anti-pigmentation activity. The purpose of the present study was to investigate whether two stilbene compounds produced by biotransformation of the extract of $Morus$ $alba$ root show skin irritation and sensitization. In skin irritation test, 1% oxyresveratrol (OXY), and 5% OXY, and 1% oxyresveratrol-3-$O$-glucoside (OXY-3) showed a P.I.I score of 0, 0.04, and 0, respectively. Accordingly, the two stilbenes were evaluated to be virtually 'non-irritant' materials. In a skin sensitization study by GPMT, 1% OXY, 5% OXY, and 1% OXY-3 did not cause edema and erythema at 24 h and 48 h after topical application and exhibited a sensitization score of 0 and a rate of 0%. Consequently, it was confirmed that OXY and OXY-3 had no contact allergic sensitization in GPMT. Therefore, OXY and OXY-3 might be potential candidates as skin-whitening agents without posing any serious side effects.

Preparation of PVdF Composite Nanofiber Membrane by Using Manganese-Iron Oxide and Characterization of its Arsenic Removal (망간-철 산화물을 이용한 PVdF 나노섬유복합막의 제조 및 비소 제거 특성 평가)

  • Yun, Jaehan;Jang, Wongi;Park, Yeji;Lee, Junghun;Byun, Hongsik
    • Membrane Journal
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    • v.26 no.2
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    • pp.116-125
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    • 2016
  • This study described a synthesis of MF having a arsenic removal characteristics and the fundamental research was performed about the simultaneous removal system of both As(III) and As(V) ions with the composite nanofiber membrane (PMF) based on PVdF and MF materials for the water-treatment application. From the TEM analysis, the shape and structure of MF materials was investigated. The mechanical strength, pore-size, contact angle and water-flux analysis for the PMF was performed to investigate the possibility of utilizing as a water treatment membrane. From these results, the PMF11 showed the highest value of mechanical strength ($232.7kgf/cm^2$) and the pore-diameter of composite membrane was reduced by introducing the MF materials. In particular, their pore diameter decreased with an increase of iron oxide composition ratio. The water flux value of PMF was improved about 10 to 60% compared with that of neat PVdF nanofiber membranes. From the arsenic removal characterization of prepared MF materials and PMF, it was shown the simultaneous removal characteristics of both As(III) and (V) ions, and the MF01, in particular, showed the highest adsorption-removal rate of 93% As(III) and 68% As(V), respectively. From these results, prepared MF materials and PMF have shown a great potential to be utilized for the fundamental study to improve the functionality of water treatment membrane.

PERIOD CHANGES OF W UMa TYPE CONTACT BINARY SS ARIETIS (W UMa형 접촉쌍성 SS ARIETIS의 공전주기 변화)

  • 김천휘;한원용;윤재혁;나일성
    • Journal of Astronomy and Space Sciences
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    • v.14 no.1
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    • pp.44-58
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    • 1997
  • The BVR CCD photometric observations of W UMa-type eclipsing binary SS Ari were made on ten nights from November 1996 to December 1996. Eight new times of minimum lights were derived. The analysis of times of minima of SS Ari confirms the suggestions of other previous investigators that the orbital period of SS Ari have been suffering from a sinusoidal varition. The amplitude and period for the cyclic period changes were calculated as about $58^{y}$ and $0.^{d}053$, respectively. The period variation has been discussed in terms of two potential mechanisms: 1) the light-time effect due to a hypothetical third body and 2) deformations in the convective envelope of a magnetically active component. In the earlier case, the third body has a mass of $1.3M_{\odot}$, if exist, in the form of a white dwarf or a binary system. It seems that the system velocities from the spectroscopic observations supports this interpretation. Meanwhile in the latter case, the primary component is mainly responsible for the magnetic activity of this system with a theoretical amplitude of $\pm0.^{m}08$. However, we cannot make a conclusion which is reasonable explanation at this point, due to lack of observational data. Moreover, the period variation of SS Ari shows duplication about $14^y$, cyclic period with an amplitude of about $0.^d001$ to the above periodic change. We also cannot make an acceptable conclusion for it at this time.

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Effects of Disinfectant Concentration, pH, Temperature, Ammonia, and Suspended Solids on the Chlorine Disinfection of Combined Sewer Overflow (소독제 농도, pH, 온도, 암모니아 농도, 부유물질이 강우 월류수 염소 소독에 미치는 영향)

  • Kim, Sang-Hyoun
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.10
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    • pp.685-690
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    • 2014
  • The treatment of combined sewer overflow (CSO) is one of potential concerns in domestic wastewater treatment in Korea due to the pre-announce of CSO regulations. This work investigated the effects of disinfectant (NaOCl) concentration (0.11 to 4.0 mg $Cl_2/L$), pH (6.5 to 8.0), temperature (15 to $25^{\circ}C$), ammonia (10 to 41 mg N/L), and suspended solids (91 to 271 mg SS/L) on the chlorine disinfection of CSO. The effect of NaOCl concentration on the pseudo-$1^{st}$ order reaction rate for total coliform inactivation was described well with a saturation-type model with the half-velocity constant of 1.212 mg/L. The total coliform inactivation reaction rate decreased with SS and pH, and increased with temperature. Ammonia in the examined range did not affect the disinfection kinetics. A chlorine contact tank with the injection chlorine level of 1 mg $Cl_2/L$ and the hydraulic retention time of 1.25 min is estimated to reduce total coliform from $1{\times}10^5MPN/mL$ to 1,000 MPN/mL at 271 mg SS/L, $15^{\circ}C$, and pH 8.0. Chlorine would be a proper option for the disinfection of CSO.

A study on electrochemical protection diagrams of steel in nitric and sulfuric acid solutions (질산과 황산 용액중의 철강의 전기방식도에 관한 연구)

  • 전대희;김진경
    • Journal of Advanced Marine Engineering and Technology
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    • v.13 no.2
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    • pp.43-63
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    • 1989
  • Various kinds of corrosion prevention methods have been developed. It is known that the method of electrochemical protection is more effective and economical than any other method on the large scale metal structures in corrosive solutions. Strong acid solutions such as nitric and sulfuric acid solutions are often used in industries, and the expensive stainless steel is almost exclusively used for the equipment that comes in contact with such acid solutions. However, it is more reasonable that carbon steel is used rather than stainless steel depending upon concentration of those acid solutions from the economical viewpoint. In this study, the typical strong acid solution such as nitric and sulfuric acid solutions are chosen for the experiment and the selected materials of specimen are the stainless steels of SUS 304L and SUS 316L, the carbon steels of SS 41, SM 50 and RA 32, and highly pure lead. Electrochemical protection diagrams can be drawn with data from the external cathodic and anodic polarization curves of SUS 304L, SUS 316L and SM 50 steels in 5-60% nitric acid solutions and from those polarization curves of SS 41, RA 32, SM 50 and SUS 316L steels, and highly pure lead in 2.5-98% sulfuric acid solutions at the slow scanning rate. The data obtained with using the determination method of the optimum cathodic protection potential, the Tafel extrapolation method and the characteristics of anodic polarization curves. The main results obtained from the diagrams are as follows: 1) In nitric acid solution : (1) Corrosion potentials exist in each of those corrosion zones on the stainless steels in the lower concentration than about 12% solutions and on the high tensile strength steels in the lower concentration than about 30% solutions, but the corrosion current (density) in each zone is small on the above mentioned former steels and large on the latter ones. (2) The stainless steels can be self-passivated in the higher concentration than 15% solutions, and the high tensile strength steels gives rise to the same phenomenon in the higher concentration than 35% solutions. (3) The stainless steels in the lower concentration than 60% solutions and the high tensile strength steels in the higher concentration than 35% solutions can be used without protection, but the latter steels must ve protected anodically in the lower conccentration than about 30% solutions. 2) In sufuric acid solution : (1) The carbon steels can be self-passivated in the higher concentration than 45% solutions, and the SUS 316L steel in higher concentration than 75% solutions and the lead in all concentration solutions also gives rise to the same phenomenon. (2) The lead in the lower concentration than 80% solutions and the SUS 316L steel in the higher concentration than 80% solutions can be used without protection. (3) The carbon steels in the higher concentration than 50% solutions also can be used without protecting economically, but the SUS 316L steel in the 20-70% solutions are considerably corrosive without protecting anodically.

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Behavior of Retinal Pigment Epithelial Cells Cultured on Silk Films (실크필름에 배양한 망막색소상피세포의 거동)

  • Lee, So Jin;Kim, Hye Yun;Kim, Seul Ji;Yang, Jaewon;Lee, Seon Ui;Park, Chan Hum;Joo, Choun-Ki;Khang, Gilson
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.364-370
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    • 2014
  • The retinal pigment epithelium (RPE) plays an important role in maintaining a healthy retina and the degeneration of RPE caused a number of retinal diseases. The transplantation of RPE has recently become a possible therapeutic modality for retinal degeneration. To transplant RPE cells securely, substrates are essential, and then as a substrate, we fabricated films using silk that has unique mechanical properties and biocompatibility. After the FTIR spectra, contact angle and biodegradation of silk films were confirmed, RPE cells were seeded and the influence of RPE cells on silk films was examined. We measured the cell adhesion, cell viability, morphology and specific mRNA expression by MTT assay, SEM, immunofluorescence and RT-PCR. In this study, we confirmed that attachment, proliferation and phenotype maintenance of RPE cells cultured on silk films were great, and thereby we were able to confirm the potential applications of silk films as tissue engineering carrier for regeneration of retina.