• Title/Summary/Keyword: Composites Material

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Graft Polymerization of MMA onto Sodium Alginate by Sodium Metaperiodate (메타과요오드산소다에 의한 알긴산소다의 MMA graft 중합)

  • Park, Tchun-Wook
    • Elastomers and Composites
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    • v.14 no.1
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    • pp.7-12
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    • 1979
  • Graft copolymerization of methlymethacrylate(MMA) onto sodium alginate(SA) aqueous solution by sodium metaperiodate$(NaIO_4)$ as an initiator was carried out with the variation of the reaction time, the reaction temperature and the concentrations of initiator and monomer. The results obtained were as follows: 1. SA was easily separated from the reaction mixture of homopolymer, graft polymer and sodium alginate ungrafted by the treatment of concentrated boiling $Na_3PO_4$, solution with the small amount of $Na_2SO_3$ to the mixture and then isolated as the acid form by acidifying the salts solution containing SA. 2. The amount of graft polymer was larger than that of homopolymer below $70^{\circ}C$ whereas above $70^{\circ}C$ the amount of homopolymer was larger. 3. The sum of each amount of graft polymer ana homopolymer was always increased with increase of the reaction time, the reaction temperature and the concentrations of initiator and monomer. 4. With increase of the concentration of initiator, the graft efficiency was increased below $70^{\circ}C$ while decreased above $70^{\circ}C$. 5. Graft copolymerization of MMA onto SA in aqueous solution was carried out without initiator.

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A Study on the Affection of Frequency and Displacement for Nonlinear Viscoelastic Bushing Model (비선형 점탄성 부싱모델에 대한 주파수와 변위의 영향에 대한 연구)

  • Kim, Sung-Jin;Min, Je-Hong;Lee, Seong-Beom
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.334-341
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    • 2003
  • A bushing is a device used in automotive suspension systems to reduce the load transmitted from the wheel to the frame of the vehicle. A bushing is a hollow cylinder, which is bonded to a solid steel shaft at its inner surface and a steel sleeve at its outer surface. The relation between the force applied to the shaft and the relative deformation of a bushing is nonlinear and exhibits features of viscoelasticity. A force-displacement relation for bushings is important for multibody dynamics numerical simulations. For the nonlinear viscoelastic axial response, Pipkin-Rogers model, the direct relation of force and displacement, has been derived from Lianis model and the sinusoidal input was used fer Pipkin-Rogers model, and the affection of displacement with frequency change was studied with Pipkin-Rogers model.

Investigation of Bottom Cracks in the Carbonated Poly(ethylene terephthalate) Bottle

  • Pae, You-Lee;Nah, Chang-Woon;Lyu, Min-Young
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.354-362
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    • 2003
  • The use of a petaloid design for the bottom of carbonated poly(ethylene terephthalate)(PET) bottles is widely spread. This study investigated the causes of bottom cracks. The tensile yield stress variations of PET according to the crystallinity and stretch ratio were examined, then the stretch ratio and strength in the bottom area of a blown bottle were analyzed. A crack test was also performed to observe the cracking phenomena. The distribution of the effective stress and maximum principal stress were both examined using computer simulation to seek the influence of the bottom design on crack. It was concluded that the bottom cracks occurred because of inadequate material strength due to the insufficient stretching of PET, plus the coarse design of a petaloid bottom. The stretch ratio at the bottom during bottle blowing should be higher than the strain hardening point of PET to produce enhanced mechanical strength. The cracks in the bottom of the PET bottles occurred through crazing below the yield stress. The maximum principal stress was higher in the valleys of the petaloid bottom than in the rest bottom area, and the maximum principal stress had a strong effect on the cracks.

Evaluation of Material Properties about CFRP Composite Adapted for Wind Power Blade by using DIC Method (풍력발전기 블레이드 적용 CFRP 복합재료의 DIC 방법에 의한 재료특성치 평가)

  • Kang, J.W.;Kwon, O.H.;Kim, T.K.;Cho, S.J.
    • Journal of Power System Engineering
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    • v.14 no.5
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    • pp.17-23
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    • 2010
  • In recent, the capacity of a commercial wind power has reached the range of 6 MW, with large plants being built world-wide on land and offshore. The rotor blades and the nacelle are exposed to external loads. Wind power system concepts are reviewed, and loadings by wind and gravity as important factors for the mechanical performance of the materials are considered. So, the mechanical properties of fiber composite materials are discussed. Plain woven fabrics Carbon Fiber Reinforced Plastics (CFRP) are advanced materials which combine the characteristics of the light weight, high stiffness, strength and chemical stability. However, Plain woven CFRP composite have a lot of problems, especially delamination, compared with common materials. Therefore, the aim of this work is to estimate the mechanical properties using the tensile specimen and to evaluate strain using the CNF specimen on plain woven CFRP composites. For the strain, we tried to apply to plain woven CFRP using Digital Image Correlation (DIC) method and strain gauge. DIC method can evaluate a strain change so it can predict a location of fracture.

Structural Characteristics of Pultruded Glass Fiber Reinforced Composite Strip (풀투루젼으로 제조한 유리섬유강화 복합소재를 스트립의 구조적 특성)

  • 이성우;신경재
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.10a
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    • pp.11-18
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    • 1999
  • Recently advanced countries are now beginning to use ACM (Advanced Composites Material), which is mostly used in the industry of airplane, ship building and sports equipments, in the construction industry. Compared with existing construction materials, ACM possesses many advantages such as light-weight, high-strength, corrosion resistant property. Among other manufacturing process of ACM, pultrusion is one of the promising one of civil engineering application. In this paper, the structural characteristics of pultruded GFRP strip were studied. Major parameters to influence structural behavior of pultruded GFRP are considered to be fiber volume fraction, die temperature, pulling speed and fiber orientations. The effect of these parameters are studied by experimently and analytically. From this study, it is concluded that fiber volume fraction and fiber orientations influence more on the mechanical property of pultruded GFRP. In addition to above parametric study, off-axis tests were carried out and the results are compared with failure theories. It showed that they agree well each other. Since this study is carried out in limited scope, further research on the reinforcement in the transverse direction, experiment on the compressive strength and research on the durability should be conducted for wide application of pultruded GFRP sections.

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Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion between CFRP and AA7075T6

  • Hur, S.Y.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.19 no.2
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    • pp.75-81
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    • 2020
  • To reduce structural weight, light metals, including aluminum and magnesium alloys, have been widely used in various industries such as aircraft, transportation and automobiles. Recently, composite materials such as Carbon Fiber Reinforced Plastics (CFRP) and Graphite Epoxy Composite Material (GECM) have also been applied. However, aluminum and its alloys suffer corrosion from various factors, which include aggressive ions, pH, solution temperature and galvanic contact by potential difference. Moreover, carbon fiber in CFRP and GECM is a very efficient cathode, and very noble in the galvanic series. Galvanic contact between carbon fiber composites and metals in electrolytes such as rain or seawater, is highly undesirable. Notwithstanding the potentially dangerous effects of chloride and temperature, there is little research on galvanic corrosion according to chloride concentration and temperature. This work focused on the effects of chloride concentration and solution temperature on AA7075T6. The increased galvanic corrosion between CRFP and AA7075T6 was evaluated by electrochemical experiments, and these effects were elucidated.

A Study on Finite Element Analysis and Aging Test for Automotive Grommet (자동차 그로멧의 유한요소해석 및 노화시험에 대한 연구)

  • Lee, Seong-Beom;Yeom, Sang-Hoon;Han, Chang-Yong;Woo, Chang-Su
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.201-209
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    • 2012
  • Grommet is one of the Automotive rubber components and is made from EPDM(Ethylene Propylene Diene monomer M-class) rubber and the nonlinear hyperelastic material properties of rubber are important to predict the behavior of rubber product. In this study, the stable stress-strain relations were obtained from the uni-axial tension test and the equi-biaxial tension test. Finite element analysis for grommet was carried out and heat aging test for the lifetime prediction of grommet was introduced.

The Investigation of Rheological Properties Development for Polymer Matrix Including Foaming Agent

  • Lee, Seung Hak;Kim, Dong Gun;Lim, Sung Wook;Park, Eun Young;Park, Tae Sun;Hyun, Kyu
    • Elastomers and Composites
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    • v.51 no.1
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    • pp.24-30
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    • 2016
  • Sole in the footwear usually modified with foaming agent on the polymer resin to improve the lightweightness and crush-cushion effect. In this study, we investigated rheological properties for polymer resin filled with the different type and concentration of foaming agent, capsule type foaming agent and organo-chemical foaming agent, under the time sweep test. Curing times of each polymer resin with different kind of foaming agent are delayed than reference material (epoxy resin with curing agent). In case of adding capsule type foaming agent, however, there is appropriate concentration to reduce the curing time, relatively. When foaming agent is activated, foaming force inflates the sample in contrast to condensation force of curing and then axial normal force develop to the (+) direction. Interestingly, by increase concentration of foaming agent, there is a specific point to break down the axial normal force development. The reason for this phenomenon is that coalescence of foams induce the blocking of axial normal force development.

Multiphase Simulation of Rubber and Air in the Cavity of Mold

  • Woo, Jeong Woo;Yang, Kyung Mi;Lyu, Min-Young
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.263-268
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    • 2016
  • In the polymer shaping process that uses molds, the quality of the molded products is determined not only by the flow of the (molten) polymer but also by the air venting in the cavity. Inadequate air venting in the cavity can cause defects in the product, such as voids, short shot, or black streaks. As it is critical to consider the location and size of the vents for proper venting of the air in the cavity, a method that predicts the flow of air and material is required. The venting of air by the flow of rubber inside the cavity was simulated by using a multi-phase computational fluid dynamics method. Through computer simulation, the interface of rubber and air over time was predicted. Then, the velocity and pressure distribution of the venting air were observed. Our research proposes a fundamental method for analyzing the multi-phase flow of polymer materials and air inside the cavity of a mold.

Optimal Design of FRP Taper Spring Using Response Surface Analysis (반응표면분석법을 이용한 FRP Leaf Spring의 최적설계)

  • 임동진;이윤기;김민호;윤희석
    • Composites Research
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    • v.17 no.2
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    • pp.1-8
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    • 2004
  • The present paper is concerned with the optimum design of taper spring, in which the static spring rate of the fiber-reinforcement composite material spring is fitted to that of the steel leaf spring. The thickness and width of springs were selected as design variables. The object functions of the regression model were obtained through the analysis with a common analytic program. After regression coefficients were calculated to get functions of the regression model, optimal solutions were calculated with DOT. E-glass/epoxy and carbon/epoxy were used as fiber reinforcement materials in the design, which were compared and analyzed with the steel leaf spring. The result of the static spring rates show that optimized composite leaf springs agree with steel leaf spring within 1%.