• The Korean Journal of Ceramics
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• 제4권3호
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• pp.213-221
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• 1998

$BaCe_{0.9}Gd_{0.1_O_{2.95}$ powder was synthesized by oxalate coprecipitation method. Precipitate with a stoichimetric ratio of the cations was prepared by adding a mixture of Ba, Ce and Gd nitrate solution to an oxalic acid solution at pH 4. Reaction between the constituent oxides to form a perovskite phase was initiated at $800^{\circ}C$ and a single phase $BaCe_{0.9}Gd_{0.1_O_{2.95}$ powder having good sinterability was obtained after calcination at $1000^{\circ}C$. Sintering green compacts of this powder for 6 h showed a considerable densification to start at $1100^{\circ}C$ and resulted in 93% and 97% relative densities at $1300^{\circ}$ and at $1450^{\circ}C$, respectively. Whereas the power compacts prepared by solid state reaction had lower relative densities, 78% at $1300^{\circ}$and 90% at $1450^{\circ}C$. Fine particles of $CeO_2$ second phase were observed in the surface of the sintered compacts. This was attributed to the evaporation of BaO from the surface that had been exposed during thermal etching.

• 정보처리학회논문지B
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• 제17B권1호
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• pp.85-92
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• 2010

부분 의미 분석 시스템은 문장의 구성 요소들이 술어와 갖는 관계를 분석하는 것으로 문장에서 술어의 주체, 객체, 도구 등을 나타내는 의미 논항을 확인하게 된다. 본 논문에서 개발한 부분 의미 분석 시스템은 두 단계로 구성되어 있는데, 먼저 부분 구문 분석 결과로부터 의미 논항의 경계를 찾는 의미 논항 확인 단계를 수행하고 다음으로 확인된 의미 논항에 적절한 의미역을 부착하는 의미역 할당 단계를 수행한다. 순차적인 두 단계 방법을 적용하는 것에 의해서, 학습 성능 저하의 주요한 원인인 클래스 분포의 불균형 문제를 완화할 수 있고, 각 단계에 적합한 자질을 선별하여 사용할 수 있다. 본 논문에서는 PropBank 말뭉치에 기반한 CoNLL-2004 shared task의 데이터 집합 및 평가 프로그램을 사용하여 각 단계가 시스템의 전체 성능에 기여하는 정도를 보인다.

• 한국정보과학회논문지:컴퓨팅의 실제 및 레터
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• 제16권5호
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• pp.531-540
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• 2010

본 논문은 최대 엔트로피 모형에 기반한 두 단계 부분 의미 분석 방법을 제안한다. 먼저, 의미 논항의 경계를 인식하고, 그 다음 단계에서 확인된 논항에 적절한 의미역을 할당한다. 두 단계 부분 의미 분석에서는 두 번째 단계인 논항 분류가 논항 확인 단계의 결과에 기반하여 수행되기 때문에 논항 확인의 성능이 매우 중요하다. 본 논문은 논항 확인의 성능을 향상시키기 위하여 논항 확인의 전처리 단계에 구문 지식을 통합한다. 구체적으로, 절 인식 결과로부터 술어의 인접절 및 상위절들을 확인하고, 구문 분석 결과로부터 술어의 부모 노드로부터 구문 구성 요소의 부모 노드까지의 트리 거리를 추출하여 전처리 단계에서 활용한다. 실험을 통해, 구문 지식을 활용하는 것이 부분 의미 분석 성능에 기여함과 제안하는 두 단계 방법이 한 단계 방법보다 우수한 성능을 낼 수 있음을 보인다.

• 열처리공학회지
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• 제29권2호
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• pp.51-55
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• 2016

The P/M processing of titanium aluminide using amorphous TiAl is developed by which it is possible to overcome inherent fabricability problems and to obtain a fine microstructure. A high quality amorphous TiAl powder produced by reaction ball milling shows clear glass transition far below a temperature at the onset of crystallization in differential scanning calorimetry above a heating rate of 0.05 K/s. We obtained a fully dense compact of amorphous TiAl powders, encapsulated in a vacuumed can, via viscous flow by hot isostatic pressing (HIP). Isothermally annealing of HIP'ed amorphous compact under a pressure of 196 MPa shows a progressive growth of ${\gamma}-TiAl$ phase with ${\alpha}2$ ($Ti_3Al$), which is characterized by increasing sharpness of X-ray peaks with temperature. Fully dense HIP'ed compact of titanium aluminide TiAl shows a high hardness of 505 Hv, suggesting strengthening mechanisms by sub-micron sized grain of ${\gamma}-TiAl$ and particle-dispersion by second phase constituent, ${\alpha}2$.

• Computers and Concrete
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• 제15권5호
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• pp.735-758
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• 2015

This work deals with unilateral effect of quasi-brittle materials, such as concrete. For this propose, a two-dimensional meso-scale model is presented. The material is considered as a three-phase material consisting of interface zone, matrix and inclusions - each constituent modeled by an appropriate constitutive model. The Representative Volume Element (RVE) consists of inclusions idealized as circular shapes randomly placed into the specimen. The interface zone is modeled by means of cohesive contact finite elements developed here in order to capture the effects of phase debonding and interface crack closure/opening. As an initial approximation, the inclusion is modeled as linear elastic as well as the matrix. Our main goal here is to show a computational homogenization-based approach as an alternative to complex macroscopic constitutive models for the mechanical behavior of the quasi-brittle materials using a finite element procedure within a purely kinematical multi-scale framework. A set of numerical examples, involving the microcracking processes, is provided. It illustrates the performance of the proposed model. In summary, the proposed homogenization-based model is found to be a suitable tool for the identification of macroscopic mechanical behavior of quasi-brittle materials dealing with unilateral effect.

• 공업화학
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• 제18권2호
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• pp.130-135
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• 2007

EGCG의 안정성을 향상시키기 위해 ethosome에 포집을 시도하였다. 물에 에탄올을 첨가해서 EGCG의 용해도를 높임으로써 ethosome에 적정량의 EGCG이 포집될 수 있도록 하였다. EGCG 수용액의 농도와 ethosome 막을 구성하는 지질의 조성은 ethosome 입자크기와 포집효율에 상당한 영향을 미치는 것을 확인하고 ethosome의 액정상 형성은 편광 현미경을 사용하여 관측하였다. EGCG가 수용액 상태로 있을 때와 ethosome에 포집되어 있을 때, UV 또는 고온의 상태에서의 안정성을 비교한 결과 ethosome에 포집된 EGCG의 안정화 효과를 확인하였다. Ethosome에 토코페롤의 첨가는 UV에 의한 EGCG의 분해를 지연시켰다.

• Korea-Australia Rheology Journal
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• 제13권4호
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• pp.189-196
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• 2001

The phase morphology is an important factor in the rheology of immiscible polymer blends. Through its size and shape, the interface between the two phases determines how the components and the interface itself will contribute to the global stresses. Rheological measurements have been used successfully in the past to probe the morphological changes in model blends, particularly for dilute systems. For more concentrated blends only a limited amount of systematic rheological data is available. Here, viscosities and first normal stress differences are presented for a system with nearly Newtonian components, the whole concentration range is covered. The constituent polymers are PDMS and PIB, their viscosity ratio can be changed by varying the temperature. The data reported here have been obtained at 287 K where the viscosities of the two components are identical. By means of relaxation experiments the measured stresses are decomposed into component and interfacial contributions. The concentration dependence is quite different for the two types of contribution. Except for the component contributions to the shear stresses there is no clear indication of the phase inversion. Plotting either the interfacial shear or normal stresses as a function of composition produces in some cases two maxima. The relaxation times of these stresses display a similar concentration dependence. Although the components have the same viscosity, the stress-component curves are not symmetrical with respect to the 50/50 blend. A slight elasticity of one of the components seems to be the cause of this effect. The data for the more concentrated blends at higher shear rates are associated with a fibrillar morphology.

• 천문학논총
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• 제22권4호
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• pp.89-95
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• 2007

The warm ionized medium (WIM) outside classical H II regions is a fundamental gas-phase constituent of the Milky Way and other late-type spiral galaxies, and is traced by faint emission lines at optical wavelengths. We calculate the photoionization models of the WIM in the Galaxy by a stellar UV radiation with the effective temperature 35,000 K assuming not only spherical geometry but also plane parallel geometry, and compare the results with the observed emission line ratios. We also show the dependence of the emission line ratios on various gas-phase abundances. The emergent emission-line ratios are in agreement with the average-values of observed ratios of [S II] ${\lambda}6716/H{\alpha}$, [N II] ${\lambda}6583/H{\alpha}$, [O I] ${\lambda}6300/H{\alpha}$, [O III] ${\lambda}5007/H{\alpha}$, He I ${\lambda}5876/H{\alpha}$. However, their extreme values could not be explained with the photoionization models. It is also shown that the addition of all stellar radiation from the OB stars in the Hipparcos stellar catalog resembles that of an O7-O8 type star.

• 한국결정성장학회지
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• 제15권5호
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• pp.202-207
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• 2005

Kaolin과 규석 및 $Mg(OH)_2$등의 원료로 만들어진 slip을 casting 할 때 slip의 점도가 slip casting 속도와 소결체의 미세조직에 미치는 영향을 보면 slip-casting속도는 slip의 점도가 낮을 경우 감소하였으며 slip의 점도범위는 $3.0\~17.0\;cP$가 적당하였다. Slip의 점도를 조절하면 표면층, 표면 내부층, 중간층, 내면층의 미세조직을 비교적 균일하게 casting 할 수 있다 소성온도 $1350^{\circ}C$에서 시편의 구성광물은 cordierite 결정만으로 되어있었다.

• Korea-Australia Rheology Journal
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• 제17권4호
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• pp.165-170
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• 2005

In this study, high intensity ultrasound was employed to induce mechano-chemical degradation during melt mixing of polycarbonate (PC) and a series of styrene-acrylonitrile (SAN) copolymers. It was confirmed that generation of macroradicals of constituent polymers can lead to in-situ copolymer formation by their mutual combination, which should be an efficient path to compatibilize immiscible polymer blends and stabilize their phase morphology in the absence of other chemical agents. Based on the effectiveness of the compatibilization by ultrasound assisted mixing process, we investigated the effects of viscosity ratio of PC and SAN and AN content in SAN on the compatibilization of PC/SAN blends. It was found that effectiveness of compatibilization is optimal when the AN content is in the range of favorable interaction with PC and the viscosity of the matrix is higher than that of the dispersed phase. In addition, changes in the interfacial tension between PC and SAN were assessed by examining relaxation spectra which were obtained from measuring rheological properties of ultrasonically treated blends.