• Title/Summary/Keyword: Concentration Gradient

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Biofilms and their Activity in Granular Activated Carbons Established in a Drinking Water Treatment Plant (정수장 활성탄 여과지의 생물막과 그 활성도)

  • Lee, Ji-Young;Kim, Se-Jun;Chung, Ik-Sang;Joh, Gyeong-Je
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.6
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    • pp.661-674
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    • 2010
  • Bacterial biomass and its activity were measured in two kinds of granular activated carbon (GAC), the experimental and existing biofiltration system in a drinking water plant. The bacterial biomass was around 210 to 250 nmol P/g WW with phospholipid concentration at acclimation of ozonation treatment. The phospholipid biomass shows more or less a declining gradient along filter depth and no clear seasonality in its values. On the other hand, the microbial activity of [$^3H$]-thymidine and [$^{14}C$]-acetate incorporation within cells increased significantly along the filter depth, showing the difference of three fold between the upper and bottom layer. These factors support the different microbial composition or metabolic activity along the depth of GAC column. Turnover rates, the rate of bacterial biomass and production of biofilm, ranged from 0.26 /hr to 0.37 /hr, indicating a highly rapid recovery itself at amature state. In the non-ozonation treatment, the bacterial biomass was lower than in the ozonation and biological activity also declined towards the filter depth. The biomass levels during cessation of ozonation in the existing GAC filters were 68% of the actively ozonated state.

MERCURY-INDUCED ALTERATIONS OF CHLOROPHYLL a FLUORESCENCE KINETICS IN ISOLATED BARLEY (Hordeum vulgare L. cv. ALBORI) CHLOROPLASTS

  • Chun, Hyun-Sik;Lee, Choon-Hwan;Lee, Chin-Bum
    • Journal of Photoscience
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    • v.1 no.1
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    • pp.47-52
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    • 1994
  • Effects of HgCl$_2$-treatment on electron transport, chlorophyll a fluorescence and its quenching were studied using isolated barley (Hordeum vulgare L. cv. Albori) chloroplasts. Depending on the concentration of HgCI$_2$, photosynthetic oxygen-evolving activities of photosystem II (PS II) were greatly inhibited, whereas those of photosystem I (PS I) were slightly decreased. The inhibitory effects of HgCl$_2$ on the oxygen-evolving activity was partially restored by the addition of hydroxyamine, suggesting the primary inhibition site by HgCl$_2$2-treatment is close to the oxidizing site of PS tl associated with water-splitting complex. Addition of 50 $\mu$M HgCI$_2$ decreased both photochemical and nonphotochemical quenching of chlorophyll fluorescence. Especially, energy dependent quenching (qE) was completely disappeared by HgCl$_2$-treatment as observed by NH$_4$CI treatment. In the presence of HgCI$_2$, F'o level during illumination was also increased. These results suggest that pH gradient across thylakoid membrane can not be formed in the presence of 0 $\mu$M HgCl$_2$. In addition, antenna pigment composition might be altered by HgCl$_2$-treatment.

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Normal and Micro Gravity Experiments on Propagation Speed of Tribrachial Flame of Propane in Laminar Jets (정상 및 미소중력장에서 프로판 층류 제트 삼지 화염의 전파속도에 관한 실험적 연구)

  • Lee, J.;Won, S.H.;Jin, S.H.;Fujita, O.;Ito, K.;Chung, S.H.
    • Journal of the Korean Society of Combustion
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    • v.7 no.3
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    • pp.47-54
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    • 2002
  • The propagation speed of tribrachial flame in laminar propane jets has been investigated experimentally under normal and micro gravity conditions. The displacement speed was found to vary nonlinearly with axial distance because flow velocity along stoichiometric contour was comparable to the propagation speed of tribrachial flame for the present experiment. Approximate solutions for velocity and concentration accounting density difference and virtual origins have been used in determining the propagation speeds of tribrachial flame. Under micro gravity condition, the results showed that propagation speed of tribrachial flame is largely affected by the mixture fraction gradients, in agreement with previous studies. The limiting maximum value. of propagation speeds under micro gravity conditions are in good agreement with the theoretical prediction, that is, the ratio of maximum propagation speed to the stoichiometric laminar burning velocity is proportional to the square root of the density ratio of unburned to burnt mixture.

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A Fast Determination of Globotriaosylsphingosine in Plasma for Screening Fabry Disease Using UPLC-ESI-MS/MS

  • Yoon, Hye-Ran
    • Mass Spectrometry Letters
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    • v.6 no.4
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    • pp.116-119
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    • 2015
  • Globotriaosylsphingosine (lyso-Gb3) is considered as one of the biological marker for Fabry disease. To date, a reliable biomarker that reflects disease severity and progression has not been discovered to guide the management of Fabry disease. A new method included a simple protein precipitation with acetonitrile in 100 μL of plasma following analyte separation on an Phenomenex Kintex- C18 column using a gradient elution (0.1% formic acid in 5-90% acetonitrile). Total run time was within 12 min including sample preparation and MS/MS analysis. The limit of detection and limit of quantitation were 1 ng/mL and 2 ng/mL, respectively. The calibration curve was linear over the concentration range of 2.0-200.0 ng/mL (r2 = 0.9999). Inter-day accuracy and precision at 7 level were 93.4-100.7% with RSD of 0.55-5.97%. Absolute recovery was 97.6-98.6%. The method was applied to human and mice plasma, proved the suitability for quantification of lyso-Gb3 for screening, diagnosis and therapeutic monitoring of Fabry disease patients.

Organic fouling in forward osmosis (FO): Membrane flux behavior and foulant quantification

  • Xia, Shengji;Yao, Lijuan;Yang, Ruilin;Zhou, Yumin
    • Membrane and Water Treatment
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    • v.6 no.2
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    • pp.161-172
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    • 2015
  • Forward osmosis (FO) is an emerging membrane technology with potential applications in desalination and wastewater reclamation. The osmotic pressure gradient across the FO membrane is used to generate water flux. In this study, flux performance and foulant deposition on the FO membrane were systematically investigated with a co-current cross-flow membrane system. Sodium alginate (SA), bovine serum albumin (BSA) and tannic acid (TA) were used as model foulants. Organics adsorbed on the membrane were peeled off via oscillation and characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). When an initial flux of $8.42L/m^2h$ was applied, both flux reduction and foulant deposition were slight for the feed solution containing BSA and TA. In comparison, flux reduction and foulant deposition were much more severe for the feed solution containing SA, as a distinct SA cake-layer was formed on the membrane surface and played a crucial role in membrane fouling. In addition, as the initial SA concentration increased in FS, the thickness of the cake-layer increased remarkably, and the membrane fouling became more severe.

FGM micro-gripper under electrostatic and intermolecular Van-der Waals forces using modified couple stress theory

  • Jahangiri, Reza;Jahangiri, Hadi;Khezerloo, Hamed
    • Steel and Composite Structures
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    • v.18 no.6
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    • pp.1541-1555
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    • 2015
  • In this paper mechanical behavior of the functional gradient materials (FGM) micro-gripper under thermal load and DC voltage is numerically investigated taking into account the effect of intermolecular forces. In contrary to the similar previous works, which have been conducted for homogenous material, here, the FGM material has been implemented. It is assumed that the FGM micro-gripper is made of metal and ceramic and that material properties are changed continuously along the beam thickness according to a given function. The nonlinear governing equations of the static and dynamic deflection of microbeams have been derived using the coupled stress theory. The equations have been solved using the Galerkin based step-by-step linearization method (SSLM). The solution procedure has been evaluated against available data of literature showing good agreement. A parametric study has been conducted, focusing on the combined effects of important parameters included DC voltage, temperature variation, geometrical dimensions and ceramic volume concentration on the dynamic response and stability of the FGM micro-gripper.

Buoyancy and Vertical Distribution of Mackerel Scomber japonicus Eggs in Korean Waters (한국 연근해 고등어(Scomber japonicus) 알의 비중과 수직분포)

  • Jung, Kyung-Mi;Kang, Sukyung;Cha, Hyung Kee;Choi, Kwang Ho;Myksvoll, Mari S.
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.6
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    • pp.957-965
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    • 2013
  • This study simulated the egg vertical distribution of mackerel Scomber japonicus in Korean waters using general numerical models. All eggs were spawned naturally by raising broodfishes (May-June 2013), and the egg specific gravity was measured by a density-gradient column. CTD surveys provided environmental data (e.g., temperature and salinity) in May near Jeju Island, Korea. The egg specific gravity during the early stages ranged from 1.0203-1.0211. In general, the fertilized eggs showed a gradual decline in egg specific gravity until full development of the main organs, with a sudden increase just before hatching. Modeled egg vertical distributions were influenced more by wind speed than by egg buoyancy and vertical structure of the sea water. During calm and normal wind speeds, the eggs were distributed from the surface to 25-m depths. Under strong wind conditions (three times higher than the normal speed), the egg concentration on the surface decreased, and the egg distributional depth was deeper (~50 m).

The characteristics of the sulfur-doped $In_{1-x}Ga_xP$ Light emitting diode (Sulfur를 첨가한 $In_{1-x}Ga_xP$의 발광 다이오드 특성)

  • Cho, M.W.;Moon, D.C.;Kim, S.T.
    • Proceedings of the KIEE Conference
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    • 1988.11a
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    • pp.168-171
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    • 1988
  • The p-n homo junction diode of the III-V ternary alloy semiconductor $In_{1-x}Ga_xP$ : S grown by the temperature gradient solution (TGS) was fabricated by Zn-diffusion, and it's characteristics was investigated. The carrier concentration of $In_{1-x}Ga_xP$ doped with sulfur, 0.5 mol %, was $1{\times}10^{17}cm^{-3}$ and the mobility was varied with the composition. In the case that the diffusion time was constant as 30 minutes. The temperature dependence of diffusion coefficient was decreased from D= $4.2{\times}10^{-5}$ exp (-1.74/$k_{B}T$) to D= $2.5{\times}10^{-5}$ exp (-3.272/$k_{B}T$) with increasing of composition $\times$ from 0.43 to 0.98. The major peak of E.L spectrum was due to D-A pair recombination and the peak intensity was increased with the increasing of input current. And the E.L intensity was decreased with the increasing temperature, and shift to the long wavelength. The luminescence efficiencies measured at $5^{\circ}C$, atmosphere temperature, was decreased from $2.6{\times}10^{-4}$% to $9.49{\times}10^{-6}$ % with increasing of composition it from 0.39, direct transition region, to 0.98, indirect transition region.

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The Epoxy-metal Interphase and Its Incidence on Practical Adhesion

  • Roche, Alain Andre;Aufray, Maelenn
    • Journal of Adhesion and Interface
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    • v.4 no.2
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    • pp.1-9
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    • 2003
  • Epoxy-amine liquid prepolymers are extensively applied onto metallic substrates and cured to obtain painted materials or bonded joint structures. Overall performances of such systems depend on the created interphase between the organic layer and the substrate. When epoxy-amine liquid mixtures are applied onto more or less hydrated metallic oxide layer, concomitant amine chemical sorption and hydroxide dissolution appear lending to the chelate formation. As soon as the chelate concentration is higher than the solubility product, these species crystallize as sharp needles. Moreover, intrinsic and thermal residual stresses are developed within painted or bonded systems. When residual stresses are higher than the organic layer/substrate adhesion, buckling, blistering, debonding may occur leading to a catastrophic drop of system performances. Practical adhesion can be evaluated with either ultimate parameters (Fmax or Dmax) or the critical strain energy release rate, using the three point flexure test (ISO 14679-1997). We observe that, for the same system, the ultimate load decreases while residual stresses increase when the liquid/solid time increases. Ultimate loads and residual stresses depend on the metallic surface treatment. For these systems, the critical strain energy release rate which takes into account the residual stress profile and the Young's modulus gradient remains quite constant whatever the metallic surface treatment was. These variations will be discussed and correlate to the formation mechanisms of the interphase.

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The comparison of the adsorption characteristic of heavy metals onto soil mixed with food compost using retardation coefficient (지연계수를 이용한 음식물 퇴비 혼합 토양의 중금속 흡착특성 비교)

  • Joo, You-Yoen;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.245-250
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    • 2008
  • Adsorption experiment was carried out to find the adsorption capacity and characteristics of heavy metals(Cd, Pb) onto soil and mixed soil with food compost. Result showed that mixed soil having higher organic content adsorbed more heavy metal than soil, indicating that food compost can be used effectively to prevent soil pollution. Linear adsorption isotherm which adopted to find the adsorption characteristics was used to calculate Retardation Factor(R). The value of Retardation Factor(R)s of Pb and Cd in mixed soil, found as 34.54, 24.42 respectively, are higher than those in soil which were found as 4.64, 3.67, respectively. The value of Retardation Factor(R) using Freundlich adsorption isotherm could be presented by the functions of concentration and showed similar result as the linear one. But Freundlich adsorption isotherm showed higher relationship than linear one and the retardation factor(R) from freundlich adsorption isotherm was thought as more effective method to assess adsorption capacity because it could reflect gradient and intercept of the isotherm.