• Title/Summary/Keyword: Compositional Structure

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Structure and Thermal Properties of SnO2-(1-x)P2O5-xB2O3 Glasses (SnO2-(1-x)P2O5-xB2O3 유리의 열적, 구조적 특성)

  • An, Yong-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Chang, Woo-Suk;Bae, Hyun;Hwang, Hae-Jin
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.117-121
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    • 2010
  • $SnO_2-(1-x)P_2O_5-xB_2O_3$ glass system were prepared by melt-quenching technique in the compositional series containing 50, 55 and 60 mol% of $SnO_2$. Local structure of the glasses was investigated by Raman and FT-IR measurements. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5~25 mol% of $B_2O_3$. According as content of $B_2O_3$ increases, theraml expansion coefficient of glass decreased but transition temperature and softening temperature increased. Because these phenomenon changed local structure of glass. According as content of $B_2O_3$ increases, quantity of bridging oxygen increased. Also, according as content of $SnO_2$ increases, confirmed that quantity of non-bridging oxygen increases.

Optimization of multiple-quantum-well structures in 1.55.$\mu$ InGaAsP/InGaAsP SL-MQW DFB-LD for high-speed direct modulation (고속직접변조를 위한 1.55.$\mu$. InGaAsP/InGaAsP SL-MQW DFB-LD의 양자우물구조의 최적화)

  • 심종인;한백형
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.3
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    • pp.60-73
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    • 1997
  • By introducing a compressive-strained quanternary InGaAsP quantum-wells instead of a conventional ternary InGaAs quantum-wells in 1.55.mu.m DFB-LD, the lasing performances canb e improved and the problems caused by the thickness non-uniformity and the compositional abruptness among the hetero-interpaces canb e relaxed. In this paper, we investigated an iptimum InGaAsP/InGaAsP multiple-quantum-well(MQW) structure as an active layer in a direct-modulated 1.55.mu. DFB-LD from the view point of threshold current, chirping charcteristics, and resonance frequency. The optimum compressive-strained MQW structure was revealed as InGaAsP/InGaAsP structure with strain amount of about 1.2%, number of wells $N_{w}$ of 7, well width $L_{w}$ of 58.agns.. The threshold current density J of 500A/c $m^{2}$, the linewidth enhancement factor a of 1.8, and differential resonance frequency of d $f_{r}$/d(I-I)$^{1}$2/=2GHz/(mA)$^{1}$2/(atI=2 $I_{th}$) were expected in 1.55.mu.m .gamma./4-shifted DFB-LD with the cavity length of 400.mu.m long and kL value of 1.25. These values are considerably improved ones compared to those of 1.55um DFB-LD with InGaAs/InGaAsP MQW which have enhancement factor and the resonance frequence frequency by the detuning of lasing wavelength and gain-peak wavelength. It was found that the linewidth enhancement factor of 20% and differential resonance frequency of 35% without the degradation of the threshold current density could be enhanced in the range of -15nm~-20nm detuning which can be realized by controlling the thickness and Incomposition of InGaAsP well. well.and Incomposition of InGaAsP well. well.

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Thermal and Creep Analysis of an Exhaust Duct of Smart UAV with FGM (경사기능재료를 사용한 스마트 무인기 덕트의 열해석과 크리프 해석)

  • Im, Jong-Bin;Park, Jeong-Seon;Yun, Dong-Yeong;Lee, Jeong-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.1
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    • pp.65-73
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    • 2006
  • The high temperature occurs due to the combustion gas from engine in unmanned aerial vehicles (UAV). The high temperature may cause serious damages in UAV structure. The Functionally Graded Material (FGM) is chosen as a candidate material of the engine duct structure. A functionally graded material (FGM) is a two- component mixture composed by compositional gradient materials from one material to the other. In contrast, traditional composite materials are homogeneous mixtures, and involve compositions between the desirable properties of the component materials. Since significant proportions of an FGM contain the pure form of each material, the need for compromise is eliminated. The properties of both components can be fully utilized. Thermal stress analysis of FGM layers (20, 40, 60, 80 and 100) is performed in this paper. In addition, the creep behavior of FGM applied in duct structure of an engine is analyzed for better understanding of FGM characteristics.

Circulation Dynamics to Improve Commercial Activity in a Mega Mall

  • Kwun, Joon-Bum;Kim, Duk-Su
    • Architectural research
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    • v.15 no.4
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    • pp.183-190
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    • 2013
  • The 'one-day-shopping' concept that we experience today in a modern mega mall changed the propensity to consume compared to the past. The idea of a mega mall originated in the U.S. and the first suburban shopping malls as we know them today were built in the 1950s. The convenience of these malls had a great impact not only on consumers but also on the retail industry in general and the new mega mall idea has since spread around the world, with the largest ones located in China and Southeast Asia. Meanwhile, Korea had the fastest-growing economy during the last three decades and with that boom the compositional structure of domestic retail facilities became extremely diverse. Today, there are 36 new mega mall development plans to be completed before 2016, which represent a rapid and dynamic change in consumerism lifestyle in Korea. In this regard, this study will re-evaluate the first mega mall in Korea, the COEX Mall, and identify initial errors regarding its circulation plan and provide an ideal design strategy for future commercial mega malls based on literature review and comparison analysis.

MS-HEMs: An On-line Management System for High-Energy Molecules at ADD and BMDRC in Korea

  • Lee, Sung-Kwang;Cho, Soo-Gyeong;Park, Jae-Sung;Kim, Kwang-Yeon;No, Kyoung-Tae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.855-861
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    • 2012
  • A pioneering version of an on-line management system for high-energy molecules (MS-HEMs) was developed by the ADD and BMDRC in Korea. The current system can manage the physicochemical and explosive properties of virtual and existing HEMs. The on-line MS-HEMs consist of three main routines: management, calculation, and search. The management routine contains a user-friendly interface to store and manage molecular structures and other properties of the new HEMs. The calculation routine automatically calculates a number of compositional and topological molecular descriptors when a new HEM is stored in the MS-HEMs. Physical properties, such as the heat of formation and density, can also be calculated using group additivity methods. In addition, the calculation routine for the impact sensitivity can be used to obtain the safety nature of new HEMs. The impact sensitivity was estimated in a knowledge-based manner using in-house neural network code. The search routine enables general users to find an exact HEM and its properties by sketching a 2D chemical structure, or to retrieve HEMs and their properties by giving a range of properties. These on-line MS-HEMs are expected be powerful tool for deriving novel promising HEMs.

Preparation and properties of multiferroic bismuth iron oxides

  • Nam, Joong-Hee;Joo, Yong-Hui;Cho, Jeong-Ho;Chun, Myoung-Pyo;Kim, Byung-Ik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.66-69
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    • 2009
  • The compositional dependence of bismuth iron oxides and effect of La-substitutions in the structure of $BiFeO_3$ compounds were investigated, which compounds were synthesized by conventional ceramic processing. It is shown that some of bismuth iron oxides including $BiFeO_3$ show the narrow single phase region. The effect of La-doping in $BiFeO_3$ was presented as disappearance of many impurity phases of Bi-Fe-O compounds. The lower electrical resistivity was obtained as those compositions of Fe deficient region and La-doped $BiFeO_3$. The saturation magnetization of La-doped $BiFeO_3$ was increased with La content. The dielectric dispersion was also observed for those Bi-Fe-O compounds with Fe deficient and La-doped $BiFeO_3$ at low frequencies under 1 kHz.

Properties of Ag Thin Films Deposited in Oxygen Atmosphere Using in- line Magnetron Sputter System (In-line 마그네트론 스퍼터 장치를 사용하여 산소 분위기에서 제작한 Ag 박막의 특성)

  • Ku, Dae-Young;Kim, Won-Mok;Cho, Sang-Moo;Hwang, Man-Soo;Lee, In-Kyu;Cheong, Byung-Ki;Lee, Taek-Sung;Lee, Kyeong-Seok;Cho, Sung-Hun
    • Korean Journal of Materials Research
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    • v.12 no.8
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    • pp.661-668
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    • 2002
  • A study was made to examine the electrical, compositional, structural and morphological properties of Ag thin films deposited by DC magnetron sputtering in $O_2$ atmosphere with deposition temperature from room temperature to 15$0^{\circ}C$ using in-line sputter system. The Ag films deposited at temperature above $100^{\circ}C$ in oxygen atmosphere gave a similar specific resistivity to and even lower oxygen content than those deposited using pure Ar sputter gas The Ag films deposited with pure Ar gas was mainly composed of crystallites with [111] preferred orientation, while, for those deposited in oxygen atmosphere, more than 50% of the volume was composed of crystallites with [100] orientation. The difference in the micro structure did not cause any difference in the specific resistivity of Ag films. The results showed that the transparent conducting oxide films and the Ag films could be processed sequentially in the same deposition chamber with careful control of deposition temperature, which might result in a cost reduction for constructing the large scale in-line deposition system.

Study on the Process of Sanguisorbae Radix -Increased Contents of Pomolic Acid and Acetylpomolic Acid by the Process- (지유의 수치에 관한 연구 -수치에 의해 함량이 증가하는 포몰린산과 아세틸포몰린산-)

  • Kang, Tak-Lim;Hwang, Gwi-Seo;Kim, Jong-Moon;Oh, Ji-Yeon;Park, Jeong-Hill;Park, Man-Ki
    • YAKHAK HOEJI
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    • v.38 no.6
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    • pp.782-785
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    • 1994
  • Some traditional herbal drugs have been used after processing to modify its activities. For example, roasted 'chiyu' (Sanguisorbae radix) has been used as antihemorrhagics while raw one used as anti-emetics. The composition of herbal drug is expected to be changed during this process. We tried to reveal the compositional difference between raw and roasted 'chiyu', and isolated the compounds which are changed in their contents. The structure of the isolated compounds were elucidated as pomolic acid and 3-O-acetyl pomolic acid. The contents of pomolic acid and 3-O-acetyl pomolic acid in raw 'chiyu' were ca. $4.5{\times}10^{-3}%$, $7.2{\times}10^{-4}%$, respectively, and in roasted 'chiyu' were ca. $7.3{\times}10^{-3}%$ and $1.1{\times}10^{-3}%$, respectively.

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Preparation and Toughening of Hot-Pressed SiC-AIN Solid Solutions

  • Lim, Chang-Sung
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.224-229
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    • 1999
  • The preparation and toughening of SiC-AIN solid solution from powder mixtures of $\beta$-SiC, AIN and $\alpha$-SiC by hot-pressing were studied in the 1870 to $2030^{\circ}C$ temperature range. The reaction of AIN and $\beta$-SiC(3C) powders causing transformation to the 2H(wurtzite) structure appeared to depend on hot-pressing temperatures and an additive of $\alpha$-SiC. For the composition of 49wt% SiC with 2 wt% $\alpha$-SiC and 47.5 wt% AIN47.5wt% SiC with 5 wt % $\alpha$-SiC at 203$0^{\circ}C$ for 1 h, th complete solid solutions with a single phase of 2H could be obtained. The appreciable amount of $\alpha$-SiC could develop the columnar inter-grains of 4H phase and the stable 2H phase with the relatively uniform composition and grain size distributions. The effect of $\alpha$-SiC on the phases present and compositional microstructures with columnar inter-grains was invetigated using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The fracture toughness and Vickers hardness of the hot-pressed solid solutions wre examined by the indentation-fracture-test method.

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Hierarchical Nanostructure on Glass for Self Cleaning and Antireflective Properties

  • Xiong, Junjie;Das, Sachindra Nath;Kar, Jyoti Prakash;Choi, Ji-Hyuk;Myoung, Jae-Min
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.24.1-24.1
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    • 2010
  • In practical operation, the exposed surfaces may get dirty thus degrade the performance of devices. So the combination of self cleaning and antireflection is very desirable for use in outdoor photovoltaic and displaying devices, self cleaning windows and car windshields. For the purpose of self cleaning, the surface needs to be either superhydrophobic or superhydrophilic. However, in practice AR in the visible region and self cleaning are a pair of competitive properties. To satisfy the requirements for superhydrophobic or superhydrophilic surfaces, high surface roughness is required. But it usually cause severely light scattering. Photo-responsive coatings (TiO2, ZnO etc.) can lead to superhydrophilic. However, the refractive indices are high. Thus for porous structure, controlling pore size in the underwavelength scale to reduce the light scattering is very crucial for highly transparent and self cleaning antireflection coating. Herein, we demonstrate a simple method to make high performance broadband antireflection layer on the glass surface, by "carving" the surface by hot alkali solution. Etched glass has superhydrophilic surface. By chemical modification, it turns to superhydrophobic. Enhanced transparency (up to 97%) in a broad wavelength range was obtained by short time etching. Also antifogging effect has been demonstrated, which may offer advantage for devices working at high humidity environment or underwater. Compositional dependence of the properties was observed by comparing three different commercially available glasses.

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