• Title/Summary/Keyword: Composites Material

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Effects of salt water environment on the mechanical behavior of composites (복합재료의 기계적 거동에 염수환경이 미치는 영향에 관한 연구)

  • Moon, Jin-Bum;Kim, Soo-Hyun;Kim, Chun-Gon
    • Composites Research
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    • v.23 no.1
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    • pp.44-50
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    • 2010
  • In this paper, two different experiments, namely, salt water spray and salt water immersion, were performed to reproduce the contact of composites with the seawater for three kinds of woven fabric composite material systems which would be used for the WIG(wing in ground effect)craft. After aging 140 days in the salt water environment, material properties of carbon/epoxy and glass/epoxy composite such as tensile, compressive and shear stiffness and strength, and inter-laminar shear strength (ILSS) were measured. By comparing baseline material properties with degraded ones, the effects of the salt water environment on the composite mechanical properties were evaluated. From the experiments, it was confirmed that the difference in aging conditions had very small influence on composite properties. And it was found that tensile strength of carbon/epoxy composites showed little degradation, but much more degradation was observed in glass/epoxy composites. And large degradations on matrix dominant properties were observed. The salt water could damage the fiber-matrix interface, matrix properties and the glass fiber.

Electrical Resistivity of Natural Graphite/Polymer Composite based Bipolar Plates for Phosphoric Acid Fuel Cells by Addition of Carbon Black (카본블랙 첨가량에 따른 인산형 연료전지(PAFC) 분리판용 천연흑연-고분자복합재료의 전기비저항)

  • Kim, Hyo-Chang;Lee, Sang-Min;Nam, Gibeop;Roh, Jae-Seung
    • Korean Journal of Materials Research
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    • v.30 no.10
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    • pp.522-532
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    • 2020
  • Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/㎤, which is 0.017 g/㎤ less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.

Study of transfer film in the sliding of nanoscale CuO-filled and fiber-reinforced polyphenylene sulfide (PPS) composites (CuO nanoparticle 및 fiber 로 구성된 PPS 복합재료의 sliding 조건하의 transfer film 에관한 연구)

  • Cho, Min-Haeng;Bahadur, Shyam;Park, Hye-Young;Kim, Yoon-Jun
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.967-972
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    • 2004
  • The role of transfer films formed during sliding of polymer composites against steel counterfaces was studied in terms of the tribological behaviors of composites. Four kinds of composites were included in this study: (1) unfilled PPS, (2) PPS+2%CuO, (3) PPS+2%CuO+5% carbon fiber (CF), and (4) PPS+2%CuO+15%Kevlar. The filler material CuO was in nanoscale particulate form and the reinforcing material was in the form of short fibers. The composites were prepared by compression molding at $310^{\circ}C$ and sliding tests were run in the pin-on-disk sliding configuration. The counterface was made of tool steel hardened to 55-60 HRC and finished to a surface roughness of 0.09-0.10 ${\mu}m$ Ra. Wear tests were run for 6 hrs at the sliding speed of 1 m/s and contact pressure of 0.65 MPa. Transfer films formed on the counterfaces during sliding were investigated using AFM and SEM. The results showed that as the transfer film became smooth and uniform, wear rate decreased. PPS+2%CuO+15%Kevlar composite showed the lowest steady state wear rate in this study and its transfer film showed the smoothest and the most uniform characteristics. The examination of worn surfaces of PPS+2%CuO composite using X-ray area scanning (dot mapping) showed back-transfer of steel counterface material to the polymer pin surface. This behavior is believed to strengthen the polymer pin surface during sliding thereby contributing to the decrease in wear rate.

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Synthesis of Si-CNT-C Composites and Their Application to Lithium Ion Battery (실리콘-탄소나노튜브-탄소 복합체 제조 및 리튬이온전지 응용)

  • Kim, Chan Mi;Kim, Sun Kyung;Chang, Hankwon;Kil, Dae sup;Jang, Hee Dong
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.42-48
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    • 2018
  • Silicon has attracted extensive attention due to its high theoretical capacity, low discharge potential and non-toxicity as anode material for lithium ion batteries. In this study, Si-CNT-C composites were fabricated for use as a high-efficiency anode material in a lithium ion battery. Aerosol self-assembly and post-heat treatment processes were employed to fabricate the composites. The morphology of the Si-CNT-C composites was spherical and an average particle size was $2.72{\mu}m$. The size of the composite increased as concentration of Si and CNT increased in the precursor solution. In the Si-CNT-C composites, CNT and C carbonized from glucose were attached to the surface of Si particles. Electrochemical measurement showed that the cycle performance of Si-CNT-C composites was better than that of silicon particles.

Experimental Study on the Improvement of Workability of Cementitious Composites Using Nano-bubble Water (나노버블수를 활용한 시멘트 복합체의 작업성 증진에 대한 실험적 연구)

  • Lee, Nankyoung;Kang, Sung-Hoon;Moon, Juhyuk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.27-32
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    • 2021
  • This study was conducted to improve the workability of cementitious composites using nano-bubble water. The used nano-bubble water contains 7% of nano-sized bubbles with an averaged bubble size of 750 nm. Various different types of cementitious composites including ultar-high performance concrete, lightweight cementitious composites, and high-strength mortar have been tested to identify the changes of material properties. From the use of nano-bubble water, it was confirmed that workability has been improved by 3-22%. On the other hand, other material characteristics such as compressive strength did not have noticeable changes. Therefore, it was proposed that the use of nano-bubble water can enhance workability of cementitious composites without having significant impact on other material properties.

Multiscale Stress Analysis of Palladium/Carbon Fiber Composites for the Hydrogen High Pressure Vessel (수소고압저장용기용 팔라듐 첨가 탄소섬유복합재에 대한 멀티스케일 응력해석)

  • Park, Woo Rim;Kwon, Oh Heon
    • Journal of the Korean Society of Safety
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    • v.33 no.2
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    • pp.1-7
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    • 2018
  • The multi-scale analysis is more proper and precise for composite materials because of considering the individual microscopic structure and properties of each material for composite materials. The purpose of this study is to verify the validity of using palladium particles in carbon/fiber composites by multi-scale analysis. The palladium is a material for itself to detect leaking hydrogen by using the property of adsorbing hydrogen. The macroscopic model material properties used in this study are homogeneous material properties from microstructure. Homogenized material properties that are calculated from periodic boundary conditions in the microscopic representative volume element model of each macroscopic analysis model. In this study, three macroscopic models were used : carbon fiber/epoxy, carbon fiber/palladium, palladium/epoxy. As a result, adding palladium to carbon/epoxy composite is not a problem in terms of strength.

Sawdust reinforced polybenzoxazine composites: Thermal and structural properties

  • Garigipati, Ravi Krishna Swami;Malkapuram, Ramakrishna
    • Advances in materials Research
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    • v.9 no.4
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    • pp.311-321
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    • 2020
  • In this study, Mangifera Indica tree sawdust reinforced bisphenol-A aniline based benzoxazine composites were prepared by varying the sawdust from 20 wt% to 45 wt%. Thermogravimetric analysis of composites revealed excellent compatibility between polybenzoxazine and sawdust from the remarkable growth in char yield from 22% (neat resin) to 36% (for highly filled) and glass transition temperature from 151 to 165℃. Ultimate weight loss of the composites evaluated from the Derivatives of TG plots. Limiting oxygen index values of the composites reported considerable growth i.e.,from 28 to 32 along with the increase in filler content. Differential scanning calorimetry results showed that sawdust particles have an insignificant effect on curing temperature (219℃) for the raise in sawdust content. Structure of the sawdust, benzoxazine monomer, polybenzoxazine and composites were studied using Fourier transformation infrared spectroscopy. Overall, polybenzoxazine composites with sawdust as filler showed improved thermal properties when compared with pure polybenzoxazine.

Development of Seismic Performance Evaluation Reinforcement by FRP and Ductile Material Layered Composites (섬유강화플라스틱과 연성재 적층복합체로 구성된 내진성능보강재의 개발)

  • Chang, Chun-Ho;Jang, Kwang-Seok;Kim, Ki-Hong;Joo, Chi-Hong
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.1486-1491
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    • 2010
  • Recently, the frequency and magnitude of the earthquake have increased. The structural safety of the public facilities such as bridges and tunnels etc. which were not concerned for earthquake resistant design are increased. Fiber reinforcement polymer that has been frequently studied for seismic retrofit has advantage as seismic reinforcement material, but it has disadvantage of the brittleness. Therefore, the investigation of safety and seismic reinforcement are required. In this study, new FRP-ductile material layered composites proposed to seismic performance reinforced of subway tunnel. Tensile test of FRP-ductile material layered composites showed that Maximum tensile force of FRP-ductile using Aluminum is similar to existing FRP reinforcement material and maximum strain was increased. In case of application of domestic subway tunnel which need ductility, layered composites of FRP-Aluminum is estimated effectively for increase of seismic performance.

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Ceramic-Ceramic Wear of Zirconia/Alumina Composites for the Application of Total Hip Replacement (인공 고관절 골두용 세라믹 복합재료에 대한 세라믹-세라믹 접촉 마멸 특성 분석)

  • Lee Kwon-Yong;Kim Hwan;Kim Dae-Jun;Lee Myong-Hyon;Seo Won-Seon
    • Tribology and Lubricants
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    • v.21 no.5
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    • pp.216-220
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    • 2005
  • The sliding wear behaviors of three different compositions of novel low temperature degradation-free zirconia/alumina (LTD-free Z/A) composites were examined in a ceramic-ceramic contact pair. The wear tests were performed by using a pin-on-disk type wear tester in a linear reciprocal sliding motion with a line contact in both dry and bovine serum lubricated conditions at room temperature. From the results of dry sliding wear tests, Z/A#1((5.3Y, 4.6Nb)-TZP/80 $vol\%Al_2O_3$) showed the best wear resistance among three kinds of LTD-free Z/A composites. For the bovine serum lubricated sliding wear tests, wear was too little to be measured for all kinds of Z/A composites. These novel LTD-free Z/A composites having excellent wear resistance demonstrated a potential as the alternative materials for the ceramic-ceramic contact pairs of femoral head and acetabular liner in total hip replacement.

Nondestructive Evaluation in the Defects of FRP Composites By Using Terahertz Waves (테라헤르츠파를 이용한 FRP 복합재료의 비파괴결함평가)

  • Im, Kwang-Hee;Kim, Ji-Hoon;Hsu, David K.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.2
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    • pp.252-258
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    • 2012
  • A study of terahertz waves was made for the nondestructive evaluation of FRP (Fiber reinforced plastics) composite materials. The terahertz systems were consisted of time domain spectroscopy (TDS) and continuous wave (CW). The composite materials investigated include both non-conducting polymeric composites and conducting carbon fiber composites. Terahertz signals in the TDS mode resembles that of ultrasound; however, unlike ultrasound, a terahertz pulse was not able to detect a material with conductivity. The CFRP (Carbon fiber reinforced plastics) laminates were utilized for confirming the experimentation in the terahertz NDE. In carbon composites the penetration of terahertz waves is quite limited and the detection of flaws is strongly affected by the angle between the electric field direction of the terahertz waves and the intervening fiber directions. A refractive index (n) was defined as one of mechanical properties; so a method was obtained in order solve the "n" in the material with non-conductivity. The usefulness and limitations of terahertz radiation are investigated for the NDE of FRP composites.