• Title/Summary/Keyword: Contact intensity

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Unusual Facilitated Olefin Transport through Polymethacrylate/Silver Salt Complexes

  • Kim, Jong-Hak;Joo, Seung-Hwan;Kim, Chang-Kon;Kang, Yong-Soo;Jongok Won
    • Macromolecular Research
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    • v.11 no.5
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    • pp.375-381
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    • 2003
  • Silver salt complex membranes with glassy poly(methyl methacrylate) (PMMA) unexpectedly showed higher propylene permeance than those with rubbery poly(butyl methacrylate) (PBMA) where as neat PMMA is much less permeable to propylene than that of neat PBMA. Such unusual facilitated olefin transport has been systematically investigated by changing the side chain length of polymethacrylates (PMAs) from methyl, ethyl to butyl. The ab initio calculation showed almost the same electron densities of the carbonyl oxygens in the three PMAs, expecting very similar intensity of the interaction between carbonyl oxygen and silver ion. However, the interaction intensity decreases with the length of the alkyl side chain: PMMA > PEMA > PBMA according to wide angle X-ray scattering and FT-Raman spectroscopy. The difference in the interaction intensity may arise from the difference in the hydrophilicity of the three PMAs, as confirmed by the contact angle of water, which determines the concentrations of the ionic constituents of silver salts: free ion, contact ion pair and higher order ionic aggregate. However, propylene solubilities and facilitated propylene transport vary with the side chain length significantly even at the same concentration of the free ion, the most active olefin carrier, suggesting possible difference in the prohibition of the molecular access of propylene to silver ion by the side chains: the steric hindrance. Therefore, it may be concluded that both the hydrophilicity and the steric hindrance associated with the side chain length in the three PMAs are of pivotal importance in determining facilitated olefin transport through polymer/silver salt complex membranes.

Analysis of a Complete Contact Problem in Bonded Condition: Comparison of Experimental-Numerical Analyses and Theoretical Solutions (응착조건의 완전접촉문제 해석: 실험 및 수치해석과 이론해의 비교)

  • Kim, Hyung-Kyu;Jang, Jae-Won;Lee, Soon-Bok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.6
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    • pp.583-588
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    • 2015
  • Asymptotic method has been often used to theoretically analyze the complete contact problem. The error of the asymptotic results increases as the distance from the contact edge increases. The singularity cannot be properly obtained from a finite element (FE) analysis owing to the finiteness of the element size. In the present work, the complete contact problem in bonded condition is analyzed using a combined experimental-numerical approach to assist and/or compare with the asymptotic results. Al and Cu alloys are used for the material combination of the punch and substrate. 120 and 135 degrees are used for the punch angle. The FE models are validated by comparison of displacement distributions obtained by the FE analysis and $moir{\acute{e}}$ experiment. Generalized stress intensity factors are evaluated using the validated FE models. Stress field in the vicinity of the sharp contact edges obtained from the FE and asymptotic analyses are compared. The discrepancies are also discussed.

Use of the Texas Eye Research and Technology Center Dry Eye Questionaire (TERTC-DEQ) as a Screening Survey for Contact Lens Wearers and Nonwearers (콘택트렌즈 착용자와 비착용자의 건성안 설문조사 TERTC-DEQ의 활용)

  • Kim, Jai-Min;Kim, Yong-Hwan;Jung, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.4
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    • pp.127-131
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    • 2007
  • This study was designed to demonstrate the ability of Texas Eye Research and Technology Center Dry Eye Questionaire (TERTC-DEQ) to examine the distribution of self-reported dry eye symptoms and their diurnal intensity in university students and compare it with McMonnies & Ho DEQ. Two dry eye questionnaires were administered to 46 contact lens wearers and 47 nonwearers. Contact lens wearers scored higher on the TERTC-DEQ (52.2%) than McMonnies & Ho DEQ (6.5%). Non-contact lens wearers also scored higher on the TERTC-DEQ (19.1%) than McMonnies & Ho DEQ (2.1%). Ocular symptoms worsened with progression of time of day in both groups of subjects. This study suggests that TERTC-DEQ provides a first-choice diagnosis tool to obtain a comprehensive assessment of patient's symptoms, especially in comparison with McMonnies & Ho DEQ. The TERTC-DEQ is an efficient screening survey and may be use in dry eye diagnosis of contact lens-related dry eye.

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Damage of Overlaid Concrete Structures Subjected In Thermally Transient Condition by Rainfall (강우에 따른 콘크리트 덧씌우기 보수체의 손상에 관한 연구)

  • 윤우현
    • Journal of the Korea Concrete Institute
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    • v.13 no.5
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    • pp.491-498
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    • 2001
  • The failure phenomenon of overlaid concrete structures, such as surface crack and peel-off failure in the contact zone, was investigated due to temperature shock(rainfall). To investigate this failure phenomenon, the surface tensile stress, and the shear stress, the vertical tensile stress in the contact zone were analysed using the non-linear stress-strain relationship of material such as strain-hardening- and strain-softening diagrams. Rainfall intensity, overlay thickness and overlay material were the main variables in the analyses. It is assumed that the initial temperature of overlaid concrete structures was heated up to 55$\^{C}$ by the solar heat. With a rain temperature 10$\^{C}$ and the rainfall intensity of nR=1/a, tR=10min, 60min, the stress states of overlaid concrete structures were calculated. The result shows that only fictitious cracks occurred in the overlay surface and no shear bond failure occurred in the contact zone. The vortical tensile stress increasing with overlay thickness was proved to be the cause of peel-off failure in the contact zone. The formulae for relationship between the vertical tensile stress and overlay thickness, material properties were derived. Using this formulae, it is possible to select proper material and overlay thickness to prevent failure in the contact zone due to temperature shock caused by rainfall.

Effects of the 1975 Haicheng Earthquake on the Korean Peninsula (1975년에 발생한 중국 해성지진이 한반도에 미친 영향)

  • 추교승
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 1998.10a
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    • pp.210-221
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    • 1998
  • In the period from the year 1500 to 1980. at least 14 large earthquake with epicenters in the northeastern China and Yellow Sea were felt or destructive in the Korean Peninsula. The most sigmificant events among them were the 1668 July 25 Tancheng earthquake of mamnitude 8.5, and the 1975 Feb. 4 Haicheng earthquake of magnitude 7.3. The Haicheng earthquake of the year 1975 in am extraordinary one among those occurred in the northeastern China in the 20th century in the sense the Shake of the event affected all over the Korean Peninsula. The tremor was felt even at the southeastern tip of the Korea and northern part of Kyushu 700km far away from the epicenter. In order to see the variation and trend of the effect of the Haicheng earthquake on the Korean Peninsula, the two data sets of the northern and southern parts of the peninsula were merged into one combined data set. The spatial variation of intensity shows smooth decrease from the value 4 of the northwestern region near the source to the value 1 of the Cheju Island and Kjushu. However, there are four regions of locally high intensity value. They are the region along downstream of Abrok(Yalu) River with intensity 5, the region around Shinpo of intensity 4, the area comprising Seoul and Chuncheon Cities of intensity 4, and Pohang-Pusan area of intensity 3. We suppose that there might be three types of possible mechanisms. The first one is concerned with the lateral inhomogeneity of velocity in the crust caused by wide distribution of relatively fractured rock. The second one is related with reflections of surface waves caused by the crestal thinning effect at border regions of the Peninsular in contact with the Ulleung Basin and the Japan Basin. The third possibility is local site effect caused by thick Tertiary or Quaternary rocks and soil layers.

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The Classification of Roughness fir Machined Surface Image using Neural Network (신경회로망을 이용한 가공면 영상의 거칠기 분류)

  • 사승윤
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.2
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    • pp.144-150
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    • 2000
  • Surface roughness is one of the most important parameters to estimate quality of products. As this reason so many studies were car-ried out through various attempts that were contact or non-contact using computer vision. Even through these efforts there were few good results in this research., however texture analysis making a important role to solve these problems in various fields including universe aviation living thing and fibers. In this study feature value of co-occurrence matrix was calculated by statistic method and roughness value of worked surface was classified, of it. Experiment was carried out using input vector of neural network with characteristic value of texture calculated from worked surface image. It's found that recognition rate of 74% was obtained when adapting texture features. In order to enhance recogni-tion rate combination type in characteristics value of texture was changed into input vector. As a result high recognition rate of 92.6% was obtained through these processes.

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A Study on the Microscopic Model for Fatigue Crack Closure Behavior (피로균열 개폐구거동의 미시적 모델에 관한 연구)

  • O, Se-Uk;Gang, Sang-Hun
    • Journal of Ocean Engineering and Technology
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    • v.4 no.1
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    • pp.81-87
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    • 1990
  • Fatigue crack closure levels based on the behavior of residual displacements on crack surfaces, are determined analytically according to the microscopic crack closure mechanisms, i.e., whether the first contact of crack surfaces takes place at the very crack tip or on the surfaces near the tip. The comparative analysis on the two models is carried out empirically by the constant amplitude fatigue tests on 2024-T3 aluminum alloy plate, and it shows that under negative stress ratio, the case of the first contact at crack tip gives better agreement with the experimental results than the other.

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A Study on the Microscopic Model for Fatigue Crack Closure Behavior (피로균열 개폐구거동의 미시적 모델에 관한 연구)

  • O, Se-Uk;Gang, Sang-Hun
    • Journal of Ocean Engineering and Technology
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    • v.4 no.1
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    • pp.87-87
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    • 1990
  • Fatigue crack closure levels based on the behavior of residual displacements on crack surfaces, are determined analytically according to the microscopic crack closure mechanisms, i.e., whether the first contact of crack surfaces takes place at the very crack tip or on the surfaces near the tip. The comparative analysis on the two models is carried out empirically by the constant amplitude fatigue tests on 2024-T3 aluminum alloy plate, and it shows that under negative stress ratio, the case of the first contact at crack tip gives better agreement with the experimental results than the other.

Aging Analysis of Catenary Wires in Accordance with Temperature Changes for a Long Period of Time (장기간 온도변화에 따른 전차선로 전선류의 노후도 분석)

  • Cho, Nam-Hee;Oh, Wan-Shik;Kim, Jae-moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1590-1596
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    • 2016
  • In this paper, catenary wires were analyzed aging through the experiment about a new product and a test sample in accordance with temperature changes from long-term use. In case of the contact wire, the maximum load was reduced within 7% and the tensile strength showed a reduced within 6.7% compared with a new reference standard $110mm^2$. 19 Strands of messenger wire have a little more than a standard value, but result data on tensile test were less than the reference value about stranded wire. Also parts among 49 strands of dropper was found to be smaller than the reference value and it appeared greatly increasing intensity as toward the center of the strand.

A Study on Improvement in a Method of Three Dimensional Configuration Scan Measurement (3차원 형상 스캔의 측정방법 개선에 관한 연구)

  • 김태호;김민주;이승수;박정보;전언찬
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2001.10a
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    • pp.375-380
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    • 2001
  • This study is on the precision of the optical scanner which is suitable for shape modeling and non-contact equipment, comparing with a razer scanner. The optical scanner not only has all merits that non-contact methods have but also improve a veil phenomenon which is a razer scanner's demerits. However, the optical scanner has not been used extensively because the measurements are not very precise and there are not the definite methods of measurement. Hence, this study is to find out how parameters such as camera's hight, angle, luminous intensity, distance to object, and so on have an influence on measuring using the optical scanner and to establish the methods of measuring precision.

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