• Journal of environmental and Sanitary engineering
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• v.14 no.2
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• pp.113-119
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• 1999

In this study, the incineration of MEK and toluene was studied on a Pt supported alumina catalyst at temperature range from 200 to $350^{\circ}C$. An approach based on the Mars-van Krevelen rate model was used to explain the results. The object of this study was to study the kinetic behavior of the platinum catalyst for deep oxidation. The conversions of MEK and toluene were increased as the inlet concentration was decreased and the reaction temperature was increased. The maximum deep conversion of MEK and toluene were 91.81% and 55.69% at $350^{\circ}C$, respectively. The ${\kappa}_3$ constant increases with temperature faster than the ${\kappa}_1$ constant, that is, the surface concentration of ($VOCs{\cdots}O$) is higher than that of (O) at higher temperature according to the Mars-van Krevelen mechanism. Also the activation energy of toluene was larger than MEK for toluene is aromatic compound which have stronger bonding energy.Therefore, the catalytic incineration kinetics of MEK and toluene with Mars-van Krevelen mechanism could be used as the basic data for industrial processes.

• Journal of Mechanical Science and Technology
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• v.20 no.8
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• pp.1209-1216
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• 2006

An AZ31 magnesium alloy was tested at constant temperatures ranging from 423 to 473 K (0.46 to 0.51 Tm) under constant stresses. All of the creep curves exhibited two types depending on stress levels. At low stress (${\sigma}/ G < 4 {\times}10^{-3}$), the creep curve was typical of class A (Alloy type) behavior. However, at high stresses (${\sigma}/ G > 4 {\times}10^{-3}$), the creep curve was typical of class M (Metal type) behavior. At low stress level, the stress exponent for the steady-state creep rate was of 3.5 and the true activation energy for creep was 101 kJ/mole which is close to that for solute diffusion. It indicates that the dominant deformation mechanism was glide-controlled dislocation creep. At low stress level where n=3.5, the present results are in good agreement with the prediction of Fridel model.

• Journal of the Korean Institute of Navigation
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• v.4 no.1
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• pp.51-61
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• 1980

In order to evaluate rolling characteristics of high speed container carrier the author developed yaw-sway-rudder coupled rool equation, which is likely to be 5th order differential equation. The free rolling time history with particular reference to automatic steering, was computed upon the base of the yaw-sway-rudder coupled roll equation. The computed result explained effects of $C_1$ and $C_2$ on rolling behaviors and furthermore the effect of $C_2$ proved to be very effective where $C_1$ and $C_2$ are yaw gin constant and yaw-rate gain constant of auto-pilot respectively. Computation was carried out using Matsumoto's data of hydrodynamic force derivatives of 5 meter long container model.

• Solar Energy
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• v.19 no.3
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• pp.53-61
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• 1999

We already presented new calculation method about the temperature distribution in hot water pipe flow of the unsteady condition. In this paper, we introduce consequence of the case study to confirm appropriation of the calculation method, and case study performs to establish actual hot water use supposed two model that is; the CWV(constant water volume) and VWV(variable water volume).

• Bulletin of the Korean Chemical Society
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• v.3 no.3
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• pp.115-119
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• 1982

The photoreaction of maleimide, one of the best model compounds of DNA molecules for psoralen-DNA photoreactions, is studied in order to investigate the photoreactivity and the mechanism of the maleimide-psoralen photoreaction. The (2+2) photocyclodimer of maleimide was obtained in solution state by direct or sensitized irradiation. The rate constant of dimerization is determined by quenching studies and found to be of the order of $10^9 M^{-1}sec^{-1}$. The direct dimerization of maleimide is found to undergo through the triplet excited state. The quantum yields of dimerization are dependent on the maleimide concentration.

• Biotechnology and Bioprocess Engineering:BBE
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• v.7 no.4
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• pp.225-230
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• 2002

Experiments on deactivation kinetics of immobilized lipase enzyme from Candida cyl-indracea were performed in stirred bath reactor using rice bran oil as the substrate and temperature as the deactivation parameter. The data were fitted In first order deactivation model. The effect of temperature on deactivation rate was represented by Arrhenius equation. Theoretical equations were developed based on pseudo-steady state approximation and Michaelis -Menten rate expression to predict the time course of conversion due to enzyme deactivation and apparent half-life of the immobilized enzyme activity in PFR and CSTH under constant feed rate polity for no diffusion limitation and diffusion limitation of first order. Stability of enzyme in these continuous reactors was predicted and factors affecting the stability were analyzed.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.506-511
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• 2007

Mechanical behavior of copper nanowire is investigated. An FCC nanowire model composed of 1,408 atoms is used for MD simulation. Simulations are performed within NVT ensemble setting without periodic boundary conditions. $Nos\acute{e}-Poincar\acute{e}$ MD algorithm is employed to guarantee preservation of Hamiltonian and temperature. Numerical tensile tests of Nanowire are carried out with constant strain rate. Additionally, temperature and strain rate effects are considered. Stress-strain curve is constructed from the calculated Cauchy stresses and specified strain values. In (22,4,4) Copper nanowire, non-linear behavior appears around ${\epsilon}\simeq0.09.$ At this instance, starting of structural reorientations are observed. At the onset of reorientation, the modulus characteristics are also investigated.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2009.01a
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• pp.413-417
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• 2009

The use of scalable video coding scheme has been regarded as a promising solution for guaranteeing the quality of service of the video streaming over the Internet because it is a capable coding scheme to perform quality adaptation depending on network conditions. In this paper, we use a streaming model that transmits base layer using TCP and enhancement layers using DCCP, which try to provide transmission reliability of the BL and TCP friendliness. Unlike pervious works, the proposed algorithm performs rate adaptation based on playout buffer status. The PoB status of the client is sent back periodically to the server and serves as a network congestion indicator. Experimental results show that our scheme improves streaming quality comparing with pervious scheme in the case of not only constant/dynamic background flows but also VBR-encoded video sequence.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.145-148
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• 2003

The batch experiments showed that 0.515mM 4-chlorophenol and its oxidation intermediates could be totally decomposed within 60 minutes by 1g/L steelers' dust and 0.485mM hydrogen peroxide at pH 2.7. The rate constants in the simplified kinetic model proposed in this study were estimated by fitting to the experimental data obtained in $H_2O$$_2$/steelers' dust system. Using the estimated kinetic rate constants, the simulation of 4-chlorophenol, ferrous iron, hydrogen peroxide, and hydroxyl radical concentration was performed. The predicted concentrations of 4-chlorophenol and hydrogen peroxide corresponded to the actual concentrations.

• 유체기계공업학회:학술대회논문집
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• 1999.12a
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• pp.46-51
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• 1999

This paper describes the control charcteristics of thermal/flow systems. In thermal/flow systems, the transport lag plays as a dead time causing a deterioration of the controllability. Besides this, such many parameters including the temperature, pressure, and flow rate affect the system response that a control scheme which can deal with multi-input is required. Particularly in a refrigerant compressor test facility, the evaporator and condenser interact each other so that the change in the evaporator pressure cause the condenser pressure to change or vice versa. Therefore, to control the evaporator pressure, not only the cooling water flow rate in the evaporator but also the coolant flow rate in the condenser is considered. Meanwhile, the conventional PID controllers, which is suitable for a single input system, shows a large overshoot for a disturbance input. In this work, the predictive control scheme is introduced and its applicability is discussed for thermal/flow systems.