• 한국지반공학회지:지반
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• 제12권2호
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• pp.85-94
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• 1996

말뚝직경이 개단말뚝의 폐색정도와 지지력에 미치는 영향을 규명하기 위하여 응력상태와 상대밀도의 조절이 가능한 토조와 직경이 다른 세개의 모형말뚝을 이용하여 모형말뚝실험을 수행하였다. 모형말뚝은 말뚝의 지지력 성분을 분리측정하기 위하여 직경이 다른 두개의 파이프로 만들어졌다. 실험결과에 의하면 말뚝이 완전폐색 상태로 되는 관입깊이는 말뚝직경과 지반의 상대밀도가 증가할수록 커지는 것을 알 수 있었으며, 관입비와 관내토 증분비가 동일하더라도 단위 관내토 지지력은 말뚝의 직경이 커질수록 감소하는 경향을 보였다. 그러나 기존의 지지력 산정식은 말뚝의 관입비나 폐색정도가 동일한 상태에 대하여 관내토 지지력은 말뚝의 직영에 관계없이 일정하거나 직경이 증가할수록 커지는 결과를 주고 있다. 이는 본 연구의 실험결과와 상반되는 것으로서 관내토 지지력의 산정시 말뚝의 폐색정도 뿐만 아니라 크기효과도 고려하는 것이 필요한 것으로 밝혀졌다.

• 폴리머
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• 제26권4호
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• pp.422-430
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• 2002

Antimony trioxide 촉매를 사용하여 241 - $260^{\circ}C$ 범위에서 bishydroxyethyl naphthalate (BHEN)의 축중합 반응에 관한 속도론적 연구를 수행하였다. 반응은 회분식 반응기에서 진행되었고 반응물의 농도는 high performance liquid chromatography (HPLC)를 사용하여 측정하였다. 분자종 모델을 적용하여 구한 반응속도상수의 정반응 및 역반응 활성화 에너지 값은 각각 19.7과 31.4 kcal/mole 이었으며, 평형상수는 1.4-2.0으로 PET 축중합 반응의 경우보다 큰 값을 가지며 온도에 따라 어느 정도 변하였다. 말단기인 hydroxyethyl기의 반응속도는 분자의 크기에 관계없이 일정함을 Flory, 모델식으로부터 확인할 수 있었다. 관능기 모델을 적용한 결과 정반응과 역반응 활성화 에너지 길기 큰 차이가 없었으며, 평형상수는 1.4정도의 값을 가졌다. 관능기 모델로부터 구한 속도상수 값은 분자종 모델로부터 구한 값의 3-4배로서 두 모델이 모두 반응계를 잘 설명하였다. 제안된 분자종 모델이 10개의 분자종을 모두 예측해야 하는 어려움에도 불구하고 실험 결과와 잘 맞음을 알 수 있었다.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2002년도 춘계학술대회 논문집
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• pp.104-109
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• 2002

In this paper, a statistical analysis of fatigue crack growth behavior under constant amplitude loads has been carried out. Fatigue crack growth tests were conducted on sixteen pre-cracked compact tension (CT) specimens of the pressure vessel (SPV50) steel in controlled identical load and environmental conditions. The assessment of the statistical distribution of fatigue crack growth experimental data obtained from SPV50 steel was studied and also the correlation of the parameter C and m in the Paris-Erdogan law was discussed. The probability distribution function of fatigue crack growth life seems to follow the 3-parameter Weibull. The fatigue crack growth rate seems to follow the 3-parameter Weibull and the log-normal distribution. The coefficient of variation (COV) of fatigue crack growth life was observed to decrease as the crack grows. A strong negative linear correlation exists between the coefficient C and the exponent m in Paris model. Fatigue crack growth rate data shows a normal distribution for both m and logC.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2877-2883
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• 2010

The folding kinetics of $WT^*$ ubiquitin variant with valine to alanine mutation at sequence position 26 (HubWA) was studied by stopped-flow fluorescence spectroscopy. While unfolding kinetics showed a single exponential phase, refolding reaction showed three exponential phases. The semi-logarithmic plot of urea concentration vs. rate constant for the first phase showed v-shape pattern while the second phase showed v-shape with roll-over effect at low urea concentration. The rate constant and the amplitude of the third phase were constant throughout the urea concentrations, suggesting that this phase represents parallel process due to the configurational isomerization. Interestingly, the first and second phases appeared to be coupled since the amplitude of the second phase increased at the expense of the amplitude of the first phase in increasing urea concentrations. This observation together with the roll-over effect in the second folding phase indicates the presence of intermediate state during the folding reaction of HubWA. Quantitative analysis of Hub-WA folding kinetics indicated that this intermediate state is on the folding pathway. Folding kinetics measurement of a mutant HubWA with hydrophobic core residue mutation, Val to Ala at residue position 17, suggested that the intermediate state has significant amount of native interactions, supporting the interpretation that the intermediate is on the folding pathway. It is considered that HubWA is a useful model protein to study the contribution of residues to protein folding process using folding kinetics measurements in conjunction with protein engineering.

• 터널과지하공간
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• 제13권2호
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• pp.100-107
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• 2003

본 암석에 외력을 가하면 내부 응력이 발생하고, 이로 인해 변형이 발생하게 된다. 암석재료에서 크리프 변형이 장기간 지속되어 어느 한계에 도달하면 급작스런 파괴로 이어진다. 따라서 구조물의 장기적 안정성 검토 시에 지반의 크리프 특성 파악이 필수적이라 할 수 있다. 본 논문에서는 일축압축강도의 40% 50%, 60%, 70%에 해당하는 하중을 가하여 변형률을 측정하였다. 크리프 특성을 비교 . 분석한 결과로써 변형률 속도의 경우 하중 이 증가함에 따라 변형률 속도 상수$\alpha$ , ${\gamma}$ 도 증가하는 경향이 나타났다. 크리프 곡선에서 Griggs가 제안한 식이 Li와Xia, Singh식 보다 적합하였으며, Burger's model을 적용하여 구한상수 G$_2$는 응력수준의 증가에 파라 감소하며, η$_1$,η$_2$, G$_1$의 경우 불규칙하게 나타났다.

• 한국통신학회논문지
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• 제32권2A호
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• pp.195-202
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• 2007

A differential space-frequency block code - orthogonal frequency division multiplexing (SFBC-OFDM) scheme as a multiple-input multiple-output (MIMO) transmission technique for next-generation digital multimedia broadcasting (DMB) is proposed in this paper. A linear decoding method for differential SFBC, which performs comparably to the ML decoding method, is derived for the cases of two or four transmit antennas. A simple table lookup method is proposed to improve the efficiency of the encoding/decoding process of DSFBC for the case of non-constant modulus constellations. A DMB MIMO channel model, developed by extending the 3GPP MIMO model to fit DMB environments, is used to compare BER performances of differential space block code schemes for various channel environments. Simulation results show that the differential SFBC-16QAM scheme using either four transmit antennas with one receive antenna or two transmit antennas with two receive antennas achieves a performance gain of 12dB than that of the conventional DQPSK scheme, even with a data rate twice faster.

• 한국정밀공학회지
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• 제15권10호
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• pp.113-119
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• 1998

Ship structures and aircraft structures are consisted of thin sheet alloy, so it is very important to understand the characteristics of fatigue crack propagation of that material and to establish the data base. The data for fatigue crack propagation behavior scatter very much even under identical experimental conditions with constant loading. The behavior of fatigue crack propagation under regular and irregular cyclic loadings is known to be highly affected by complicated factors such as plastic zone developed at the vicinity of crack tip and reduction of cross sectional area. In this paper, the controlled stress amplitude and overload fatigue crack propagation tests have been conducted to investigate the effect of varying factors such as plastic zone size near the crack tip and area reduction factor (AF) on the fatigue crack propagation behavior A better simulation of fatigue crack propagation behavior is found to be obtainable by using Wheeler and Willenborg models with AF effect.

• Macromolecular Research
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• 제9권3호
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• pp.164-170
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• 2001

Recently in order to describe the complex rheological behavior of polymer melts with long side branches like low density polyethylene, new constitutive equations called the pom-pom equations have been derived by McLeish and Larson on the basis of the reptation dynamics with simplified branch structure taken into account. In this study mathematical stability analysis under short and high frequency wave disturbances has been performed for the simplified differential version of these constitutive equations. It is proved that they are globally Hadamard stable except for the case of maximum constant backbone stretch (λ = q) with arm withdrawal s$\_$c/ neglected, as long as the orientation tensor remains positive definite or the smooth strain history in the now is previously given. However this model is dissipative unstable, since the steady shear How curves exhibit non-monotonic dependence on shear rate. This type of instability corresponds to the nonlinear instability in simple shear flow under finite amplitude disturbances. Additionally in the flow regime of creep shear flow where the applied constant shear stress exceeds the maximum achievable value in the steady now curves, the constitutive equations will possibly violate the positive definiteness of the orientation tensor and thus become Hadamard unstable.

• Bulletin of the Korean Chemical Society
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• 제19권2호
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• pp.218-222
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• 1998

Removal of Cd(Ⅱ), Zn(Ⅱ) and Cu(Ⅱ) from aqueous solutions using the adsorption process on magadiite has been investigated. It was found that the removal percentage of metal cations at equilibrium increases with increasing temperature, and follows the order of Cd(Ⅱ) > Cu(Ⅱ) > Zn(Ⅱ). Equilibrium modeling of adsorption showed that the adsorptions of Cd(Ⅱ), Cu(Ⅱ), and Zn(Ⅱ) were fitted to Langmuir isotherm. Kinetic modeling of the adsorption showed that first order reversible kinetic model fitted to experimental data. From kinetic model and equilibrium data, the overall rate constant (k) and the equilibrium constant (K) for the adsorption process were calculated. The overall rates of adsorption of metal ions follow the order of Cd(Ⅱ) > Cu(Ⅱ) > Zn(Ⅱ). From the results of thermodynamic analysis, standard Gibbs free energy (ΔG°), standard enthalpy (ΔH°), and standard entropy (ΔS°) of adsorption process were calculated.

• The Plant Pathology Journal
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• 제33권2호
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• pp.206-211
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• 2017

The effect of temperature on the rate of systemic infection of potatoes (Solanum tuberosum L. cv. Chu-Baek) by Potato virus Y (PVY) was studied in growth chambers. Systemic infection of PVY was observed only within the temperature range of $16^{\circ}C$ to $32^{\circ}C$. Within this temperature range, the time required for a plant to become infected systemically decreased from 14 days at $20^{\circ}C$ to 5.7 days at $28^{\circ}C$. The estimated lower thermal threshold was $15.6^{\circ}C$ and the thermal constant was 65.6 degree days. A systemic infection model was constructed based on experimental data, using the infection rate (Lactin-2 model) and the infection distribution (three-parameter Weibull function) models, which accurately described the completion rate curves to systemic infection and the cumulative distributions obtained in the PVY-potato system, respectively. Therefore, this model was useful to predict the progress of systemic infections by PVY in potato plants, and to construct the epidemic models.