• 제목/요약/키워드: Constant rate model

검색결과 887건 처리시간 0.021초

고정층 흡착탑에서 석탄비산재로부터 합성한 Zeolite의 VOCs 흡착 해석 (Adsorption Analysis of VOCs of Zeolite Synthesized by Coal Fly Ash in a Fixed-bed Adsorber)

  • 김성수;이창한;박상욱
    • Korean Chemical Engineering Research
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    • 제48권6호
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    • pp.784-790
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    • 2010
  • 고정층 반응기에서 비산재로부터 합성한 제올라이트와 4종류의 활성탄을 사용하여 질소 기류에서 아세톤, 벤젠, 톨루엔, 에틸벤젠 증기의 파과곡선을 측정하였다. 흡착실험은 101.3 kPa, $40^{\circ}C$에서 혼합 가스의 유량 $70cm^3/min$, 흡착제의 공급량 5 g, 그리고 VOCs 증기의 농도는 포화조의 온도를 $30^{\circ}C$로 하여 행하였다. 실험으로부터 얻은 파과곡선의 비선형해석으로부터 VOCs의 흡착과 흡착제의 비활성화를 동시에 고려한 비활성모델의 흡착속도상수와 비활성속도상수를 구하여 문헌의 다른 흡착등온모델과 비교하였다. 검토한 모델 중 비활성모델이 실험결과와 가장 일치하였고 다음으로 Freundlich, DRK 모델 순으로 높은 상관관계를 나타내었다. 또한 파과곡선으로부터 구한 흡착제의 흡착용량은 VOC의 끓는점이 증가할수록 감소하였으며, 증기압이 증가할수록 증가하였다.

Power-Efficient Rate Allocation of Wireless Access Networks with Sleep-Operation Management for Multihoming Services

  • Lee, Joohyung;Yun, Seonghwa;Oh, Hyeontaek;Newaz, S.H. Shah;Choi, Seong Gon;Choi, Jun Kyun
    • Journal of Communications and Networks
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    • 제18권4호
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    • pp.619-628
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    • 2016
  • This paper describes a theoretical framework for rate allocation to maximize the power efficiency of overall heterogeneous wireless networks whose users are assumed to have multihoming capabilities. Therefore, the paper first presents a power consumption model considering the circuit power and radio transmission power of each wireless network. Using this model, two novel power efficient rate allocation schemes (PERAS) for multihoming services are proposed. In this paper, the convex optimization problem for maximizing the power efficiency over wireless networks is formulated and solved while guaranteeing the required quality of service (QoS). Here, both constant bit rate and variable bit rate services are considered. Furthermore, we extend our theoretical framework by considering the sleep-operation management of wireless networks. The performance results obtained from numerical analysis reveal that the two proposed schemes offer superior performance over the existing rate allocation schemes for multihoming services and guarantee the required QoS.

MODELING AND ANALYSIS OF AN EPIDEMIC MODEL WITH CLASSICAL KERMACK-MCKENDRICK INCIDENCE RATE UNDER TREATMENT

  • Kar, T.K.;Batabyal, Ashim;Agarwal, R.P.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제14권1호
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    • pp.1-16
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    • 2010
  • An epidemic model with Classical Kermack-Mckendrick incidence rate under a limited resource for treatment is proposed to understand the effect of the capacity for treatment. We have assumed that treatment function is strictly increasing function of infective individuals and becomes constant when the number of infective is very large. Existence and stability of the disease free and endemic equilibrium are investigated, boundedness of the solutions are shown. Even in this simple version of the model, backward bifurcation and multiple epidemic steady states can be observed with some sets of parameter values. Hopf-bifurcation analyses are given and numerical examples are provided to help understanding.

공냉식 수직평판형 흡수기의 흡수과정에 대한 근사해법 (Approximate Solution of Absorption Process in an Air-Cooled Vertical Plate Absorber)

  • 정은수
    • 설비공학논문집
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    • 제6권4호
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    • pp.453-462
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    • 1994
  • An unsteady quasi one-dimensional model of momentum, heat and mass transfer in a falling film of a vertical plate absorber which is cooled by air was developed using the integral method. Energy conservation of the absorber wall is considered in the model. The model can predict absorption rate, film thickness and mean velocity as well as concentration and temperature profiles. Predictions of steady state temperature and concentration profiles for LiBr/water system for constant wall temperature condition are in good agreement with the two-dimensional finite difference method solutions. Effects of operating conditions, such as convective heat transfer coefficient between the cooling air and the absorber wall, cooling air temperature and film thickness at inlet, on absorption rate of water vapor into LiBr/water solution were shown.

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공동주택 세대별 난방 성능 개선 연구 (A Study on Improved Heating Performance of an Apartment Housing Unit)

  • 서정아;신영기;김용기;이태원
    • 설비공학논문집
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    • 제28권2호
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    • pp.69-74
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    • 2016
  • Most hot water heating valves for apartments are constant-flow types, which limit the flow rate through an individual household for even distribution of heating water to other households. The constant-flow type is implemented by an on-off control. As a result, heating water is supplied intermittently and hence, indoor air temperature also fluctuates. Returning water temperature is also high, which reduces energy efficiency. To implement continuous feedback control, the indoor temperature dynamics was simulated to fit a measured temperature history by a state-of-the-art physical model. From the model, it was found that the most important disturbance is outdoor temperature and its effect on indoor temperature lasts about an hour. To cope with the slow response and the significant disturbance, a prediction control with proportional feedback is proposed. The control was found to be successful in implementing continuous heating water flow and improved indoor temperature control.

수학적 정량평가모델을 이용한 Listeria monocytogenes의 성장 예측모델의 개발 (Development of Predictive Growth Model of Listeria monocytogenes Using Mathematical Quantitative Assessment Model)

  • 문성양;우건조;신일식
    • 한국식품과학회지
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    • 제37권2호
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    • pp.194-198
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    • 2005
  • 게맛살의 HACCP system에 있어서 critical control point중의 하나인 L. monocytogenes가 오염된 제품에서 균의 성장변화를 정량적으로 예측할 수 있는 수학적 모델의 개발을 위한 기초 자료를 제공하고자 게맛살 성분조성을 고려한 modified imitation crab(MIC) broth에서 온도와 초기균수에 따른 L. monocytogenes의 성장 실험 결과를 데이터베이스화하여 이를 바탕으로 균의 성장을 정량적으로 평가할 수 있는 수학적 모델을 개발하였다. 균의 증식 지표인 최대증식속도상수(k), 유도기(LT), 세대시간(GT)은 온도에 지배적인 영향을 받았으며, 초기균수에 따른 유의적인 차이는 없었다(p>0.05). 최대증식속도상수(k)와 온도 및 초기균수의 상관관계를 나타내는 수학적 정량평가모델인 polynomial model과 square root model을 이용하여 L. monocytogenes 성장을 정량적으로 예측할 수 있는 모델인 $polynomial\;mode(k=0.71{\cdot}exp(-0.5(\;((T-36.05)/11.84)^{2}+((A_{0}+8.12)/21.59)^{2})))$과 square root model($\sqrt{k}$ =0.02(T-(-3.42)) [1-exp(0.36(T-44.51))])을 개발하였으며 실험치와 예측치의 상관관계는 각각 0.92. 0.95로 polynomial model보다 square root model 예측치가 실험치와 상관관계가 더 높은 것으로 나타났다.

혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발 (The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion)

  • 전석준
    • 한국물환경학회지
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    • 제18권4호
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

동적신경망을 이용한 이암풍화토의 전단거동예측 (A Prediction of Shear Behavior of the Weathered Mudstone Soil Using Dynamic Neural Network)

  • 김영수;정성관;김기영;김병탁;이상웅;정대웅
    • 한국지반공학회논문집
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    • 제18권5호
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    • pp.123-132
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    • 2002
  • 본 연구에서는 인간의 사고과정을 근거로 개발된 동적 인공신경망을 이용하여 이암풍화토의 전단거동을 예측하였다. 흙의 비선형거동을 예측함에 있어 피드백 과정에 의해 시간경과에 따른 패턴의 특성변화를 연속적으로 예측할 수 있는 동적신경망의 종류인 SNN모델과 RNN모델을 이용하였다. 인공신경망의 학습능력과 예측능력에 영향을 미치는 여러 변수등을 분석후 SNN모델에서는 학습율, 모멘텀 상수, 신경망구조가 0.5, 0.7, 8$\times$18$\times$2, RNN모델인 경우는 각각 0.3,0.9,8$\times$24$\times$2의 구조가 적합한 것으로 나타났다 예측결과는 두 네트워크 모두 정규압밀 상태의 전단거동을 잘 예측하였지만, 과압밀 상태의 전단거동 예측에서는 불규칙적인 입력패턴에 효과적인 RNN모델의 예측능력이 더욱 우수하였다.

망간과 휴믹산에 의한 세라믹 막 오염의 제어를 위한 약품 스팀세정의 적용 (Chemically enhanced steam cleaning for the control of ceramic membrane fouling caused by manganese and humic acid)

  • 안선아;박철규;이진산;김한승
    • 상하수도학회지
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    • 제35권6호
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    • pp.425-436
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    • 2021
  • In this study, chemically enhanced steam cleaning(CESC) was applied as a novel and efficient method for the control of organic and inorganic fouling in ceramic membrane filtration. The constant filtration regression model and the resistance in series model(RISM) were used to investigate the membrane fouling mechanisms. For total filtration, the coefficient of determination(R2) with an approximate value of 1 was obtained in the intermediate blocking model which is considered as the dominant contamination mechanism. In addition, most of the coefficient values showed similar values and this means that the complex fouling was formed during the filtration period. In the RISM, R c/R f increased about 4.37 times in chemically enhanced steam cleaning compared to physical backwashing, which implies that the internal fouling resistance was converted to cake layer resistance, so that the membrane fouling hardly to be removed by physical backwashing could be efficiently removed by chemically enhanced steam cleaning. The results of flux recovery rate showed that high-temperature steam may loosen the structure of the membrane cake layer due to the increase in diffusivity and solubility of chemicals and finally enhance the cleaning effect. As a consequence, it is expected that chemically enhanced steam cleaning can drastically improve the efficiency of membrane filtration process when the characteristics of the foulant are identified.

ETAMs 용액내에서 p-Nitrophenylvalate의 가수분해반응에 미치는 o-Iodosobenzoate Ion의 촉매효과 (The Catalytic Effects of o-Iodosobenzoate Ion on Hydrolysis of p-Nitrophenylvalate in ETAMs Solution)

  • 김정배
    • 한국환경과학회지
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    • 제20권1호
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    • pp.119-126
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    • 2011
  • In this study, reaction model and reactions rate accelerated by o-iodosobenzoate ion(IB$^{\ominus}$) on hydrolysis reaction of p-nitrophenyl valate(NPV) using ethyl tri-octyl ammonium mesylate(ETAMs) for quaternary ammonium salts, the phase transfer catalysis(PTC) reagent, were investigated. The effect of IB$^{\ominus}$ on hydrolysis reaction rate constant of NPV was weak without ETAMs solutions. Otherwise, in ETAMs solutions, the hydrolysis reactions exhibit higher first order kinetics with respect to the nucleophile, IB$^{\ominus}$, and ETAMs, suggesting that reactions are occurring in small aggregates of the three species including the substrate(NPV), whereas the reaction of NPV with OH$^{\ominus}$ is not catalyzed by ETAMs. Different concentrations of NPV were tested to measure the change of rate constants to investigate the effect of NPV as substrate and the results showed that the effect was weak. This means the reaction would be the first order kinetics with respect to the nucleophile. This behavior for the drastic rate-enhancement of the hydrolysis is referred as 'Aggregation complex model' for reaction of hydrophobic organic ester with o-iodosobenzoate ion(IB$^{\ominus}$) in hydrophobic quarternary ammonium salt(ETAMs) solutions.