• Journal of the Korean Chemical Society
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• v.38 no.12
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• pp.864-872
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• 1994

Absorption spectra of thermochromic spiropyran and spirooxazine derivatives were investigated. The effects of solvent polarity on the absorption spectra indicate that the merocyanine-like form of non-substituted spiro compound is likely to the quinoid type. However, the merocyanine-like form of electron-withdrawing substituted spiro compound is likely to the zwitter-ion type. The enthalpy changes between the closed and merocyanine-like forms were measured. The enthalpy change of spiro compound decreases as the solvent polarity increases. The UV-Vis spectrum of merocyanine-like form was resolved into three Lorentzian-Gaussian product bands. The solvent dependence of the amount of the three band was also examined.

• Journal of Communications and Networks
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• v.12 no.5
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• pp.411-432
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• 2010

We consider three different secure broadcasting scenarios: i) Broadcast channels with common and confidential messages (BCC), ii) multi-receiver wiretap channels with public and confidential messages, and iii) compound wiretap channels. The BCC is a broadcast channel with two users, where in addition to the common message sent to both users, a private message, which needs to be kept hidden as much as possible from the other user, is sent to each user. In this model, each user treats the other user as an eavesdropper. The multi-receiver wiretap channel is a broadcast channel with two legitimate users and an external eavesdropper, where the transmitter sends a pair of public and confidential messages to each legitimate user. Although there is no secrecy concern about the public messages, the confidential messages need to be kept perfectly secret from the eavesdropper. The compound wiretap channel is a compound broadcast channel with a group of legitimate users and a group of eavesdroppers. In this model, the transmitter sends a common confidential message to the legitimate users, and this confidential message needs to be kept perfectly secret from all eavesdroppers. In this paper, we provide a survey of the existing information-theoretic results for these three forms of secure broadcasting problems, with a closer look at the Gaussian multiple-input multiple-output (MIMO) channel models. We also present the existing results for the more general discrete memoryless channel models, as they are often the first step in obtaining the capacity results for the corresponding Gaussian MIMO channel models.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.29 no.8
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• pp.615-623
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• 2018

The probability density function(PDF) for the amplitude of the reflectivity of low-grazing-angle sea clutter has generally been modeled by a compound-Gaussian distribution, rather than by the Rayleigh distribution, owing to the intensity variation of each clutter patch over time. The texture component forming the reflectivity has been simulated by combining Gamma distribution and memory-less nonlinear transformation(MNLT). On the other hand, there is no typical method available that can be used to simulate the speckle component. We first review Watt's method, wherein the speckle is simulated starting from the Doppler spectrum of the received echoes that is modeled as having a Gaussian shape. Then, we introduce a newly proposed method. The proposed method simulates the speckle by manipulating a clutter covariance matrix through the Cholesky decomposition after minimizing the effect of adjacent clutter patches using an equalizer. The feasibility of the proposed method is validated through simulation, wherein the results from two methods are compared in terms of the Doppler spectrum and the correlation function.

• Journal of the Korean Institute of Telematics and Electronics
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• v.22 no.1
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• pp.1-6
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• 1985

The point spread function of defocussed image is known as two dimensional function, one of rectangular type and Gaussian type function and etc, and the defocussed image can be modeled as the convolved output between original image and the supposed PSF. But, in .case of analog method using the scanning line of TV camera, one dimensional Process can be effective, and it was shown thats the defocussed image can be analyzed as the convolved output betlween the original image and the pule with finite width in the horizontal irection. And uslng TV camera and a analog compound high pass filter, the restoration experiment Is matte and we have got some pictures with remarked improvements.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2007.11a
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• pp.469-473
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• 2007

For the quantitative analysis of inclusion using OES data, separating of noise and inclusion is needed. In previous methods assuming that noises come from a normal distribution, intensity levels beyond a specific threshold are determined as inclusions. However, it is not possible to classify inclusions in low intensity region using this method, even though every inclusion is an element of some chemical compound. In this paper, we assume that distribution of OES data is a Gaussian mixture and estimate the parameters of the mixture model using EM algorithm. Then, we calculate mixing ratio of noise and inclusion using these parameters to separate noise and inclusion.

• Korean Journal of Optics and Photonics
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• v.10 no.6
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• pp.500-506
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• 1999

We designed and fabricated a bidirectional optical transceiver module for low cost access network. An integrated chip forming a pin-PD on an 1.3 urn FP-LD was assembled by flip-chip bonding on a Si optical bench, a single mode fiber with an angled end facet was aligned passively with the integrated chip on V-groove of Si-optical bench. Gaussian beam theory was applied to evaluate the coupling coefficients as a function of some parameters such as alignment distance, angle of fiber end facet, vertical alignment error. The theory is also used to search the bottle-neck between transmittance and receiving coupling efficiency in the bi-directional optical system. Tn this paper, we confirmed that reduction of coupling efficiency by the vertical alignment error between laser beam and fiber core axis can be compensated by controlling the fiber facet angle. In the fabrication of sub-module, a'||'&'||' we made such that the fiber facet have a corn shape with an angled facet only core part, the reflection of transmitted laser beam from the fiber facet could be minimized below -35 dE in alignment distance of 2: 30 /J.m. In the same condition, transmitted output power of -12.1 dEm and responsivity of 0.2. AIW were obtained.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.3
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• pp.96-102
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• 2015

Traditional propellants emit toxic gases such as carbon dioxide and hydrogen chloride during combustion which are harmful to the environment. This study established a synthetic process of a high nitrogen containing derivative of tetrazine, 3,3-Azobis(6-Amino-1,2,4,5-Tetrazine) (DAAT), which can be applied as solid fuels for a solution to environmental concerns. Also, this paper described the detailed process and the analytic results of properties, which were not mentioned in previous reports. The compound was characterized by NMR, IR spectroscopy, and thermal, impact, and friction stability were measured. In addition, the heats of formation (${\Delta}H_f$) and detonation properties (pressure and velocity) of DAAT were calculated using Gaussian 09 and EXPLO5 programs.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.881-886
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• 2010

A novel Schiff base N-(2,4-dinitro-phenyl)-N'-(1-phenyl-ethylidene)-hydrazine has been synthesized and structurally characterized by X-ray single crystal diffraction, elemental analysis, IR spectra and UV-vis spectrum. The crystal belongs to monoclinic with space group P21/n. The molecules are connected via intermolecular O-$H{\cdots}O$ hydrogen bonds into 1D infinite chains. The crystal structure is consolidated by the intramolecular N-$H{\cdots}O$ hydrogen bonds. weak intermolecular C-$H{\cdots}O$ hydrogen bonds link the molecules into intriguing 3D framework. Furthermore, Density functional theory (DFT) calculations of the structure, stabilities, orbital energies, composition characteristics of some frontier molecular orbitals and Mulliken charge distributions of the title compound were performed by means of Gaussian 03W package and taking B3LYP/6-31G(d) basis set. The time-dependent DFT calculations have been employed to calculate the electronic spectrum of the title compound, and the UV-vis spectra has been discussed on this basis. The results show that DFT method at B3LYP/6-31G(d) level can well reproduce the structure of the title compound.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.492-497
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• 2016

The intermediate product resulting from the radical degradation experiment of PCE and the atomic charge gained through Gaussian03W were compared against each other. The result was that the ratio of PCE radical degradation was almost 98% or higher after the 9 hr point in reaction time. The reaction speed constant was $0.16hr^{-1}$ and it followed the first reaction. We could see that at each location of the PCE molecule, dechlorination happened at a point where the negative atomic charge was the greatest. Moreover, the intermediate product of PCE radical degradation that was confirmed in the experiment and literature coincided exactly with the intermediate product in the atomic charge calculation. Therefore, when the atomic charge is calculated, the radical degradation pathway of the organic chlorine compound could be forecast.

• Journal of Integrative Natural Science
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• v.6 no.1
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• pp.8-11
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• 2013

In this manuscript, we report a protocol to determine most of the lowest energy conformations from the ensemble of conformations. 12-crown-4 was taken as study compound to get the most of energy minima conformations. Molecular dynamic (MD) simulation for 1 nanosecond (ns) was performed at 300, 500, 700, 900 and 1100 K temperature. At particular interval conformations were sampled. Then Gaussian program was used to minimize compounds using PM6 energy levels. Duplicates were removed by checking energy as well as mirror image conformations, and only unique conformations were retained for the next $6-31+G^*$ level minimization. It was observed that upto certain increment in temperature the number of unique conformations were increased, but afterword it decreased.