• Journal of Korean Ophthalmic Optics Society
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• v.19 no.2
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• pp.179-188
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• 2014

Purpose: The present study was aimed to investigate the cleaning efficacy of multi-purpose solutions containing different types and content of surfactants and their effect on the visible light transmittance of soft lens. Methods: Soft lenses made of different materials (etafilcon A and hilafilcon B) were deposited tear proteins by using the artificial tear and then compared the resulting cleaning efficacy and visible light transmittance after cleaning the lens with 6 types of multi-purpose solutions containing different content of surfactants. Results: The cleaning efficacy of multi-purpose solutions was variously shown as approximately 23~43% according to the active concentration of surfactants and surface tension in multi-purpose solution when etafilcon A lens cleaned with rubbing. The highest cleaning efficacy was detected when cleaned with the multi-purpose solution containing hydrogen peroxide besides surfactant however, the amount of remaining protein was still high on the lens. After washed with multi-purpose solution, the visible light transmittance of lens was in 89.8 to 90.8%. The amount of protein deposited on hilafilcon B lens was very small compared with it on etafilcon A lens even though it was incubated in artificial tears for 7 days, which showed 5~10% of protein amount in etafilcon A lens and the decrease of visible light transmittance was also not significant. In case of rubbing with multi-purpose solution, the cleaning efficacy on hilafilcon B lens was in 45.4 to 67.4% however, the order of cleaning efficacy of multi-purpose solution was different from it on etafilcon A lens. The visible light transmittance of hilafilcon B lens has been restored to the level of new lens. Conclusions: From the result, it is concluded that the appropriate multi-purpose solution should be selected according to the lens material and the amount of protein deposit on the basis of understanding surfactants and active principle for proper care of protein deposit on soft lens and the cleaning with rubbing is more efficient for lens care regardless of manufacturer's guideline.

• Journal of Korean Ophthalmic Optics Society
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• v.21 no.2
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• pp.91-98
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• 2016

Purpose: This study investigated the masking effect of the hydrogel lens and silicone hydrogel lens on the cornea with refractive surgery and without surgery. Methods: 24 university students (means age: $23.48{\pm}2.89years$) without refractive surgery (12, control group) and with refractive surgery (LASIK: 8, LASEK: 4, experimental group) participated in the study. Mean refractive errors of right eyes were -2.73 D for control group and -0.24 D for experimental group. The differences in the refractive power and corneal topography map between pre- and post-wearing the -3.00 D lenses were compared, and 2 kinds of hydrogel contact lenses (0.89 Mpa, 0.49 Mpa) and 2 kinds of silicone hydrogel lenses (1.5 Mpa, 0.8 Mpa) were used for -3.00 D lenses. NVision-K5001 (Shin nippon, Japan) was used to measure the refractive power and Keratograph 5M (Oculus, Germany) to measure the corneal topography map change. Results: Variations in the refractive power increased to the plus direction in the experimental group after wearing soft contact lenses. The corneal topography map showed significant changes on the both groups after wearing soft contact lenses (p<0.05). However there were no significant differences in the refractive power and corneal topography map variations by lens materials. Conclusions: Wearing soft contact lenses showed corneal topography map changes. Especially wearing soft contact lenses on the flat cornea after corneal refractive surgery showed greater corneal power changes. Therefore, it should pay attention to refractive change in case of prescribing soft contact lenses to patients with corneal refractive surgery.

• Tribology and Lubricants
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• v.25 no.4
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• pp.207-216
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• 2009

Friction tests were carried out in order to investigate the effects of temperature on the friction and wear behaviors between a PMMA film and a fused silica lens using a microtribometer. The friction forces on the PMMA film were measured under atmospheric condition as the temperature of the film was increased from 300 K to 443 K. The contact area between the film and the lens was observed. The tribological characteristics of the film were significantly changed as the temperature increased. The changes were discussed with the change of the film state from glassy to viscous flow. In addition, the results showed that the friction behavior can be varied with the thermal history of the PMMA film. Residual solvent in the PMMA film could emerge to the PMMA surface due to an additional heating and the solvent on the film surface decreased the friction force.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.749-754
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• 2009

HEMA (2-hydroxyethyl methacrylate) is a hydrophilic material which is broadly used for ophthalmologic purposes and especially in the manufacture of soft contact lenses. Also, the oxygen transmissibility (Dk/t) is a very important physical characteristic in the evaluation of a material’s adequacy to be used to produce contact lenses. This study used HEMA (2-hydroxyethyl methacrylate), MMA (methylmethacrylate), NVP (Nvinyl-pyrrolidone), the cross-linker EGDMA (ethylene glycol dimethacrylate) for copolymerization, and measured the oxygen transmissibility of the central and peripheral areas of the manufactured general and color contact lenses using the polarographic method. The measurement showed that the decreased amount of oxygen transmissibility of the central and peripheral areas of the contact lenses measured using the polarographic method range between 40.77% and 49.13%, and the oxygen transmissibility of the color contact lens showed a larger decrease due to the effects of the coloring materials.

• Design & Manufacturing
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• v.17 no.2
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• pp.15-21
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• 2023

In this study, a diamond turning machine and a laser-assisted machining module were utilized for the complex combined cutting of aspheric shapes and fine patterns on the surface of high-hardness brittle material, silicon. The analysis of material's form accuracy and corrective machining was conducted based on key factors such as laser output, rotational speed, feed rate, and cutting depth to achieve form accuracy below 1 ㎛ and surface roughness below 0.1 ㎛. The cutting condition and corrective machining methods were investigated to achieve the desired form accuracy and surface roughness. The rotational speed of the spindle and the linear feed rate of the diamond turning machine were varied in five stages for the cutting condition test. Surface roughness and form accuracy were measured using both a contact surface profilometer and a non-contact surface profilometer. The experimental results revealed a tendency of improved surface roughness with increased rotational speed of the workpiece, and the best surface roughness and form accuracy were observed at a feed rate of 5 mm/min. Furthermore, based on the cutting condition experiments, corrective machining was performed. The experimental results demonstrated an improvement in form accuracy from 0.94 ㎛ to 0.31 ㎛ and a significant reduction in the average value of the surface roughness curve from 0.234 ㎛ to 0.061 ㎛. This research serves as a foundation for future studies focusing on the machinability in relation to laser output parameters.

• Journal of the Korean Chemical Society
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• v.55 no.1
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• pp.98-103
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• 2011

This study was done for the preparation of macromolecular material with UV-blocking features by adding the benzophenone group that is commonly used as a UV-absorbent and $TiO_2$ which is known to be a very stable material in chemical and physical aspects. Also, we compared the level of UV absorbency of the polymer produced from polymerization with previous materials and measured basic properties such as water content, refractive index and optical transmittance of produced contact lenses. The results of the measurement showed that the refractive index and water content of the contact lens with added UV-absorbent was 1.430~1.440 and 35.0~45.0% respectively, which was similar to that of previous contact lenses. Also, for optical transmittances of each wave length, contact lenses without the UV-absorbent was 89%, 88% and 89% respectively for UV-A, UV-B and visible light, indicating that the UV transmittance is very high though contrary with cases of contact lenses with added 2-hydroxy-4-methoxy-benzophenone and 2,4-dihydroxy-benzophenone which showed transmittances of 0% and 6% respectively for UV-A and UV-B showing a UV-blocking effect. Meanwhile, contact lenses with added $TiO_2$ showed transmittance of 6% and 51% respectively for UV-A and UV-B also showing a UV-blocking effect. The visible transmittance was 77~89% showing that it satisfies the visible transmittance required for ophthalmological materials.

• Journal of Integrative Natural Science
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• v.6 no.1
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• pp.1-7
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• 2013

Polyurethane resin containing isocyanate is marked by excellent tensile and mechanical strengths and this test aims to gauge its applicability as a medical high polymer. Tris [2-(acryloyloxy)ethyl]isocyanurate and hexamethylenediisocyanate were added to a basic mixing ratio of HEMA (2-hydroxyethyl methacrylate), MMA (methyl methacrylate), NVP (n-vinyl-2-pyrrolidone) and crosslink agent, EGDMA (ethylene glycol dimethacrylate) with increasing proportions and copolymerized respectively. Also, the basic physical properties of the polymerized high polymers including refraction rate, tensile strength, light transmission and water content were measured to confirm that they are appropriate as hydrogelcontact lenses. After measuring the physical properties of high performance polymers produced by adding tris [2-(acryloyloxy) ethyl]isocyanurate, it was found that the average tensile strengths of sample TRIS1 to TRIS10 were between 0.285 and 0.612 kgf, while the average values of refractive index were ranged from 1.441 to 1.449 with water content from 30.00 to 37.35%.The measurement of physical properties of the copolymers generated by adding hexamethylenediisocyanate showed that the average tensile strength of sample HEXA1 to HEXA10 ranged from 0.267 to 1.742 kgf, the refractive index ranged from 1.443 to 1.475 and water contents were in the range of 21.22 to 35.58%. In all combinations the transmission rates satisfied the transmittance of general hydrogel contact lenses. From theresults, it is possible to conclude that the produced copolymers can be used as contact lens materials with excellent tensile strength.

• Journal of Korean Ophthalmic Optics Society
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• v.15 no.1
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• pp.39-46
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• 2010

Purpose: To assess the reliability for measuring the back vertex power of soft contact lenses by dry blotting and wet cell method using an auto-lensmeter. Methods: The soft contact lenses used for measurement were 5 types that were distributed in Korea, and 4 back vertex powers (-1.50D, -3.00D, -6.00D, -9.00D) were used. and repeatability and reproducibility were evaluated by measuring them with an auto-lensmeter by two examiners. Results: Measured powers by dry blotting method were ranged in mean differences from 0.03D to 0.18D for overall lenses, 0.10D to 0.18D for silicone hydrogel lenses, 0.03D to 0.08D for hydrogel lenses. The mean differences between two examiners were less than 0.10D, and the inter-examiner reproducibility was good for dry blotting method. The mean difference between powers determined by wet cell method were 0.09D to 0.69D, the mean differences between two examiners were 0.02D to 0.59D. The reliability of measurements and inter-examiner reproducibility were less than dry blotting method. Conclusions: The reliability of measurements for all materials was better in dry blotting than wet cell method, the re liability of measurements for silicone hydrogel lenses was low in both methods. In clinical practical which requires quick checking of back vertex power using an auto-lensmeter. dry blotting method is thought to be more efficient than wet cell one.

• Korean Journal of Materials Research
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• v.23 no.8
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• pp.453-461
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• 2013

Controlling the stick and slip motions of the contact lines in a confined geometry comprised of a spherical lens with a flat substrate is useful for manufacturing polymer ring patterns. We used a sphere on a flat geometry, by which we could control the interfaces of the solution, vapor and substrate. By this method, hundreds of concentric ring-pattern formations of a linear conjugated polymer, poly [2-methoxy-5-(2-thylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), were generated with excellent regularity over large areas after complete solvent evaporation. Subsequently, the MEH-PPV ring patterns played a role as a directed template to organize highly regular concentric rings of single-walled carbon nanotubes(SWCNTs); when a droplet of the SWCNT suspension in water was casted onto the prepared substrate, hydrophobic polymer patterns confined the water dispersed SWCNTs in between the hydrophilicized $SiO_2/Si$ substrate. As the solvent evaporated, SWCNT-rings were formed in between MEH-PPV rings with controlled density. Finally, we used a lift-off process to produce SWCNT patterns by the removal of a sacrificial polymer template with organic solvent. We also fabricated a field effect transistor using self-assembled SWCNT networks on a $SiO_2/Si$ substrate.

• Economic and Environmental Geology
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• v.39 no.1 s.176
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• pp.1-7
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• 2006

This paper attempts to locate and define a quartzite deposit in Geochang, Kyongsangnam Province in order to establish its commercial viability. The quartzite deposit (Poongwon Mine) occurs as lens or boudinage at the contact between mica schist of the Deogyusan formation and granite gneiss. During Precambrian, regional metamorphism and granitization may have caused the formation ot quartzite layers through recrystallization and rearrangement of silica components derived from older sedimentary rocks, probably chert and/or sandstone. The deposit is composed of fine-grained milky, or light yellowish quartz showing weak laminations with fairly dense and rough appearance in outcrop. It reaches about $60\;m(height)\times140\;m(length)\times35m(width)$ with attitude of $N57^{\circ}E-N8^{\circ}4E\;and\;51^{\circ}-60^{\circ}NW$. The average grade of the quartzite samples is $SiO_2=94.4\;wt\%,\;A1_2O_3=3.3\;wt\%,\; Fe_2O_3=0.8\;wt\%,\;K_2O=0.7\;wt\%$, which can be used for foundry, constructional materials, or concrete making. The proved reserve was estimated as 200,811 tonnage.