• Journal of Korean Society of Water and Wastewater
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• v.35 no.2
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• pp.135-142
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• 2021

The activity of anaerobic ammonium oxidation (ANAMMOX) immobilized in synthetic media (Poly Ethylene Glycol, PEG) and granular form was evaluated comparatively to investigate the effect of influent nitrogen concentration and exposure of oxygen. In ANAMMOX granule reactor, when concentration of influent total nitrogen increased to 500mg/L, removal efficiency of ammonium, nitrite and nitrate were shown to 90.5±6.5, 96.6±4.9, and 93.2±6.1%, respectively. In the case of the PEG gel, it showed lower nitrogen removal performance, resulting in that the removal efficiency of ammonium, nitrite and nitrate were shown to 83.3±13.0, 96.4±6.1, and 90.3±7.5%, respectively. In second step, when exposed to oxygen, the nitrogen removal performance in the ANAMMOX granule reactor also remained stable, but the activity of PEG gel ANAMMOX was found to be inhibited. Consequently, the PEG gel ANAMMOX was a higher sensitivity than that of granular ANAMMOX with two variables applied in this study.

• Journal of the Mineralogical Society of Korea
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• v.32 no.4
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• pp.287-301
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• 2019

Preservation of the original form is the principle for conservation, management and utilization of cultural heritages. Thus, non-destructive analysis of these samples are important field of the conservation science. In this study, examined the applicability of nondestructive surface X-ray diffraction analysis (ND-XRD) for cultural heritage by materials (rock specimen, jade stone, pigment painted specimen, earthen artifact, metal artifact). In result, all type of sample is recorded suitable X-ray diffraction patterns for identifying mineral composition in case of surface condition with adequate particle size and arrangement. And diffraction pattern is reflected surface information than matrix. Therefore, ND-XRD is thought to be applicable not only mineral identification but also interpretation of manufacturing technique and alteration trend about layered sample (in horizontally or vertically). Whereas some exceptional diffraction patterns were recorded due to overlapping information on specific crystal planes. It caused by skip the sample treatment (powdering and randomly orientation). It could be advantageously used for mineral identification, such as preferred orientation of clay minerals. In contrast, irregular diffraction pattern caused by single crystalline effect is required careful evaluation.

• Journal of Conservation Science
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• v.27 no.4
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• pp.345-356
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• 2011

To remove metal stains of the ceramics, chemical cleaning is essential case by case. This study investigated the removal characteristics of iron stains by oxalic acid and citric acid including their application methods of soaking and poultice. The soaking method in cleaning agents showed removal process by color difference and released iron contents from iron stains on ceramics. Iron stains were removed successfully from ceramics, which soaked in oxalic acid for 60 hours. However, it is recommendable to soak in 0.25M oxalic acid for one to three hours because most iron stains were disappeared in 3 hours soaking. Citric acid is less effective than oxalic acid in removing iron stains because of heavy molecular weight and low acidity. Poultices (bentonite, sepiolite, activated carbon fiber and celite) with oxalic acid were applied on contaminated ceramics. After ten hours, iron stains on ceramics were removed successfully by poultice. Among them, bentonite and sepiolite have better application. Therefore, sepiolite with 0.25M oxalic acid was applied on the iron stains of whiteware and celadon from Ma Island, and then stains were removed. However, it is judged that the application methods can be varied according to the form and depth of contaminant. In addition, the residues of poultice on the ceramics will be considered for preventing contamination.

• Journal of Conservation Science
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• v.33 no.4
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• pp.241-254
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• 2017

The Stone Guardian and Memorial Tablets from the Muryeong Royal Tomb are composed of the same kind of plutonic igneous rocks, the so-called hornblendite. Color of the rocks show greenish gray, and both of them occurred with medium-grained granular texture. The rock-forming minerals composed mainly of amphibole and plagioclase. Magnetic susceptibility of the Stone Guardian is 0.15 to 0.63 (mean $0.42{\times}10^{-3}SI\;unit$), the King's Stone Memorial Tablet is 0.11 to 0.38 (mean $0.24{\times}10^{-3}SI\;unit$) and the Queen's Stone Memorial Tablet ranges from 0.10 to 0.33 (mean $0.18{\times}10^{-3}SI\;unit$). The rocks of the artifacts are hard to find in the Gongju area. Large scaled out crop of hornblendite is not distributed, but found in many places that the form of dike. The lithology and occurrences indicate that the artifacts are made of plutonic rock rather than dike. Reddish brown and pale brown contaminants, are also distributed on the surface of the Stone Guardian and Memorial Tablets. The reddish brown color is due to Fe oxide, and the pale brown color occurs due to the elution of Ca. The reddish brown contaminants are influenced by the internal components of the rock and oxidation of burial iron accessories. In contrast, the pale brown contaminants are considered to have flown from the carbonate materials used in the Royal Tomb, with a little added Fe oxide. Physical and chemical deterioration operate intricately in the Stone Guardian and Memorial Tablets. Physical deterioration is extremely rare and chemical deterioration is stable except for a part of the Stone Guardian and the front of the Queen Stone Memorial Tablet.

• Journal of Conservation Science
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• v.26 no.2
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• pp.149-156
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• 2010

One of resins, V-Flon is useful as a coating material because YK-D80, which is a solvent for V-Flon, is not highly volatile. However, it can not completely harden and can flow out when metal artifacts are joined and restored in the process of the treatment. Therefore, after the impregnation process in order to accelerate the hardening speed of a coating material, usually a dry oven was adopted. This study focused on finding the problems on the dry oven which is employed to increase the speed and investigating the most effective solvent and its composition by checking any change occurred depending on the concentration of solvents. Six different types of solvents were selected and samples were prepared in a manner that they were impregnated with solvents in three concentrations respectively (10%, 20%, 30%). To determine the condition of the samples, the stability evaluation was performed by measuring the change of color and the gloss, the thickness of coated layers, the corrosion after coating, the water resistance by contact angles. Through the comparative experiments between the natural drying and the artificial drying using a dry oven, it was found that when the dry oven is used, some problems are identified on the point of forming a uniform and stable layer because of the unstable data collected from the forced artificial dry. The experiments performed using 3 different concentration rates (10%, 20%, 30%) presented that in the case of 10% V-Flon in Xylene (using as a solvent), its layer was thin as well as it showed the high water-barrier property, which allows it to form the stably coated layer with the lower gloss and color change.

• Journal of Conservation Science
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• v.28 no.4
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• pp.377-385
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• 2012

Anoxic treatments using argon and nitrogen gas in controlled atmospheres have been used as a alternative to methyl bromide for insect disinfection in museums. Anoxic chamber system was manufactured and installed at The National Folk Museum of Korea for the first time in Korea. The internal capacity of anoxic chamber is 0.5m3 in which is able to use argon, nitrogen and carbon dioxide gas. This system is equipped with oxygen concentration, temperature and ralative humidity control devices and automatically controlled oxygen concentration from 0.01 to 20%, temperature from 10 to $50^{\circ}C$ and relative humidity 30 to 80%. To control the oxygen concentration, anoxic chamber system is adopted semi-dynamic method which supplies mixture of humidified gas and dry gas whenever oxygen concentration in chamber becomes higher than setting value. It has kept regularly oxygen concentration, temperature and relative humidity for 20 days using argon gas. To evaluate the disinfection of cigarette beetle larvae and adults and varied carpet beetle larvae, the anoxic chamber system maintained 0.01% of oxygen concentration, $25^{\circ}C$ in temperature and 50% in relative humidity for 30 days. Cigarette beetle larvae were killed in 7 days and adults in 3~5 days. And varied carpet beetle larvae were killed in 3 days. It reaches the conclusion form the evaluation this anoxic chamber system can be used to develop anoxic treatment as an alternative of methyl bromide for insect disinfection of infested cultural properties in museums.

• Conservation Science in Museum
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• v.26
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• pp.119-142
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• 2021

The gilt-bronze-and-silver shoes, excavated from the Tomb of King Muryeong, revealed many defective parts, which constantly raised in-depth re-investigation and reporting. In that point, scientific treatment and analysis were conducted to investigate the manufacturing techniques applied. The conservation treatment was carried out with an emphasis on the restoration of the original form and joining parts. As a result, the upper part of the right shoe and some part of the back heel were joined, confirming the joining method and the number of rivet used for instep bonding. From the component analysis, it is presumed that the outer plate was gilded with mercury amalgam on pure copper, and pure silver was used for the inner plate. The main pattern of the gilt-bronze-and-silver shoes includes designs of phoenix, lotus, and six-petal flower, while the lotus pattern is high in terms of ratio. Thus, youngnaksa(twisted gilt-bronze thread), geumdongsa(gilt-bronze thread), wondujeong (rivet), and samyeonjeong(quadrangular cleats) were used for bonding each plate. Twisted gilt-bronze thread was used to join the inner and outer plates, while the center and rear of the inner plate were combined with only gilt-bronze threads. From the fact, it is presumed that the joining method was different whether the function was decoration or just bonding. Regarding the manufacturing process, traces of burnishing were confirmed on the outer surface of the gilt-bronze and silver shoes, but no burnishing traces were identified on the inner surface of the silver plate, which is likely to prove more importance put on the finishing of the outer plates rather than that of the inner.

• Conservation Science in Museum
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• v.27
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• pp.1-22
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• 2022

A chimi(a roof ridge decoration) excavated from the Busosan Temple Site in Buyeo was restored in 1978 at the Buyeo Museum. The gypsum restoration material had deteriorated over time and part of it was seriously damaged and unable to bear the weight of the chimi. The chimi features traces of emergency treatment revealing that the inside of the body and some portions of the tail were reinforced several times using epoxy resin. A condition survey performed in preparation for its transfer for an exhibition found the lower body and wings of the chimi to be highly vulnerable and it was determined that the chimi needed further restoration. The dismantling of the chimi for restoration revealed several elements that provide clues to the production techniques applied by its makers, so they were subjected to inspection. This study explores the production techniques used in the chimi from the Busosan Temple Site that were revealed during the process of dismantling it for restoration. The chimi was inspected using 3D scanning and its rigid vertical shape was restored to a natural form based on the production techniques identified during the dismantling process. The existing restoration material was replaced to improve durability. 3D printed elements were produced based on 3D modelling and were joined to the original chimi to correct its shape and fill in the missing parts, restoring the chimi to its original appearance.

• Korean Journal of Heritage: History & Science
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• v.54 no.1
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• pp.52-69
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• 2021

The transcriptions of Buddhist sutra in the Goryeo Dynasty are more elaborate and splendid than those of any other period and occupy a very important position in Korean bibliography. Among them, the transcriptions made on indigo paper show decorative features that represent the dignity and quality that nobles would have preferred. Particularly, during the Goryeo Dynasty, a large number of transcriptions were made on indigo paper, often in hand-scrolled and folded forms. If flexibility was not guaranteed, the hand-scrolled form caused inconvenience and damage when handling the transcription because of the structural limitations of the material that is rolled up and opened. It was possible to overcome these shortcomings by changing from the hand-scrolled to the folded form to obtain convenience and structural stability. The folded form of the transcription utilizes the same principle as the folding screen, so it is a structure that can be folded and unfolded, and it is made by connecting parts at regularly spaced intervals. No matter how small the transcription is, if it is made of thin paper, it is difficult to handle it and to maintain its shape and structure. For this reason, the folded transcription was usually made of thick paper to support the structure, and the cover was made thicker than the inner part to protect the contents. In other words, the forded form was generally manufactured to suit the characteristics of maintaining strength by making the paper thick. Because a large amount of indigo paper was needed to make this type of transcription, it is assumed that there were craftsmen who were in charge only of dark dyeing the papers. Usually, paper dyeing requires much more dye than silk dyeing, and dyeing dozens of times would be required to obtain the deep indigo color of the base of the transcription of Buddhist sutra in the Goryeo Dynasty. Unfortunately, there is no record of the Goryeo Dynasty's indigo blue paper manufacturing technique, and the craftsmen who made indigo paper no longer remain, so no one knows the exact method of making indigo paper. Recently, Hanji artisans, natural dyers, and conservators attempted to restore the Goryeo Dynasty's indigo paper, but the texture and deep colors found in the relics could not be reproduced. This study introduces the process of restoring indigo paper in the Goryeo Dynasty through collaboration between dyeing artisans, Hanji artisans, and conservators for conservation of the transcription of Buddhist sutra in the late Goryeo dynasty, yielding a suggested method of making indigo paper.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.14 no.6
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• pp.57-69
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• 2011

The present paper deals with a research of life form and vegetation of the plants extant in the habitat of endangered Parnassius bremeri in Uiseong, Gyeongsangbuk-do with a view to restore their habitat and create substitute habitats. The research found that there are a total of 130 vascular plants including 47 families, 96 genera, 113 species, 1 subspecies and 16 varieties. In terms of their life form, hemicryptophytes (H) is the majority of dormancy form with 41 species or 31.54%, while $R_5$ is majority of radicoid form with 72 species or 55.38%, gravitational disseminule form ($D_4$) is majority among the disseminule forms with 68 species or 52.31% and erect type (e) is majority of growth form with 57 species or 43.85%. Major constituents of the habitat are Sedum kamtschaticum, Selaginella tamariscina, Orostachys japonica, Arundinella hirta, Cymbopogon tortilis var. goeringii, Themeda triandra var. japonica, Carex humilis, Indigofera kirilowii, Imperata cylindrica var. koenigii, Festuca ovina, Artemisia capillaris, etc., all of species which are in the initial stage of succession and show simultaneously features characteristic of vegetation on the rock. In the habitat 1. Sedum kamtschaticum- Selaginella tamariscina community and Pinus densiflora community are distributed whereas, in the habitat 2. Sedum kamtschaticum-Selaginella tamariscina community, Sedum kamtschaticum-Carex humilis community, Sedum kamtschaticum-Cymbopogon tortilis var. goeringii community and Sedum kamtschaticum-Imperata cylindrica var. koenigii community are growing and in the habitat 3. Sedum kamtschaticum-Selaginella tamariscina community, Selaginella tamariscina community, Sedum kamtschaticum-Indigofera kirilowii community and Quercus acutissima community are seen distributed there, too. Typical of food plants growing in the habitat is Sedum kamtschaticum, found mostly in the rocky area and its surroundings. Absorption plants are those that usually bloom in the season when imagoes emerge. From the research, it becomes evident that the blooming season of Sedum kamtschaticum, obviously a food plant, corresponds exactly to the emergence timing of imagoes. Cirsium japonicum var. ussuriense, Rosa multiflora, Erigeron annuus, Spiraea prunifolia var. simpliciflora are found to belong to these plants.