• Title/Summary/Keyword: Condensate water

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Dependence of Na+ leakage on intrinsic properties of cation exchange resin in simulated secondary environment for nuclear power plants

  • Hyun Kyoung Ahn;Chi Hyun An;Byung Gi Park;In Hyoung Rhee
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.640-647
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    • 2023
  • Material corrosion in nuclear power plant (NPP) is not controlled only by amine injection but also by ion exchange (IX) which is the best option to remove trace Na+. This study was conducted to understand the Na+ leakage characteristics of IX beds packed with ethanolamine-form (ETAH-form) and hydrogen-form (H-form) resins in the simulated water-steam cycle in terms of intrinsic behaviors of four kinds of cation-exchange resins through ASTM test and Vanselow mass action modeling. Na+ was inappreciably escaped throughout the channel created in resin layer. Na+ leakage from IX bed was non-linearly raised because of its decreasing selectivity with increasing Na+ capture and with increasing the fraction of ETAH-form resin. Na+ did not reach the breakthrough earlier than ETAH+ and NH4+ due to the increased selectivity of Na+ to the cation-exchange resin (H+ < ETAH+ < NH4+ ≪ Na+) at the feed composition. Na+ leakage from the resin bed filled with small particles was decreased due to the enhanced dynamic IX processes, regardless of its low selectivity. Thus, the particle size is a predominant factor among intrinsic properties of IX resin to reduce Na+ leakage from the condensate polishing plant (CPP) in NPPs.

Field Case Study for the Productivity Analysis of B2 Reservoir, Donghae-1 Gas Field (동해-1 가스전 B2 저류층의 생산성 분석에 관한 Field Case Study)

  • Kwon Sun-Il;Ryou Sangsoo;Kwon Oukwang;Sung Wonmo
    • Journal of the Korean Institute of Gas
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    • v.5 no.1
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    • pp.60-72
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    • 2001
  • This paper presents the user-interactive productivity analysis model based on material balance as well as deliverability equations equipped with EOS model to perform a productivity analysis for Gorae V structure, Donghae-1 gas field. This model is designed to be able to analyse the productivity in the case of reservoir contacting with the aquifer. Also, in order to investigate the effect of condensation on productions, condensation phenomenon is considered as an apparent skin effect in the computation of bottomhole pressure from average reservoir pressure. By utilizing the developed model, we investigate the productivity analysis for B2 layer of Garae V structure with the various production cases in volumetric and non­volumetric reservoirs that contact with aquifer. From the results in the case of 5500 MMSCF/year of production and reservoir-aquifer contacting angle 270$^{\circ}C$ with aquifer size of 10 times greater than reservoir, B2 layer could maintain peak production rate even after 8.5 years of production by considering the bottomhole pressure which is estimated above the operating pressure of 1298 psia. It is also found that condensate will be formed after 1100 days of production and existed throughout the reservoir at 1270 days. Note that the computed reservoir pressure of B2 layer is maintained sufficiently high enough for production due to the water influx into the reservoir, and skin effect caused by condensation is not significant.

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A Case Study on the Development of New Process for Treatment of Waste Waters from Ships (선박폐수 처리공정의 개발에 관한 사례)

  • Choi, Sang-Mo;Heo, In-Seok;Yang, Seok-Jun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.1
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    • pp.71-78
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    • 2009
  • Korea Marine Environment Management Corporation (KOEM) has waste oil facilities in 13 ports to collect and treat waste oil, bilge, etc. from ships based upon the Marine Environment Management Act of Korea and MARPOL 73/78 convention. Those facilities were designed and have been operated simply to discharge water under the level 15 ppm of oil contents. However, bad smells occurred from rotten organic matters in waste water and direct discharge of harmful substances to receiving water caused civil appeals. Therefore, KOEM tried to develop new process for treatment of oily waste water from ships, which could mitigate harmful substances, save cost, calm down civil appeals and contribute to marine environment preservation. This process consists of 3 steps to remove oil contents via gravity variation at first, $O_3$ input to contact water and organism deposition by inputting condensate deposits. Then finally upper water will be discharged, and the deposited substances in the bottom will be compressed through spinning machine to transfer to the designated contractors for treatment of wastes. This is very effective and innovative in that it could reduce 3 or 4 steps compared with existing process and mitigate not only waste oil concentration but also hard resolving materials such as colloid, ABS, phosphorus, nitrogen and bad smells. This method is expected to minimize bad smells and harmful gases, to save more than 10% of maintenance cost, and to arrange the good base for garbage treatment business dealing with waste water and bad smell.

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MANAGING A PROLONGED STATION BLACKOUT CONDITION IN AHWR BY PASSIVE MEANS

  • Kumar, Mukesh;Nayak, A.K.;Jain, V;Vijayan, P.K.;Vaze, K.K.
    • Nuclear Engineering and Technology
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    • v.45 no.5
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    • pp.605-612
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    • 2013
  • Removal of decay heat from an operating reactor during a prolonged station blackout condition is a big concern for reactor designers, especially after the recent Fukushima accident. In the case of a prolonged station blackout condition, heat removal is possible only by passive means since no pumps or active systems are available. Keeping this in mind, the AHWR has been designed with many passive safety features. One of them is a passive means of removing decay heat with the help of Isolation Condensers (ICs) which are submerged in a big water pool called the Gravity Driven Water Pool (GDWP). The ICs have many tubes in which the steam, generated by the reactor core due to the decay heat, flows and condenses by rejecting the heat into the water pool. After condensation, the condensate falls back into the steam drum of the reactor. The GDWP tank holds a large amount of water, about 8000 $m^3$, which is located at a higher elevation than the steam drum of the reactor in order to promote natural circulation. Due to the recent Fukushima type accidents, it has been a concern to understand and evaluate the capability of the ICs to remove decay heat for a prolonged period without escalating fuel sheath temperature. In view of this, an analysis has been performed for decay heat removal characteristics over several days of an AHWR by ICs. The computer code RELAP5/MOD3.2 was used for this purpose. Results indicate that the ICs can remove the decay heat for more than 10 days without causing any bulk boiling in the GDWP. After that, decay heat can be removed for more than 40 days by boiling off the pool inventory. The pressure inside the containment does not exceed the design pressure even after 10 days by condensation of steam generated from the GDWP on the walls of containment and on the Passive Containment Cooling System (PCCS) tubes. If venting is carried out after this period, the decay heat can be removed for more than 50 days without exceeding the design limits.

Numerical Investigation on Experiment for Passive Containment Cooling System (피동 원자로건물 냉각계통 실험에 관한 수치적 연구)

  • Ha, Hui Un;Suh, Jung Soo
    • Journal of the Korean Society of Safety
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    • v.35 no.3
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    • pp.96-104
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    • 2020
  • The numerical simulations were conducted to investigate the thermal-fluid phenomena occurred inside the experimental apparatus during a PCCS, used to remove heat released in accidents from a containment of light water nuclear power plant, operation. Numerical simulations of the flow and heat transfer caused by wall condensation inside the containment simulation vessel (CSV), which equipped with 18 vertical heat exchanger tubes, were conducted using the commercial computational fluid dynamics (CFD) software ANSYS-CFX. Shear stress transport (SST) and the wall condensation model were used for turbulence closure and wall condensation, respectively. The simulation using the actual size of the apparatus. However, rather than simulating the whole experimental apparatus in consideration of the experimental cases, calculation resources, and calculation time, the simulation model was prepared only in CSV. Selective simulation was conducted to verify the effects of non-condensable gas(NC gas) concentration, CSV internal pressure, and wall sub-cooling conditions. First, as a result of the internal flow of CSV, it was observed that downward flow due to condensation occurred surface of the vertical tube and upward flow occurred in the distant place. Natural convection occurred actively around the heat exchanger tube. Due to this rising and falling internal flow, natural circulation occurred actively around the heat exchanger tubes. Next, in order to check the performance of built-in condensation model using according to the non-condensable gas concentration, CSV internal flow and wall sub-cooling, the heat flux values were compared with the experimental results. On average, the results were underestimated with and error of about 25%. In addition, the influence of CSV internal pressure and wall sub-cooling was small, but when the condensate was highly generated due to the low non-condensable gas concentration, the error was large compared to the experimental values. This is considered to be due to the nature of the condensation model of the CFX code. However, in spite of the limitations of CFD, it is valid to use the built-in condensation model of CFD for PCCS performance prediction from a conservative perspective.

Local Heat Transfer Coefficients for Reflux Condensation Experiment in a Vertical Tube in the Presence of Noncondensible Gas

  • Moon, Young-Min;No, Hee-Cheon;Bang, Young-Seok
    • Proceedings of the Korean Nuclear Society Conference
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    • 1999.05a
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    • pp.104-104
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    • 1999
  • The local heat transfer coefficient is experimentally investigated for the reflux condensation in a countercurrent flow between the steam-air mixture and the condensate. A single vertical tube has a geometry which is a length of 2.4m, inner diameter of 16.56mm and outer diameter of 19.05mm and is made of stainless steel. Air is used as a noncondensible gas. The secondary side is installed in the form of coolant block around vertical tube and the heat by primary condensation is transferred to the coolant water. The local temperatures are measured at 15 locations in the vertical direction and each location has 3 measurement points in the radial direction, which are installed at the tube center, at the outer wall and at the coolant side. In three different pressures, the 27 sets of data are obtained in the range of inlet steam flow rate 1.348 -3.282kg/hr, of inlet air mass fraction 11.8 -55.0%. The local heat transfer coefficient increases as the increase of inlet steam flow rate and decreases as the decrease of inlet air mass fraction. As an increase of the system pressure, the active condensing region is contracted and the heat transfer capability in this region is magnified. The empirical correlation is developed represented with the 165 sets of local heat transfer data. As a result, the Jacob number and film Reynolds number are dominant parameters to govern the local heat transfer coefficient. The rms error is 17. 7% between the results by the experiment and by the correlation.

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Local Heat Transfer Coefficients for Reflux Condensation Experiment in a Vertical Tube in the Presence of Noncondensible Gas

  • Moon, Young-Min;No, Hee-Cheon;Bang, Young-Seok
    • Nuclear Engineering and Technology
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    • v.31 no.5
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    • pp.486-497
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    • 1999
  • The local heat transfer coefficient is experimentally investigated for the reflux condensation in a countercurrent flow between the steam-air mixture and the condensate, A single vertical tube has a geometry which is a length of 2.4m, inner diameter of 16.56mm and outer diameter of 19.05mm and is made of stainless steel. Air is used as a noncondensible gas. The secondary side has a shape of annulus around vertical tube and the lost heat by primary condensation is transferred to the coolant water. The local temperatures are measured at 11 locations in the vertical direction and each location has 3 measurement points in the radial direction, which are installed at the tube center, at the outer wall and at the coolant side. In three different pressures, the 27 sets of data are obtained in the range of inlet steam flow rate 1.348∼3.282kg/hr, of inlet air mass fraction 11.8∼55.0%. The investigation of the flooding is preceded to find the upper limit of the reflux condensation. Onset of flooding is lower than that of Wallis' correlation. The local heat transfer coefficient increases as the increase of inlet steam flow rate and decreases as the increase of inlet air mass fraction. As an increase of the system pressure, the active condensing region is contracted and the heat transfer capability in this region is magnified. The empirical correlation is developed by 165 data of the local heat transfer. As a result, the Jacob number and film Reynolds number are dominant parameters to govern the local heat transfer coefficient. The rms error is 17.7% between the results by the experiment and by the correlation.

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A Study on the Preparation of Solvent-Free Low Foaming Scouring Agents (무용제형 저기포성 정련제의 제조에 관한 연구)

  • Keun, Jang-Hyoun;Kim, Seung-Jin;Hahm, Hyun-Sik;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.760-769
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    • 1993
  • Solvent-free low foaming scouring agents(LFSA) were prepared by blending of polyoxyethylene(30) octadecylbenzylammonium chloride(POAC), block copolymer of propylene oxide-ethylene oxide[p(PO-b-EO) glycol], Sedlan FF-200(FF-200) and sulfonic acid-amine condensate of polyoxyethylene(10) nonylphenyl ether(PSAC). In consequence of several tests, FF-200/POAC/p(PO-b-EO) glycol/PSAC/water (20g/10g/5g/5g/60g) mixture (LFSA-5) showed good cleaning power, penetrating ability, emulsifiability and stability to alkali, and gave less problem in water pollution. Scouring effect of LFSA-5 was investigated by the change of percentage of exhaustion before and after scouring at various dyeing temperatures. The percentage of exhaustion of the unscoured PET fabric was 4.5% at $70^{\circ}C$, while that scoured with LFSA-5 was 1.3% at the same temperature, which proved LFSA-5 to be a good scouring agent. Moreover, the foaming power of LFSA-5 measured by Ross and Miles method was 6mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 20mm at $80^{\circ}C$. As a result, LFSA-5 proved a good low foaming scouring agent.

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Estimation of Characteristics Treatment for Food Waste with Blast Volume and Preheating of Air using Bio-Drying Process (Bio-drying 공법 활용 공기 투입 및 예열에 따른 음식물류 폐기물 분해 특성 평가)

  • Park, Seyong;Lee, Wonbea
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.15-25
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    • 2022
  • In this study, the efficiency of treatment of moisture and organic matter in food waste was analyzed according to the air blast volume and preheating using the bio-drying method. Te mount of air blast volume and preheating were determined by the evaluation of temperature and CO2 during food waste treatment using the bio-drying method. As a results, the increase in the air blast volume increased the moisture removal efficiency and removal rate, but, lowered the temperature inside the bio-drying by the decease in microbial activity. In order to maintain the activity of microorganisms, it was estimated that it was necessary to inject an appropriate air blast rate according th the properties of the food waste. In this study, the injection of air blast volume at 15L/min was optimal. It was evaluated that the organic matter and water removal rates according to the presence or absence of air preheating, the organic matter removal rate and water removal rate increased by 3-5% when air preheating was not performed. Also, there was no internal aggregation caused by the generation of condensate inside the bio-drying. Therefore, for effective bio-drying of food waste, it is necessary to maintain an appropriate air blast volume to maintain microbial activity, and it is considered that injection through preheating of air is required.

Tritium Distribution in Leachates from Domestic Solid Waste Landfills (생활폐기물 매립장 침출수의 삼중수소 분포)

  • Park, Soon Dal;Kim, Jung Suk;Joe, Kih Soo;Kim, Jong Gu;Kim, Won Ho
    • Analytical Science and Technology
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    • v.17 no.3
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    • pp.251-262
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    • 2004
  • It is for the purpose of investigating the tritium distribution in the leachates, the raw and treated leachates and the condensates of the methane gas, which have occurred from domestic solid waste landfills. Also it aims to measure the tritium distribution level on the colloid size of the leachates, the raw and treated leachates. It was found that the major inorganic contaminants of the leachates were Na, K, Ca, Mg, $NH{_4}^+$-N and $Cl^-$. The mean tritium level of the raw leachates of the investigated 13 landfill sites for 6 months was 17 ~ 1196 TU. It corresponded to a several scores or hundreds of magnitude higher value than that of the normal environmental sample level except for two landfill sites. Also such a high concentration of the tritium was found in the treated leachates and methane gas condensates as well. Nevertheless it is important to emphasize that the tritium level which was found in this research is about 100 times lower than the tritium limit for the drinking water quality. And most of the tritium existed in the dissolved colloid of the leachate of which the colloid size is below $0.45{\mu}m$. Also, according to the tritium analysis results of the leachates after filtration with $0.45{\mu}m$ membrane filter for some landfills, it is likely that some tritium of the leachate would be distributed in a colloid size over $0.45{\mu}m$. In general the relationship between the tritium and other contaminants in the raw leachate was low, but it was relatively high between the tritium and TOC. However, the tritium content in the leachate had no meaningful relationship with the scale, hydrological characteristics and age of the landfill.