• Title/Summary/Keyword: Composition gradient

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Effects of Sm:Ba:Cu Composition Ratio on the Superconducting Properties of SmBCO Coated Conductor Prepared by using a Composition Gradient Method (SmBCO 초전도 선재 특성에 대한 Sm:Ba:Cu 조성비의 영향)

  • Kim, H.S.;Oh, S.S.;Jang, S.H.;Min, C.H.;Ha, H.S.;Ha, D.W.;Ko, R.K.;Youm, D.J.;Moon, S.H.;Chung, K.C.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.7-11
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    • 2011
  • The effects of Sm:Ba:Cu composition ratio in SmBCO coated conductor on their superconducting properties were investigated. The SmBCO coated conductors were fabricated by reactive co-evaporation method using EDDC(Evaporation using Drum in Dual Chamber) system. In this system, we could obtain various samples with different composition ratios in a batch by the technique providing composition gradient at deposition zone. From the specimens prepared by EDDC system, we found that composition ratio is uniform parallel to the drum axis, but gradient along the circumferential direction of the drum. We installed a shield having parallelogram open area between the deposition chamber and the evaporation chamber in EDDC system, and attached a 30 cm long template, which is parallel to drum axis, onto the drum surface. In this configuration, we could obtain SmBCO coated conductors having a gradient composition along the length of template. We measured the composition ratios and surface morphologies with periodic interval by SEM and EDAX, and confirmed the profile of composition ratio. We also measured critical current using non-contact Hall probe critical current measurement system and thereby could plot composition ratio vs. critical current. The maximum critical current was obtained, and the surface morphology with the shape of roof tile was observed at the corresponding composition ratio of Sm:Ba:Cu = 1.01:1.99:4.87. It was also found that composition ratio had an effect on not only critical current but also surface morphology.

A Study on Zirconia/Metal.Functionally Gradient Materials by Sintering Method(1) (소결법에 의한 $ZrO_2/Metal$계 경사기능재료에 관한 연구(1))

  • 정연길;최성철
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.321-329
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    • 1994
  • Functionally gradient materials(FGM), which have the continuous or stepwise variation in a composition and microstructure, are being noticed as the material that solves problems caused by heterogeneous interface of coating or joining. And these materials also expect new functions occured by gradient composition itself. Therefore, to examine possibility of thermal barrier materials, TZP/Mo·FGM and TZP/Ni·FGM were fabricated by sintering method. As to the sintered specimens, sintering shrinkage, relative density and Vicker's hardness in each composition were examined. The phenomena due to the difference of sintering shrinkage velocity during sintering process and the thermal stress induced through differences of thermal expansion coefficient in FGM were discussed. And the structure changes at interface and microsturcture of FGM were investigated. As a results, the difference of shrinkage between ceramic and metal was about 14% in TZP/Mo and 7% in TZP/Ni. The relative density and hardness were considerably influenced by metal content changes. Owing to unbalance of sintering shrinkage velocity between ceramic and metal, various sintering defects were occured. To control these sintering defects and thermal stress, gradient composition of FGM should be narrow. The microstructure changes of FGM depended on the ceramic or metal volume percents and were analogous to the theoretical design.

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Effects of Combustion Atmosphere Pressure on Non-premixed Counterflow Flame (비예혼합 대향류 화염에서 연소 분위기 압력 영향 연구)

  • Lee, Kee-Man
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.8
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    • pp.853-862
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    • 2006
  • The present study is numerically investigated the flame structure of non-premixed counterflow jet flames using the laminar flamelet model Detailed flame structures with the fuel composition of 40% CO, 30% $H_2$. 30% $N_2$ and an oxidizer composition of 79% $N_2$ and 21% $O_2$ in a non-premixed counterflow flame are studied numerically. This study is aimed to investigate the effects of axial velocity gradient and combustion atmosphere pressure on flame structure. The results show that the role of axial velocity gradient on combustion processes is globally opposite to that of combustion atmosphere pressure. That is, chemical nonequilibrium effects become dominant with increasing axial velocity gradient, but are suppressed with increasing ambient pressure. Also, the flame strength is globally weakened by the increase of axial velocity gradient but is augmented by the increase of ambient pressure. However, flame extinction is described better on the basis of only chemical reaction and in this study axial velocity gradient and ambient pressure play a similar role conceptually such that the increase of axial velocity gradient and ambient pressure cause flame not to be extinguished and extend the extinction limit, respectively. Consequently it is suggested that a combustion process like flame extinction is mainly influenced by the competition between the radical formation reaction and the third-body recombination reaction.

Development of AlN/Al-Ti Functionally Gradient Materials (AlN/Al-Ti계 경사기능재료의 개발)

  • 이현규;박진성;공창덕
    • Journal of the Korean Society of Propulsion Engineers
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    • v.5 no.1
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    • pp.49-59
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    • 2001
  • Functionally gradient materials(FGMs) generally consist of different material components, such as ceramics and metals. Continuous changes in their composition, microstructure, porositys, and so on result in gradients in the properties of FGMs. In this study AlN/Al-$Al_3$Ti FGM cubes were fabricated by the powder metallurgical process, and the characteristics of the FGMs were investigated. Powders of Mg and Ti mixed with Al in different ratios or the stack of the mixed powders having a stepwisely controlled compositional gradient from one plane to another were formed in a steel mold. The more the composition of Mg and sintering temperature are increased, the more the amount of AlN is formed. AlN and $Al_3$Ti distributed with continuously gradient composition were detected by XRD analysis and also revealed in optical microstructures, and microhardness tests.

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Steep plasma density gradient at middle latitudes observed by DMSP and TOPEX during the magnetic storm of 11-12 April 2001

  • Park, Sa-Rah;Kim, Khan-Hyuk;Kil, Hyo-Sub;Jee, Geon-Hwa;Lee, Dong-Hun;Goldstein, J.
    • Bulletin of the Korean Space Science Society
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    • 2011.04a
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    • pp.26.3-27
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    • 2011
  • Formation of a steep plasma density gradient in the middle-latitude ionosphere during geomagnetic storms and the latitudinal migration of its location depending on the storm phase are suggested to be associated with the ionospheric signature of the plasmapause. We test this idea by using the satellite and ground observation data during the 11 April 2001 storm. The locations of the steep plasma density gradient identified by TOPEX/Poseidon (2001 LT) and DMSP (1800 and 2130 LT) satellites coincide with the ionospheric footprints of the plasmapause identified by the IMAGE satellite. This observation may support the dependence of the middle-latitude plasma density gradient location on the plasmapause motion, but does not explain why the steep density gradient whose morphology is largely different from the morphology of the middle-latitude ionization trough during quiet period is formed in association with the plasmapause. The ionospheric disturbances in the total electron content (TEC) maps shows that the steep TEC gradient is formed at the boundary of the positive ionospheric storm in low-middle latitudes and the negative ionospheric storm in middle-high latitudes. We interpret that the thermospheric neutral composition disturbance in the dayside is confined within the middle-high latitude ionospheric convection zone. The neutral composition latitudes and, therefore, the locations of the steep plasma density gradient coincide with the footprints of the plasmapause. The TEC maps show that the appearance of the steep plasma density gradient in the pre-midnight sector during the recovery phase is related to the co-rotation of the gradient that is created during the main phase.

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Vertical and longitudinal variations in plant communities of drawdown zone of a monsoonal riverine reservoir in South Korea

  • Cho, Hyunsuk;Marrs, Rob H.;Alday, Josu G.;Cho, Kang-Hyun
    • Journal of Ecology and Environment
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    • v.43 no.2
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    • pp.271-281
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    • 2019
  • Background: The plant communities within reservoir drawdown zones are ecologically important as they provide a range of ecosystem services such as stabilizing the shoreline, improving water quality, enhancing biodiversity, and mitigating climate change. The aim of the study was therefore to identify the major environmental factors affecting these plant communities within the drawdown zone of the Soyangho Reservoir in South Korea, which experiences a monsoonal climate, and thereafter to (1) elucidate the plant species responses and (2) compare the soil seedbank composition along main environmental gradients. Results: Two main environmental gradients affecting the plant community structure were identified within the drawdown zone; these were a vertical and longitudinal gradient. On the vertical dimension, a hydrological gradient of flood/exposure, the annual-dominated plant community near the water edge changed to a perennial-dominated community at the highest elevation. On the longitudinal dimension from the dam to the upstream, plant species composition changed from an upland forest-edge community to a lowland riverine community, and this was correlated with slope degree, soil particle size, and soil moisture content. Simultaneously, the composition of the soil seedbank was separated along the vertical gradient of the drawdown zone, with mainly annuals near the water edge and some perennials at higher elevations. The species composition similarity between the seedbank and extant vegetation was greater in the annual communities at low elevation than in the perennial communities at higher elevation. Conclusions: The structures of plant community and soil seedbank in the drawdown zone of a monsoonal riverine reservoir were changed first along the vertical and secondly along the longitudinal gradients. The soil seedbank could play an important role on the vegetation regeneration after the disturbances of flood/exposure in the drawdown zone. These results indicate that it is important to understand the vertical and longitudinal environmental gradients affecting shoreline plant community structure and the role of soil seedbanks on the rapid vegetation regeneration for conserving and restoring the drawdown zone of a monsoonal reservoir.

Ceramic Actuators with PLZT Functionally Gradient Material (PLZT 경사 기능 재료를 이용한 세라믹 엑튜에이터)

  • Choi, Seung-Chul;Kim, Han-Soo;Sohn, Jeong-Ho;Kim, Hyun-Jai;Jeong, Hyeong-Jin
    • Korean Journal of Materials Research
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    • v.1 no.2
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    • pp.105-112
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    • 1991
  • In PLZT system, a new type of material for piezoelectric actuator was developed and its properties were investigated. This material consists of three layers : a piezoelectric ceramic layer, an interlayer which composition changes gradually, and another piezoelectric layer. This kind of materials is called functionally Gradient Materials(FGM). The composition of these layers were selected from the $(Pb,\;La)(Zr,\;TiO_3$ system through the concept of materials design. Sintered FGM at $1300^{\circ}C$, 2hr has an interlayer of about $20\mu\textrm{m}$ with no distorted damage. Dielectric and piezoelectic properties of FGM show intervalues of each side composition. The strain-voltage characteristics in FGM system was improved comparison with any single composition. Especially, the FGMs were fabricated which has high piezoelectric-low dielectric composition and low piezoelectric-high dielectric composition. The properties of both FGMs were significantly improved.

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Composition and interface quality control of AlGaN/GaN heterostructure and their 2DEG transport properties

  • Kee, Bong;Kim, H.J.;Na, H.S.;Kwon, S.Y.;Lim, S.K.;Yoon, Eui-Joon
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.3
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    • pp.81-85
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    • 2000
  • The effects of $NH_3$ flow rate and reactor pressure on Al composition and the interface of AlGaN/GaN heterostructure were studied. Equilibrium partial pressure of Ga and Al over AiGaN alloy was calculated as a function of growth pressure, $NH_3$flow rate and temperature. It was found equilbrium vapor pressure of Al is significantly lower than that of Ga, thus, the alloy composition mainly controlled by Ga partial pressure. We believe that more decomposition of Ga occur at lower $NH_3$ flow rate and higher growth pressure leads to preferred Al incorporation into AlGaN. The alloy composition gradient became larger at AlGaN/GaN heterointerface at higher reactor pressures, higher Al composition and low $NH_3$ flow rate. This composition gradient lowered sheet carrier concentration and electron mobility as well. We obtained an AlGaN/GaN heterostructure with sheet carrier density of ${\sim}2{\times}10^{13}cm^{-2}$ and mobility of 1250 and 5000 $cm^2$/Vs at 300 K and 100 K, respectively.

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Phycobilisome composition in Chondrus crispus (Gigartinales, Rhodophyta) from a wild type strain and its vegetatively derived green mutant

  • Cornish, M. Lynn;O' Leary, Stephen J.B.;Garbary, David J.
    • ALGAE
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    • v.28 no.1
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    • pp.121-129
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    • 2013
  • Intact phycobilisomes from a wild-type red Chondrus crispus and its vegetatively derived green mutant were isolated by centrifugation through a discontinuous sucrose density gradient. Pigment composition was subsequently characterized by spectrophotometry. Vegetative thalli of the two strains grown together for six months in the laboratory resulted in different pigment profiles. Two pigmented phycobilisome bands appeared in the sucrose gradient of the wild-type alga, a purple coloured one, and a pink one, whereas only a single blue band appeared in the gradient of the green mutant. Spectrophotometric and fluorescence analyses identified the phycobiliprotein composition of the purple band as the typical phycoerythrin-phycocyanin-allophycocyanin complement in the wild-type, but there was no detectable phycoerythrin present in the blue band of the green mutant. Sodium dodecyl sulphate, preparative polyacrylamide gel electrophoresis analysis confirmed the presence of allophycocyanin subunits in all extracts, but firm evidence of an R-phycoerythrin linker polypeptide in the blue band was missing. These results highlight the ability of C. crispus to adapt to a phycoerythrin deficiency by adjusting light harvesting pigment ratios.

Carbon and Cobalt Diffusion in Liquid Phase Sintering of WC-Co with Gradient Composition

  • Park, Dong-Kyu;Kim, Ki-Won;Jung, Woo-Hyun
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.635-636
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    • 2006
  • In this study, the diffusion behaviors of C and Co in liquid phase sintering of WC-Co system were investigated whether these two components diffused in the same direction in case of having opposite gradient each other with not being $\eta$ phase. The green compacts with controlled compositions in not being of $\eta$ phase and gradient composition which one is WC-5Co-1.2%C, the other is WC-XCo-0.2%C (where X = 5, 10, 15, 20, 25) were sintered at $1350^{\circ}C$ and $1400^{\circ}C$ and then the diffusion behaviors of C and Co were investigated by analyses of compositional change, also determined for microstructure and microhardness. Also, same testing was carried out on the specimens with dual layers sintered in upright and reverse positions to evaluate the effect of gravity on the diffusion in liquid Co. From the results of this study, we can find the fact that the direction of diffusion for C and Co in WC-Co system during liquid phase sintering was different and the effect of gravity for the liquid was insignificant. Also other physical properties were changed on the diffusion of elements.

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