• Title/Summary/Keyword: Contact angle (CA)

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Water droplet behavior on a solid-infused surface cured with commercial Gentoo polymer (상용 Gentoo 폴리머가 경화된 고체주입표면에서 물방울 거동)

  • Hyeongwon Kim;Jeong-Hyun Kim
    • Journal of the Korean Society of Visualization
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    • v.22 no.1
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    • pp.61-67
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    • 2024
  • In this study, the behavior of water droplets on a solid-infused surface was evaluated by quantifying a water droplet's contact angle, sliding angle, and terminal velocity. The contact angle hysteresis and sliding angle of water on the solid-infused surface were measured to be lower than those of the hydrophobic PTFE surface. It led to the enhancement of the initiation of the water droplet's movement. When the capillary number was lower than Ca < 0.004, the terminal velocity of the water droplet on the solid-infused surface was higher than the PTFE surface due to the low contact line resistance. However, the transition of the droplet morphology from a hemispherical shape to a streamlined teardrop shape beyond Ca > 0.004 lost the effect of reducing frictional resistance on the solid-infused surface.

PLAQUE ADHESION ON THE SURFACES OF VARIOUS COMPOSITE RESIN (수종 복합레진에 대한 치태 부착도 비교)

  • Kim, Young-Jong;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.4
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    • pp.547-554
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    • 2004
  • The surface characteristics of restoration such as surface roughness and droplet contact angle are important part for the process of bacterial adhesion. The purpose of this study is to compare plaque adhesion by measuring roughness, droplet contact angle, and amount of accumulated plaque on the surfaces of composite resins. Four kinds of composite resins, Z-100(Z1), Durafil(DF), Filtek supreme(FS), Clearfil AP X(CA) were used. Ten samples were divided into unpolished and polished group. Surface roughnesses and droplet contact angles were measured by profilometer and goniometer. Plaque weight gains are measured. The results were as follows: 1. The experimental group were rougher than the control group. Surface roughnesses were decreased in the following order; (Z1, DF, CA)>FS in the control group, and CA>Z1>(FS, DF) in the experimental group(P<0.05). 2 The control group showed larger contact angle than the experimental group. Contact angles were decreased in the following order; CA>(FS, DF, Z1) in the control group, and (CA, DF)>(FS, Z1) in the experimental group(P<0.05). 3. The experimental group showed more much plaque than the control group. The amounts of plaque accumulation in vitro were decreased in the following order; Z1>(DF, FS)>CA in the control group, and Z1>FS>(CA, DF) in the experimental group. The latter showed more much plaque than the former(P<0.05). 4. There were stronger correlation between plaque deposition and contact angle (P<0.05) than that of plaque deposition and surface roughness.

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Effects of Simulated Acid Rain and Soil Fertilizers on Photosynthetic Rate, wax Content, and Contact Angle of Japanese Red Pine(Pinus densiflora Sieb. et Zucc.) Leaves (인공산성우와 토양시비가 소나무잎의 광합성속도, 왁스 함량 및 접촉각에 미치는 영향)

  • 최기영;이용범;채의석;이경재
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.3
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    • pp.263-268
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    • 1996
  • This study was conducted for the assessment of the effects of acid rain and soil fertilizers on photosynthetic rate, was content, and contact angle on 5-year seedlings of Japanese red pine (Pinus densiflora Sieb. et Zucc.) leaves. The seedlings were exposed to pH 3.0 (simulated acid rain), pH 6.5 (groung water) and rain (pH around 4.6). The seedlings were also treated with $Ca(OH)_2, Mg(OH)_2, and Ca(OH)_2 + Mg(OH)_2 + C.F.(compound fertilizer)$. Photosynthetic rate, stomatal conductance, was content, contact angle value, and mineral nutrient content of the leaves were measured and the results were as follows: 1. Photosynthetic rate and stomatal conductance of the leaves increased with the increase of pH. Photosynthetic rate and stomatal conductance increased with application of soil fertilizer in the pH 3.0 treatment, but showed no changes in the rain and the pH 6.5. 2. Contact angle value and was content of the leaves did not change with the pH treatment, but increased with the fertilizer treatments. 3. Mineral nutrient contents of the leaves were lowest in the rain treatment and highest in the pH 6.5 treatment. The increase of mineral nutrient contents was observed with the soil fertilizer treatments.

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A Study on Water Contact Angle and Peel Strength by Anti- Adhesion Coating on Die Blade Materials for Adhesive Film Cutting (점착필름 절단용 다이 칼날 소재에 적용된 점착 방지 코팅의 물 접촉각 및 박리강도에 관한 연구)

  • Yujin Ha;Min-Wook Kim;Wook-Bae Kim
    • Tribology and Lubricants
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    • v.39 no.5
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    • pp.190-196
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    • 2023
  • Anti-adhesion coatings are very important in the processing of adhesive materials such as optical clear adhesive (OCA) films. Choosing the appropriate release coating material for dies and tools can be quite challenging. Hydrophobic surface treatment is usually performed, and its performance is often estimated by the static water contact angle (CA). However, the relationship between the release performance and the CA is not well understood. In this study, the water CAs of surfaces coated with anti-adhesion materials and the peel strengths of the acrylic-based adhesive films are evaluated. STC5 and SUS304 are selected as the base materials. Base materials with different surface roughnesses are produced by hairline finishing, mirror-polishing, and end milling. Four fluoropolymer compounds, including a self-assembled monolayer, are selected to make the base surface hydrophobic. Static, advancing, and receding CAs are mostly increased due to the coating, but the CA hysteresis is found to increase or decrease depending on the coating material. The peel strengths all decreased after coating and are largely dependent on the coating material, with significantly lower values observed for fluorosilane and perfluoropolyether silane coatings. The peel strength is observed to correlate better with the static CA and advancing CA than with the receding CA or hysteresis. However, it is not possible to accurately predict the anti-adhesion performance based on water CA alone, as the peel strengths are not fully proportional to the CAs.

Effects of Soil Fertilizers on Was Content, Contact Angle, Mineral Nutrient Content of Japanese Red Pine(Pinus densiflora Sieb. et Zucc.) Leaves and Soil Acidity of Japanese Red Pine Communities in Na (남산과 광릉지역 소나무림 토양시비가 소나무잎의 왁스함량, 접촉각 및 무기양이온 함량과 토양산도에 미치는 영향)

  • 최기영;이용범;조영렬;이경재
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.3
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    • pp.255-262
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    • 1996
  • This study was carried out to investigate the effects of soil fertilizers on wax content, contact angle, mineral nutrient content of Japanese red pine (Pinus densiflora Sieb, et Zucc.) leaves and soil acidity of Japanese red pine communities in Namsan and Kwangnung to see whether they can recover forest decline. Japenese red pine communities were treated with $Ca(OH)_2$, $Mg(OH)_2$, $Ca(OH)_2+Mg(OH)_2$+C.F.(compound fertilizer) in a randomized complete block design with 3 replication from November, 1990 through October, 1993. Wax content, contact angle value and mineral nutrient content of Japanese red pine leaves and soil pH of communities were measured and the results obtained are as follows: 1. Contact angle value and wax content of Japenese red pine leaves increased when the fertilizers were applied in soil. The order leaves grew, the smaller their contact angle values. 2. K and Ca contents of Japanese red pine leaves were higher in Namsan than in Kwangnung, whereas Mg content was higher in Kwangnung. K and Mg contents of the leaves increased with fertilization both in Namsan and Kwangnung. 3. Soil acidity of pH 4.2 ~ 4.3 was shown in Namsan and pH 4.6 ~ 4.9 in Kwangnung. No acidity changes were shown when the fertilizers were applied in soil. However with the lapse of the soil fertilizer application time, there was the indication that soil pH became higher in the fertilizer treatments than in the control.

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Microfiltration of Chlorella sp.: Influence of material and membrane pore size

  • Ahmad, A.L.;Yasin, N.H. Mat;Derek, C.J.C.;Lim, J.K.
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.143-155
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    • 2013
  • Four membranes were used to separate Chlorella sp. from their culture medium in cross-flow microfiltration (MF) experiments: cellulose acetate (CA), cellulose nitrate (CN), polypropylene (PP) and polyvinylidenefluoride (PVDF). It was found that the hydrophilic CA and CN membranes with a pore size of 1.2 ${\mu}m$ exhibited the best performances among all the membranes in terms of permeation flux. The hydrophobicity of each membrane material was determined by measuring the angle between the water (liquid) and membrane (solid). Contact angle measurements showed that deionized (DI) water had almost adsorbed onto the surfaces of the CA and CN membranes, which gave $0.00^{\circ}$ contact angle values. The PP and PVDF membranes were more hydrophobic, giving contact angle values of $95.97^{\circ}$ and $126.63^{\circ}$, respectively. Although the pure water flux increased with increasing pore diameter (0.8 < 1.2 < 3.0 ${\mu}m$) in hydrophilic CA and CN membranes, the best performance in term of filtration rate for filtering a microalgae suspension was attained by membranes with a pore size of 1.2 ${\mu}m$. The fouled membrane pore sizes and pore blocking were inspected using a scanning electron microscope (SEM). MF with large pore diameters was more sensitive to fouling that contributed to intermediate blocking, where the size of the membrane pores is almost equivalent to that of cells.

Friction Drag Reduction using Microstructured Surfaces (마이크로 구조를 이용한 유체 표면마찰의 감소)

  • Park, Chi-Yeol;Bae, Seung-Il;Lee, Sang-Min;Ko, Jong-Soo;Chung, Kwang-Hyo
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.12
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    • pp.117-122
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    • 2009
  • The hexagonal network-type PDMS microstructures were fabricated and they were employed to low-friction drag surfaces. While the lowest contact angle measured from the smooth surface was $108^{\circ}$ the highest contact angle measured from the microstructured surfaces was $145^{\circ}$ The moving speed of bullet-type capsule attached with a PDMS pad of smooth surface ($CA=108^{\circ}$) was 0.1261 m/s and that with a PDMS pad of microstructured surface ($CA=145^{\circ}$) was 0.1464 m/s. Compared with the smooth surface, the microstructured surface showed 16.1% higher moving speed. The network-type microstructures have a composite surface that is composed with air and PDMS solid. Therefore, the surface does not wet: rather water is lifted by the microstructures. Because of the composite surface, water shows slip-flow on the microstructures, and thus friction drag can be reduced.

Formation of Superhydrophobic Surfaces on Fluoropolymer Films Using Ion Implantation

  • Park, Yong-Woon;Jo, Yong-Jun;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak
    • Journal of Radiation Industry
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    • v.6 no.4
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    • pp.323-328
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    • 2012
  • In this study, a facile method to fabricate superhydrophobic surfaces on perfluoroalkoxy (PFA) films using ion implantation was developed. PFA films were implanted at 100 keV with a fluence ranging from $4{\times}10^{16}$ to $7{\times}10^{16}ions\;cm^{-2}$. The surface properties of the implanted films were investigated in terms of their surface morphology, wettability, and chemical composition. As the fluence increased to $6{\times}10^{16}ions\;cm^{-2}$, the surface morphology and surface roughness of the PFA films were dramatically changed. The PFA surface implanted at a fluence of $6{\times}10^{16}ions\;cm^{-2}$ showed a maximum contact angle (CA) of $157.1^{\circ}$, while the control CA of the smooth PFA surface was $103.6^{\circ}$. Thus, the superhydrophobic surface was successfully fabricated by ion implantation.

Physical Properties of the Hydrogel Using Alginate (Alginate가 포함된 하이드로겔의 물리적 특성)

  • Woo, Chul-min;Heo, Seongin;Lee, Hyun Mee
    • Journal of Korean Ophthalmic Optics Society
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    • v.20 no.4
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    • pp.463-469
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    • 2015
  • Purpose: A hydrogel including alginate and $CaCl_2$ extracted from seaweed was manufactured, and their physical properties were investigated. Also, its applicability as contact lenses was examined. Methods: A film-type sample used in this experiment was manufactured using 2-hydroxyethyl methacrylate (HEMA), which is the raw material of hydrogel contact lenses; azobisiobutyonitile (AIBN), which is an initiator and ethylenglycoldimethacrylate (EGDMA), which is a cross-linking agent. It was hydrated in a PBS solution for 24 hours, and an interpenetrating polymer network (IPN) was formed in 1% and 2% alginate and 1%, 3%, and 5% $CaCl_2$ solutions for 24 hours, respectively. Results: The measurement of the physical properties of the film after the IPN showed that the moisture content was 30.89~36.89%, the refractive index was 1.431~1.441, the contact angle was $62.98{\sim}80.45^{\circ}$, and the tensile strength was 2.378~4.215 ($gf/mm^2$). Also, the physical properties hardly changed as the content of alginate increased, and the moisture content decreased as the content of $CaCl_2$ increased. As a result of the IPN, the moisture content and contact angle decreased compared to those of basic HEMA, but the tensile strength increased. The tensile strength of the second IPN was higher than that of the first IPN. In the case of $CaCl_2$, for the sample polymerized for 24 hours and the second IPN sample with 2% alginate, the contact angle decreased as the content of $CaCl_2$ increased. Conclusions: In this study, the tensile strength increased as the content of $CaCl_2$ increased, and the wettability increased as a result of IPN of alginate and $CaCl_2$. The hydrogel containing the alginate and $CaCl_2$ was confirmed possible utilization as contact lens material.

Effects of Static Contact Angle and Roughness on Rolling Resistance of Droplet (액적의 구름저항에 대한 정접촉각 및 거칠기의 영향)

  • Cho, Won Kyoung;Cho, Sang Uk;Kim, Doo-In;Kim, Dae-Up;Jeong, Myung Yung
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.1
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    • pp.23-28
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    • 2016
  • In this study, the effects of the contact angle (CA) and contact angle hyteresis (CAH) of planar and nano-patterned surfaces on rolling resistance of water droplet were studied. Based on the investigation on the CAH of water droplet on surfaces with various static wettability, it was found that the rolling resistance coefficient of water droplet is highly influenced by the surface pattern as well as CAH. The observed results suggest that the optimal surface patterns should be designed in order to minimize the rolling resistance of water droplet for the practical applications where superhydrophocitiy is required.