• 제목/요약/키워드: Constituent phase

검색결과 123건 처리시간 0.022초

유기합금의 열처리조건에 따른 구성상의 제어와 최적 항균특성 측정방법의 선정 (The Selection of Optimum Measurement Method of Antimicrobial Activity and Constituent Phase of Yuggi Alloy according to Heat Treatment Condition)

  • 박규하;황대연;손홍주;최지웅;김혜성
    • 열처리공학회지
    • /
    • 제34권5호
    • /
    • pp.233-238
    • /
    • 2021
  • The mechanical, anti-tarnishing, and corrosion characteristics of Yuggi (Cu-22wt%Sn) alloy are greatly affected by fraction of constituent phases according to heat treatment method. The Yuggi heat-treated at 750℃ has a β1' phase of 98% or more, which is a high-temperature disordered beta phase, on the other hand, cast Yuggi that Sn is solid-solutioned into Cu consists with α-phase over 60v/o. This difference of constituent phases of Yuggi may cause a difference in dissolution of Cu under antimicrobial test condition. Nonetheless, few studies have been conducted on the effect of fraction of constituent phases and constituent phases in antimicrobial activity. In addition, few studies have also been conducted on the suitable method measuring the antimicrobial activity of Yuggi. Hence, the purpose of this study is to provide an optimum measurement method of antimicrobial activity, and to evaluate quantitatively the effect of constituent phases on antimicrobial activity.

Ni기 초내열합금의 액상확산접합부 생성상의 금속조직학적 검토 (Metallurgical Study of Microconstituents in Transient Liquid Phase Bended Joints of Ni Base Superalloy)

  • 김대업
    • Journal of Welding and Joining
    • /
    • 제19권1호
    • /
    • pp.75-81
    • /
    • 2001
  • The metallurgical study of microconstituents in transient liquid phase bonded joints of Ni-base single crystal superalloys, CMSX-2 and CMSX-4 was investigated employing MBF-80 insert metal. TLP bonding of specimens was carried out at 1,373~1,523K for 0~19.6ks in vacuum. Three types of microconstituents ; needle-like constituent, dot-like constituent and abnormal shape constituent were formed in the bonded interlayer during TLP bonding operation. All these microconstituents were identified as boride. Microconstituents contain a large percentage of Cr in the early stage of bonding. As increasing the holding time, the amount of Cr was decreased and the amount of W, Co and Re were increased. From the analysis results of electron diffraction pattern by TEM, composition of elements in microconstituents were into MBlongrightarrowM$_{5}$B$_3$longrightarrowM$_2$B type with the increased in holding time. It can be explained by the fact that the relative amount of boron in microconstituents was decreased when the holding time was increased.d.

  • PDF

나노인덴테이션으로 측정한 Ti(C0.7N0.3)-WC-Ni 써멧 구성상의 경도 (Hardness of Constituent Phases in Ti(C0.7N0.3)-WC-Ni Cermets Measured by Nanoindentation)

  • 김성원;김대민;강신후;김형준;김형태
    • 한국세라믹학회지
    • /
    • 제46권1호
    • /
    • pp.116-121
    • /
    • 2009
  • The constituent phases in Ti($C_{0.7}N_{0.3}$)-xWC-20Ni (wt%, x=5, 15, 25) cermets were characterized using nanoindentation in conjunction with observation of microstructure. The microstructure of cermet is composed of hard phase and binder phase, which gave rise to a wide range of hardness distribution when nanoindentation was carried out on the polished surface of cermets. Because of the inhomogeneous nature of cermet microstructure, observation of indented surface was indispensable in order to separate the hardness of each constituent phase. The measured values of hardness using nanoindentation were ${\sim}14\;GPa$ for the binder phase and ${\sim}24$ to 28 GPa for the hard phase, of which nanoindentation hardness was decreased with the addition of WC into Ti($C_{0.7}N_{0.3}$)-Ni system. In addition, the nanoindentation hardness of Ni binder phase was much higher than reported Vickers hardness, which could result from confined deformation of binder phase due to the surrounding hard phase particles.

$Pb(Zn, Mg)_{1/3}Nb_{2/3}O_3-PbTiO_3$계에서 구성 산화물 첨가에 따른 Perovskite상 안정화 및 DPT성 증대 효과 (Stbilization of Perovskite Phase and Enhanced DPT Characteristics of $Pb(Zn, Mg)_{1/3}Nb_{2/3}O_3-PbTiO_3$ Ceramics by the Additionof Excess Constituent Oxides)

  • 이규만;장현명;유병두
    • 한국세라믹학회지
    • /
    • 제30권11호
    • /
    • pp.925-932
    • /
    • 1993
  • The perovskite phase in PZN-PMN-PT (Pb(Zn, Mg)1/3Nb2/3O3-PbTiO3) pseudoternary ceramics was stabilized by the addition of excess constituent divalent oxides (PbO, MgO and ZnO). The excess addition of 5mol% MgO or 7.5mol% PbO fully stabilized the perovskite phase. The enhanced diffuse phase transition (DPT) and the decrease in the electrical resistivity observed in the presence of excess ZnO or MgO were interpreted in terms of the additional formation of negatively charged, short-range ordered 1:1 domains with a concomitant generation of charge carriers, holes.

  • PDF

나노인덴테이션을 이용한 Ti(C0.7N0.3)-NbC-Ni 써멧 구성상의 경도평가 (Measurement of Hardness of Constituent Phases in Ti(C0.7N0.3)-NbC-Ni Cermets Using Nanoindentation)

  • 김성원;김대민;강신후;류성수;김형태
    • 한국분말재료학회지
    • /
    • 제15권6호
    • /
    • pp.482-488
    • /
    • 2008
  • The indentation technique has been one of the most commonly used techniques for the measurement of the mechanical properties of materials due to its experimental ease and speed. Recently, the scope of indentation has been enlarged down to the nanometer range through the development of instrumentations capable of continuously measuring load and displacement. In addition to testing hardness, the elastic modulus of submicron area could be measured from an indentation load-displacement (P-h) curve. In this study, the hardness values of the constituent phases in Ti($C_{0.7}N_{0.3}$)-NbC-Ni cermets were evaluated by nanoindentation. SEM observation of the indented surface was indispensable in order to separate the hardness of each constituent phase since the Ti($C_{0.7}N_{0.3}$)-based cermets have relatively inhomogeneous microstructure. The measured values of hardness using nanoindentation were ${\sim}20$ GPa for hard phase and ${\sim}10$ GPa for binder phase. The effect of NbC addition on hardness was not obvious in this work.

제주도 동부 해안대수층의 수리특성 산정과 지하수위 예측 (Estimation of Hydraulic Characteristics and Prediction of Groundwater Level in the Eastern Coastal Aquifer of Jeju Island)

  • 조시범;전병칠;박은규;최광준;송성호;김기표
    • 한국환경과학회지
    • /
    • 제23권4호
    • /
    • pp.661-672
    • /
    • 2014
  • Due to tidal force, it is very difficult to estimate the hydraulic parameters of high permeable aquifer near coastal area in Jeju Island. Therefore, to eliminate the impact of tidal force from groundwater level and estimate the hydraulic properties, tidal response technique has been mainly studied. In this study we have extracted 38 tidal constituents from groundwater level and harmonic constants including frequency, amplitude, and phase of each constituent using T_TIDE subroutine which is used to estimate oceanic tidal constituents, and then we have estimated hydraulic diffusivity associated with amplitude attenuation factor(that is the ratio of groundwater level amplitude to sea level amplitude for each tidal constituent) and phase lag(that is phase difference between groundwater level and sea level for each constituent). Also using harmonic constants for each constituent, we made the sinusoidal wave and then we constructed the synthesized wave which linearly combined sinusoidal wave. Finally, we could get residuals(net groundwater level) which was excluded most of tidal influences by eliminating synthesized wave from raw groundwater level. As a result of comparing statistics for synthesized level and net groundwater level, we found that the statistics for net groundwater level was more insignificant than those of synthesized wave. Moreover, in case of coastal aquifer which the impact of tidal force is even more than those of other environmental factors such as rainfall and groundwater yield, it is possible to predict groundwater level using synthesized wave and regression analysis of residuals.

한국연안의 비조화상수 개선에 관한 연구 (Method for improving calculation of nonharmonic constants of tidal stations in Korea)

  • 김영택;유학렬;이은일
    • 한국지구과학회:학술대회논문집
    • /
    • 한국지구과학회 2010년도 춘계학술발표회 논문집
    • /
    • pp.59-62
    • /
    • 2010
  • 우리나라 주변 해역별 조석특성을 쉽게 보기 위해 정의된 비조화상수를 고찰하였다. 국립해양조사원의 표준항 가운데 20개 조위관측소의 자료로부터 계산한 조화상수 값을 기반으로 비조화 상수를 계산하였다. 이 가운데 표준항의 관측 및 예보조위자료를 이용하여 임의지점의 조위를 개략적으로 추산하기 위해 사용되는 개정수(조시차 및 조고비)는 천해분조가 강하게 발달하는 해역에서는 적용하는데 한계가 있음을 알 수 있었다. 또한 기존의 조화분해 소프트웨어로부터 구한 표준시 자오선기준 지각(phase lag, 또는 epoch)에서 로컬 지각(local phase lag)을 구하는데 사용하고 있는 p 값을 관습적으로 통용되고 있는 정수(integer)형의 첨가수(suffix)대신 a/15(a=각 분조의 각속도)를 사용하는 방안을 제시하였다.

  • PDF

Microstructural Characterization of Composite Electrode Materials in Solid Oxide Fuel Cells via Image Processing Analysis

  • Bae, Seung-Muk;Jung, Hwa-Young;Lee, Jong-Ho;Hwang, Jin-Ha
    • 한국세라믹학회지
    • /
    • 제47권1호
    • /
    • pp.86-91
    • /
    • 2010
  • Among various fuel cells, solid oxide fuel cells (SOFCs) offer the highest energy efficiency, when taking into account the thermal recycling of waste heat at high temperature. However, the highest efficiency and lowest pollution for a SOFC can be achieved through the sophisticated control of its constituent components such as electrodes, electrolytes, interconnects and sealing materials. The electrochemical conversion efficiency of a SOFC is particularly dependent upon the performance of its electrode materials. The electrode materials should meet highly stringent requirements to optimize cell performance. In particular, both mass and charge transport should easily occur simultaneously through the electrode structure. Matter transport or charge transport is critically related to the configuration and spatial disposition of the three constituent phases of a composite electrode, which are the ionic conducting phase, electronic conducting phase, and the pores. The current work places special emphasis on the quantification of this complex microstructure of composite electrodes. Digitized images are exploited in order to obtain the quantitative microstructural information, i.e., the size distributions and interconnectivities of each constituent component. This work reports regarding zirconia-based composite electrodes.

Fabrication Condition for Single Phase of Bi-superconductor Thin Film

  • Ahn, Joon-Ho;Park, Yong-Pil;Wang, Jong-Bae
    • Transactions on Electrical and Electronic Materials
    • /
    • 제2권4호
    • /
    • pp.11-14
    • /
    • 2001
  • Phase intergrowth in BSCCO thin films has been Investigated. It turfed out from XRD analyses of these phases that molar fraction of each constituent phase in the intergrowth thin film can be exhibited as a function of substrate temperature and ozone pressure. Super- conducting behavior of the intergrowth thin aim Is also discussed.

  • PDF

텅스텐 중합금에 Mn 첨가에 따른 미세조직 (The Effect of Mn on Microstructural Change in 93W-5.6Ni-1.4Fe Heavy Alloy)

  • 김은표
    • 한국분말재료학회지
    • /
    • 제5권1호
    • /
    • pp.35-41
    • /
    • 1998
  • The effect of Mn on the densification and the microstructural change in W heavy alley was investigated with adopting the improved Mn-adding method. In order to avoid the pore formation problems associated with Mn powder mixing to the other constituent powders, Mn was added afterwards to the sintered heavy alloy; Mn powder was spread homogeneously on the surface of the sintered heavy alloy compact, and this Mn powder contained specimen was resintered at the same sintering temperature. As expected, the resintered specimen showed the pore free microstructure because Mn was reduced separately from the other constituent elements. It was also founded that W grains grew rapidly at the initial stage of resintering treatment due to the activated reprecipitation of the excess W atoms substituted by Mn atoms, but the growth rate of W grains was slowly lowered with the prolonged sintering time, especially, compared to the Mn free heavy alloy. Such a retardation of grain growth should be attributed to the decreased W solubility in the Mn contented matrix phase. Furthermore, Mn addition resulted in the decrease of contiguity by improving the wetting between matrix phase and W grain.

  • PDF