• Title/Summary/Keyword: Concentration Gradient

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True Sedimentation and Particle Packing Rearrangement during Liquid Phase Sintering

  • Lee, Jong-K.;Xu, Lei;Lu, Shu Zu
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.68-69
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    • 2006
  • When an alloy such as Ni-W is liquid phase sintered, heavy solid W particles sedimentate to the bottom of the container, provided that their volume fraction is less than a critical value. The sintering process evolves typically in two stages, diffusiondriven macrosegregation sedimentation followed by true sedimentation. During macrosegregation sedimentation, the overall solid volume fraction decreases concurrently with elimination of liquid concentration gradient. However, in the second stage of true sedimentation, the average solid volume fraction in the mushy zone increases with time. It is proposed that the true sedimentation results from particle rearrangement for higher packing efficiency.

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Electric double layers interactions under condition of variable dielectric permittivity

  • Payam, Amir Farrokh;Fathipour, Morteza
    • Interaction and multiscale mechanics
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    • v.3 no.2
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    • pp.157-171
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    • 2010
  • In this paper, a theoretical method has been developed for the electric double layer interaction under condition of the variable dielectric permittivity of water. Using Poisson-Boltzmann equation (PBE), for one plate and two plates having similar or dissimilar constant charge or constant potential, we have investigated the electric double layer potential, its gradient and the disjoining pressure as well as the effect of variation of dielectric permittivity on these parameters. It has been assumed that plates are separated by a specific distance and contain a liquid solution in between. It is shown that reduction of the dielectric permittivity near the interfaces results in compression of electric double layers and affects the potential and its gradient which leads to a decreased electrostatic repulsion. In addition, it is shown that variation of dielectric permittivity in the case of higher electrolyte concentration, leads to a greater change in potential distribution between two plates.

Double-Diffusive Convection in a Salt-Stratified Fluid Heated From Below (농도 성층화된 유체의 아랫면 가열에 의한 이중확산대류에 관한 연구)

  • 강신형;김무현;이진호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.12
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    • pp.3297-3304
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    • 1994
  • Experimental investigation have been made to study the double-diffusive nature of convection of an initially stratified salt-water solution heated from below in a cylindrical cavity. The objective is to examine the process of mixed-layer formation, the flow phenomena, the heat transfer characteristics, and temperature and concentration distribution according to the changes in the effective Rayleigh number based on the reference height which represents the relation of temperature and concentration gradient. The types of initially formed flow pattern are categorized in three regimes depending on the effective Rayleigh number ; stagnant flow regime, single mixed-layer flow regime and successively formed multiple mixed-layer flow regime. The temperature and concentration profiles are both uniform in each layer due to convective mixing in the layered flow regime, but both linear in stagnant flow regime and single mixed-layer flow regime. At the interface between adjacent layers, the temperature changes smoothly but the concentration changes rapidly. The layers expand by diffusion of concentration through the interface along with its random fluctuation.

Annealing Effects on Concentration Profiles of Deep Energy Levels in Platinum-diffused Silicon (백금 확산 실리콘의 깊은 에너지 준위의 농도분포에 대한 열처리효과)

  • Kwon, Young-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.3
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    • pp.207-212
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    • 2007
  • The concentration profiles of deep energy levels($E_c$ -0.23e V, $E_v$+0.36e V and $E_c$ -0.23e V) in platinum-diffused silicon have generally a sharp gradient in the vicinity of the surface of the silicon wafer. In this work two efficient methods are proposed to obtain the uniform concentration profiles throughout the silicon wafer. One is that the platinum diffusion is carried out at $1000^{\circ}C$ for 1h in oxygen atmosphere. In this case the values of obtained uniform concentration, $1{\times}10^{15}cm^{-3}$ for the $E_c$ -0.23e V level, and 1{\times}10^{14}cm^{-3}$ for the $E_c$ -0.52e V level, are very restricted, respectively. The other is two-step annealing process. The platinum diffusion is carried out at $850{\sim}1100^{\circ}C$ in a nitrogen ambient for 1h and then the annealing is performed at $1000^{\circ}C$ in oxygen ambient after removing platinum-source from the platinum diffused samples. The advantage of this method is that the uniform concentration of these levels required power devices can be controlled by setting the desired temperatures when the platinum diffusion is carried out in nitrogen ambient.

Control of carrier concentrations by addition of $B_{2}O_{3}$ in Si-doped vertical gradient freeze (VGF) GaAs single crystal growth (수직경사응고(VGF)법에 의한 Si 도핑 GaAs 단결정 성장시 $B_{2}O_{3}$ 첨가에 따른 캐리어 농도 변화)

  • Bae, So-Ik;Han, Chang-Woon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.75-78
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    • 2009
  • Si-doped GaAs single crystals were grown by vertical gradient freeze using PBN crucibles. The amount of oxide layer $B_{2}O_{3}$ in PBN crucible was changed($0{\sim}0.2wt%$) and measured the concentration of carriers. The segregation coefficients of Si in GaAs melt decreased rapidly from initial 0.1 to 0.01 as the amount of $B_{2}O_{3}$ increases. At the same time, concentration of carriers was shown to decrease. It is likely that the reaction between dopant Si and $B_{2}O_{3}$ in GaAs melt results in the reduction of Si dopants(donor) while increase in the amount of boron(acceptor). The thin layer of $B_{2}O_{3}$ glass in PBN crucible was proved to be a better way to reduce defect formation rather than the total amount of $B_{2}O_{3}$.

Variation of Ecological Niche of Quercus serrata under Elevated $CO_2$ Concentration and Temperature ($CO_2$ 농도 및 온도 상승에 의한 졸참나무의 생태적 지위 변화)

  • Cho, Kyu-Tae;Jeong, Heon-Mo;Han, Young-Sub;Lee, Seung-Hyuk
    • Korean Journal of Environmental Biology
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    • v.32 no.2
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    • pp.95-101
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    • 2014
  • In order to investigate effects of elevated $CO_2$ concentration and temperature on the ecological niche of Quercus serrata in Korea. We divided experimental condition in the greenhouse that are control (ambient condition) and treatment with elevated $CO_2$ (approximately 1.6 above than control) and increased air temperature (approximately $2.2^{\circ}C$ above than control). We measured twenty kind characters of seedlings and calculated the ecological niche breadth. As a result, the ecological niche breadth, treatment was widened in the light gradient than the control, was narrowed in the moisture and nutrient gradient. This is may be predicted when the global warming progress, Q. serrata is increases resistance to light environment, and decrease resistance to moisture and nutrient environment. According to the principal component analysis (PCA), control and treatment were arranged based on factor 1 and 2 in each environment gradients. Ecological response is involved variety characters. Among them, indicating that Characters of production is involved in many a parts.

Development of Machine Learning Models Classifying Nitrogen Deficiency Based on Leaf Chemical Properties in Shiranuhi (Citrus unshiu × C. sinensis) (부지화 잎의 화학성분에 기반한 질소결핍 여부 구분 머신러닝 모델 개발)

  • Park, Won Pyo;Heo, Seong
    • Korean Journal of Plant Resources
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    • v.35 no.2
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    • pp.192-200
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    • 2022
  • Nitrogen is the most essential macronutrient for the growth of fruit trees and is important factor determining the fruit yield. In order to produce high-quality fruits, it is necessary to supply the appropriate nitrogen fertilizer at the right time. For this, it is a prerequisite to accurately diagnose the nitrogen status of fruit trees. The fastest and most accurate way to determine the nitrogen deficiency of fruit trees is to measure the nitrogen concentration in leaves. However, it is not easy for citrus growers to measure nitrogen concentration through leaf analysis. In this study, several machine learning models were developed to classify the nitrogen deficiency based on the concentration measurement of mineral nutrients in the leaves of tangor Shiranuhi (Citrus unshiu × C. sinensis). The data analyzed from the leaves were increased to about 1,000 training dataset through the bootstrapping method and used to train the models. As a result of testing each model, gradient boosting model showed the best classification performance with an accuracy of 0.971.

Model-Based Simulation Analysis of Wicking Behavior in Hygroscopic Cotton Fabric

  • Hong, Cheol-Jae;Kim, Byung-Jick
    • Journal of Fashion Business
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    • v.20 no.6
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    • pp.66-78
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    • 2016
  • Hygroscopic knitted cotton fabric was found to spontaneously absorb water showing a significantly wide concentration gradient in the absorption direction. A semi-empirical diffusion model was introduced to describe how the wicking behavior compared to the classical capillary model (Washburn's equation), which has been widely used in the textiles industry. The capillary sorption curve and the permeability coefficient, which are key variables for the model equations, were measured using an electronic balance. The concentration profile as a function of the wicking distance and the elapsed time was derived, based on the diffusion model. From the concentration profile, the wicking distance detectable by the human eye or a digital camera with the aid of an image-analysis system, could be described realistically as a function of the time. The classical capillary model could be modified by introducing the tortuous correction factor to match the diffusion model. Wicking models and data-processing techniques in the work could provide useful tools for objectively evaluating the textile's wicking performances.

Simulations of Pollutant Dispersion over Rectangular Building (사각 건물 주위의 오염물 확산에 대한 수치해석적 연구)

  • Hong B. Y.;Park C. G.
    • Journal of computational fluids engineering
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    • v.6 no.4
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    • pp.1-7
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    • 2001
  • Wind flow perturbations, recirculations and turbulence generated by buildings often dominate air pollutant distributions around buildings. This paper describes dispersion of contaminants in the vicinity of a building by solving the concentration equation based on previously simulated wind flow field. Turbulence closure is achieved by using the standard k-ε two-equation model. The paper shows application of the CIP method for solving a species concentration equation of contaminant gas around a rectangular building for two different sources under conditions of neutral atmospheric stratification. Results have been compared to the experimental data and the previous numerical results by hybrid scheme. The computational results of concentration profiles by the CIP method agree well with experimental data.

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Development of Numerical Analysis Program Considering Variation of Soil Properties During Electrokinetic Remediation (Electrokinetic 정화 처리 중 토체내의 특성변화를 고려한 수치해석 프로그램 개발)

  • 한상재;김치열;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.202-205
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    • 2001
  • In this study, the electrokinetic remediation test for the kaolin contaminated by lead was performed and voltage, zeta potential, pH distribution, current, contamination transport in soil sample were studied and finite differential numerical analysis program(HERP) for a contaminated soil were compared with those of test. From the result of HERP, in the anode it was represented that the rest concentration was decreased with the voltage. Hence, if treatment time was continued for a long in the constant voltage, comparing with sample having no change in the rest concentration, it is considered that the voltage gradient is the control factor of the rest concentration.

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