• 제목/요약/키워드: Constant Surface Area

검색결과 364건 처리시간 0.027초

Silver Loading Effect for the Activated Carbon Fibers Pre-treated with Acid

  • Oh, Won-Chun;Yum, Min-Hyung
    • Bulletin of the Korean Chemical Society
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    • 제25권8호
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    • pp.1189-1194
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    • 2004
  • The adsorption isotherms of N2 onto the metallic silver treated activated carbon fiber samples after acid treatment are Type I with a small amount of capillary condensation hysteresis. Increasing amount of acid treatment leads to a decrease in SBETs and external surface area. But, micropore volume and average pore diameter are presented in constant regular values with increasing amount of sulfuric acid treatment. SEM observes the surface morphology and crystal grown state of metal on the fiber surface. The results of EDX of Ag-activated carbon fiber pre-treated with acid show the spectra corresponding to almost all samples rich in silver with increasing the amount of acid treated. The FT-IR spectra of Ag-activated carbon fiber show that the acid pre-treatment is consequently associated with the homogeneous dispersion of metal with the increased surface acidity of the activated carbon fiber. The type and quality of oxygen groups are determined with Boehm titration method. From the those results, a positive influence of the acidic groups on the carbon fiber surface by acid treatment is also demonstrated by an increase in the contents of metallic silver with increasing of acidic groups.

시편의 준비 방법 및 접촉저항이 알루미늄 합금의 아노다이징 피막 형성에 미치는 영향 (Effects of Specimen Preparation Method and Contact Resistance on the Formation of Anodizing Films on Aluminum Alloys)

  • 문성모
    • 한국표면공학회지
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    • 제53권1호
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    • pp.29-35
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    • 2020
  • In this study, five different specimen preparation methods were introduced and their advantages and disadvantages were presented. One of them, an epoxy mounting method has advantages of constant exposure area, ease of surface preparation without touching the specimen surface during polishing or cleaning, use of small amount of material and ease of specimen reuse by polishing or etching. However, in order to eliminate unexpected errors resulting from preferable reaction at the specimen/epoxy interface and contact resistance between the specimen and copper conducting line for electrical connection, it is recommended to cover the wall side of the specimen with porous anodic oxide films and to remain the contact resistance lower than 1 ohm. The increased contact resistance between the specimen and Cu conducting line appeared to result in increases of anodizing voltage and solution temperature during anodizing by which thickness and hardness of anodizing film on Al2024 alloy were drastically decreased and color of the films became more brightened.

응축기용 낮은 핀관의 내부 나선 홈에 의한 응축 열전달 성능과 압력손실에 관한 연구 (A Study on the Condensation Heat Transfer and Pressure Drop in Internally Grooved Tubes Used in Condenser)

  • 한규일;조동현
    • 수산해양기술연구
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    • 제34권2호
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    • pp.212-222
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    • 1998
  • Heat transfer performance improvement by fin and groovs is studied for condensation of R-11 on integral-fin tubes. Eight tubes with trapczodially shaped integral-fins having fin density from 748 to 1654fpm(fin per meter) and 10, 30 grooves are tested. A plain tube having the same diameter as the finned tubes is also used for comparison. R-11 condensates at saturation state of 32 $^{\circ}C$ on the outside tube surface coded by inside water flow. All of test data are taken at steady state. The heat transfer loop is used for testing singe long tubes and cooling is pumped from a storage tank through filters and folwmeters to the horizontal test section where it is heated by steam condensing on the outside of the tubes. The pressure drop across the test section is measured by menas pressure gauge and manometer. The results obtained in this study is as follows : 1. Based on inside diameter and nominal inside area, overall heat transfer coefficients of finned tube are enhanced up to 1.6 ~ 3.7 times that of a plain tube at a constant Reynolds number. 2. Friction factors are up to 1.6 ~ 2.1 times those of plain tubes. 3. The constant pumping power ratio for the low integral-fin tubes increase directly with the effective area to the nominal area ratio, and with the effective area diameter ratio. 4. A tube having a fin density of 1299fpm and 30 grooves has the best heat transfer performance.

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Immobilization of Horseradish Peroxidase to Electrochemically Deposited Gold-Nanoparticles on Glassy Carbon Electrode for Determination of H2O2

  • Ryoo, Hyun-woo;Kim, You-sung;Lee, Jung-hyun;Shin, Woon-sup;Myung, No-seung;Hong, Hun-Gi
    • Bulletin of the Korean Chemical Society
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    • 제27권5호
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    • pp.672-678
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    • 2006
  • A new approach to fabricate an enzyme electrode was described based on the immobilization of horseradish peroxidase (HRP) on dithiobis-N-succinimidyl propionate (DTSP) self-assembled monolayer (SAM) formed on gold-nanoparticles (Au-NPs) which were electrochemically deposited onto glassy carbon electrode (GCE) surface. The overall surface area and average size of Au-NPs could be controlled by varying deposition time and were examined by Field Emission-Scanning Electron Microscope (FE-SEM). The $O_2$ reduction capability of the surface demonstrated that Au-NPs were thermodynamically stable enough to stay on GCE surface. The immobilized HRP electrode based on Au-NPs/GCE presented faster, more stable and sensitive amperometric response in the reduction of hydrogen peroxide than a HRP immobilized on DTSP/gold plate electrode not containing Au-NPs. The effects of operating potential, mediator concentration, and pH of buffer electrolyte solution on the performance of the HRP biosensor were investigated. In the optimized experimental conditions, the HRP immobilized GCE incorporating smaller-sized Au-NPs showed higher electrocatalytic activity due to the high surface area to volume ratio of Au-NPs in the biosensor. The HRP electrode showed a linear response to $H_2O_2$ in the concentration range of 1.4 $\mu$M-3.1 mM. The apparent Michaelis-Menten constant ($K _M\; ^{app}$) determined for the immobilized HRP electrodes showed a trend to be decreased by decreasing size of Au-NPs electrodeposited onto GCE.

Patch-based Cortical Source Modeling for EEG/MEG Distributed Source Imaging: A Simulation Study

  • Im Chang-Hwan
    • 대한의용생체공학회:의공학회지
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    • 제27권2호
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    • pp.64-72
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    • 2006
  • The present study introduces a new cortical patch-based source model for EEG/MEG cortical source imaging to consider anatomical constraints more precisely. Conventional source models for EEG/MEG cortical source imaging have used coarse cortical surface mesh or sampled small number of vertices from fine surface mesh, and thus they failed to utilize full anatomical information which nowadays we can get with sub-millimeter modeling accuracy. Conventional ones placed a single dipolar source on each cortical patch and estimated its intensity by means of various inverse algorithms; whereas the suggested cortical patch-based model integrates whole cortical area to construct lead field matrix and estimates current density that is assumed to be constant in each cortical patch. We applied the proposed and conventional models to realistic EEG data and compared the results quantitatively. The quantitative comparisons showed that the proposed model can provide more precise spatial descriptions of neuronal source distribution.

A Deformation Model of a Bag-Finger Skirt and the Motion Response of an ACV in Waves

  • Lee, Gyeong-Joong;Rhee, Key-Pyo
    • Selected Papers of The Society of Naval Architects of Korea
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    • 제2권1호
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    • pp.29-46
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    • 1994
  • In this paper, the effect of a skirt deformation on the responses of an Air Cushion Vehicle in waves is investigated. The air in the bag and plenum chamber is assumed to be compressible and to have a uniform pressure distribution in each volume. The free surface deformation is determined in the framework of a linear potential theory by replacing the cushion pressure with the pressure patch which is oscillating and translating uniformly. And the bag-finger skirt assumed to be deformed due to the pressure disturbance while its surface area remained constant. The restoring force and moment due to the deformation of bag-finger skirt from equilibrium shape is incorporated with the equations of heave and pitch motions. The numerical results of motion responses due to various ratios of the bag and cushion pressure or bag-to-finger depth ratios are shown.

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마이크로볼로미터 소자설계에 따른 적외선 검출특성 (Infrared Response Characterization on the Microbolometer Device Design)

  • 한명수;안수창;강태영;임성수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.343-344
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    • 2008
  • A surface micromachined uncooled microbolometer based on the amorphous silicon was designed, fabricated, and characterized. We designed the microbolometer with a pixel size of $44\times44{\mu}m^2$ and a fill factor of about 50 % ~ 70% by considering such important factors as the thermal conductance, thermal time constant, the temperature coefficient of resistance, and device resistance. Also, we successfully fabricated the microbolometer by using surface MEMS technology. Finally, we investigated responsivity and detectivity properties depends on the active area size.

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구간해석방법을 통한 새로운 비구형 입자성장해석 모델 (A New Model for the Analysis of Non-spherical Particle Growth Using the Sectional Method)

  • 정재인;최만수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집B
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    • pp.416-421
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    • 2000
  • We have developed a simple model for describing the non-spherical particle growth phenomena using modified 1-dimensional sectional method. In this model, we solve simultaneously particle volume and surface area conservation sectional equations which consider particles' irregularities. From the correlation between two conserved properties of sections, we can predict the evolution of the aggregates' morphology. We compared this model with a simple monodisperse-assumed model and more rigorous two dimensional sectional model. For the comparison, we simulated silica and titania particle formation and growth in a constant temperature reactor environment. This new model shows a good agreement with the detailed two dimensional sectional model in total number concentration, primary particle size. The present model can also successfully predict particle size distribution and morphology without costing very heavy computation load and memory needed for the analysis of two dimensional aerosol dynamics.

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Al:ZnO의 펄스 스퍼터 증착에서 주파수에 따른 플라즈마의 특성과 기판 온도 변화 (Plasma Characteristics and Substrate Temperature Change in Al:ZnO Pulse Sputter Deposition: Effects of Frequency)

  • 양원균;주정훈
    • 한국표면공학회지
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    • 제40권5호
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    • pp.209-213
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    • 2007
  • Change of the plasma volume by pulse frequency in a bipolar pulsed DC unbalanced magnetron sputtering was investigated. As increasing the frequency at off duty 10% and at a constant power, the plasma volume was lengthened in vertical direction from the AZO target. When there is an electrically floated substrate, the vertical length of the plasma area was not affected by the pulse frequency. Instead, the diameter of the plasma volume was increased. We found that the temperature rise of a substrate was affected by the pulse frequency, too. As increasing it, the maximum temperature rise of a glass substrate was decreased from $132^{\circ}C\;to\;108^{\circ}C$.

새로운 비구형 입자 성장 해석 모델 (A New Model for the Analysis of Non-Spherical Particle Growth)

  • 정재인;최만수
    • 대한기계학회논문집B
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    • 제24권7호
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    • pp.1020-1027
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    • 2000
  • A simple model for describing the non-spherical particle growth phenomena has been developed. In this model, we solve simultaneously particle volume and surface area conservation sectional equations that consider particles' non-sphericity. From the correlation between two conserved properties of sections, we can predict the evolution of the aggregates' morphology. This model was compared with a simple monodisperse-assumed model and more rigorous two-dimensional sectional model. For comparison, formation and growth of silica particles have been simulated in a constant temperature reactor environment. This new model showed good agreement with the detailed two-dimensional sectional model in total number concentration and primary particle size. The present model successfully predicted particle size distribution and morphology without costing very heavy computation load and memory needed for the analysis of two dimensional aerosol dynamics.