• 한국응용과학기술학회지
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• 제22권2호
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• pp.96-105
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• 2005

Core-shell polymers of methyl methacrylate-styrene system were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) in an initiator and the characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, whereas polymer blends or copolymers show a combined physical properties of two homopolymers. This unique behavior of core-shell composite latex can be used in various industrial fields. However, in preparation of core-shell composite latex, several unexpected matters are observed, for examples, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve this matters, we study the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the core-shell structure of PMMA-PSt and PSt-PMMA. Particle size and particles distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass temperature was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions was measured.

• 폴리머
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• 제25권5호
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• pp.617-624
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• 2001

음이온계 유화제를 사용하여 monomer pre-emulsion을 제조한 다음 ammonium persulfate를 개시제로 하여 단계 중합법에 의해 새로운 입자의 생성이 적고 중합 과정에서 안정성이 우수한 poly(methyl methacrylate)(PMMA)/polystyrene (PSt) 라텍스를 제조하였다. 본 연구에서는 shell 중합시에 새로운 입자의 생성이 적고 중합 중 안정성이 우수한 라텍스를 제조하기 위해 개시제농도, 유화제농도, 중합온도가 PMMA/PSt와 PSt/PMMA의 core-shell 구조에 미치는 영향을 알아보았다. 중합한 라텍스를 입도분석기 (particle size analyzer: PSA) 및 투과전자현미경(transmission electron microscope; TEM)을 이용하여 실제 입자측정과 입자형태 특성을 확인하였으며 시차주사열량계 (differential scanning calorimeter, DSC)를 이용하여 유리전이온도($T_g$)의 측정, 필름 조막성 (minimum film formation temperature: MFFT), NaOH 첨가에 의한 가수 분해에 따르는 pH를 측정하여 core-shell의 또 다른 특성을 확인하였다.

• 복합신소재구조학회 논문집
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• 제3권2호
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• pp.47-54
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• 2012

In this study, composite laminate cantilever type cylindrical shells with edge-stiffeners are analyzed. A versatile 4-node flat shell element which is useful for the analysis of shell structures is used. An improved flat shell element is established by the combined use of the addition of non-conforming displacement modes and the substitute shear strain fields. Two models by load conditions are considered. Load type A and B are loaded by point load at the free edge and line load respectively. A various parameter examples are presented to obtain proper stiffened length and stiffened thickness of edge-stiffeners. It is shown that the thickness of shell can be reduced minimum 30% by appropriate edge-stiffeners.

• Journal of Mechanical Science and Technology
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• 제14권6호
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• pp.666-674
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• 2000

Large deflection dynamic responses of laminated composite cylindrical shells under impact are analyzed by the geometrically nonlinear finite element method based on a generalized Sander's shell theory with the first order transverse shear deformation and the von-Karman large deflection assumption. A modified indentation law with inelastic indentation is employed for the contact force. The nonlinear finite element equations of motion of shell and an impactor along with the contact laws are solved numerically using Newmark's time marching integration scheme in conjunction with Akay type successive iteration in each step. The ply failure region of the laminated shell is estimated using the Tsai- Wu quadratic interaction criteria. Numerical results, including the contact force histories, deflections and strains are presented and compared with the ones by linear analysis. The effect of the radius of curvature on the composite shell behaviors is investigated and discussed.

• 접착 및 계면
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• 제12권1호
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• pp.16-25
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• 2011

Core 입자로 methyl methacrylate (MMA), n-butyl methacrylate (BMA)를 하고 shell 입자로 MMA, BMA, stylene (St), 2-hydroxylethylmethacrylate (2-HEMA), acrylic acid (AA)를 각각 사용하여 개시제 aommonium persulfate (APS), 유화제로 sodium dodecyl benzene sulfonate (SDBS)의 농도(0.01~0.03 wt%), 단량체의 종류와 조성을 변화시켜 수용성 유화중합으로 다중 core-shell 복합입자를 제조하여 전화율, 입자경 및 입도 분포, 평균 분자량, 분자구조, 유리전이온도, 입자의 형태 및 인장강도와 신율을 각각 측정하여 다음과 같은 결론을 얻었다. SDBS 농도 0.02 wt%에서 MMA core-(BMA/St/AA) shell 복합인자가 전화율이 98%로 우수하였고, 입자 직경은 SDBS 농도 0.03 wt%에서 BMA core-(MMA/St/AA) shell의 복합입자가 $0.47{\mu}m$로 높게 나왔다. 유리전이온도 측정은 단일 core-shell 복합입자의 2군데에 비하여 다중 core-shell 복합입자는 3군데가 존재하여 shell단량체 내의 단량체의 종류와 조성에 따라 유리전이온도 조절도 가능하고 동시에 접착력이 향상된 접착소재로서 부직포 섬유 결속제로 사용될 수 있었다.

• Elastomers and Composites
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• 제37권1호
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• pp.21-30
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• 2002

개시제 ammonium persulfate(APS)와 유화제 sodium dodecyl benzene sulfonate(SDBS)를 이용하여 methyl methacrylate(MMA), styrene(St), ethyl acrylate(EA)등의 단량체를 core(내부)와 shell(외부)의 폴리머성분이 다른 core-shell 폴리머를 합성하고 각 core-shell 폴리머에 대한 구조를 연구하였다. 한 입자의 내부와 외부의 고분자 조성이 다른 composite 라텍스는 고분자 블렌딩과 공중합의 물성과는 달리 한 입자 내에서도 상반된 두 가지 물성을 동시에 나타내는 특성으로 인하여 여러 산업 분야에 응용이 가능하다. 그러나, core-shell 라텍스를 제조할 때 반응중입자가 성장하는 과정에서 입자의 응집과 중합율이 떨어지고, 라텍스의 응용시 기계적 안정성이 문제점으로 되고 있다. 따라서 shell 중합시에 새로운 입자의 생성이 적고 중합중 안정성이 우수한 라텍스를 제조하기 위해 유화제농도, 개시제농도, 중합온도가 PMMA/PSt과 PSt/PMMA의 core-shell 구조에 미치는 영향과 중합 후 입도분석기(particle size analyzer; PSA) 및 투과전자현미경(transmission electron microscope; TEM)을 이용하여 실제 입자측정과 입자형태 특성을 확인하였으며 시차주사열량계(differential scanning calorimeter, DSC)를 이용하여 유리전이온도($T_g$)의 측정, 최저성막온도(minimum film formation temperature; MFFT), NaOH 첨가에 의한 가수 분해에 따르는 pH를 측정하여 core-shell의 새로운 특성을 확인하였다.

• 접착 및 계면
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• 제14권1호
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• pp.1-12
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• 2013

Core 입자로 methyl methacrylate (MMA), ethyl methacrylate (EMA)를 사용하고 shell 입자로 MMA, EMA, 2-hydroxyl ethyl methacrylate (2-HEMA), glycidyl methacrylate (GMA) 및 methacrylic acid (MAA)를 각각 사용하여 개시제 ammonium persulfate (APS), 유화제로 sodium dodecyl benzene sulfonate (SDBS)의 농도(0.01~0.03 wt%), 단량체의 종류와 조성을 변화시켜 수용성 유화중합으로 다중 core-shell복합입자를 제조하여 전환율, 입자경 및 입도분포, 평균분자량, 분자구조, 유리전이온도, 플라즈마 처리후의 접촉각, 등온열분해속도 및 인장강도를 각각 측정하여 다음과 같은 결론을 얻었다. SDBS 농도 0.02 wt%에서 MMA core-(EMA/GMA) shell 복합입자의 전환율이 98.5%로 우수하였고, 입자직경은 SDBS 농도 0.03 wt%에서 EMA core-(MMA/GMA) shell의 복합입자가 $0.48{\mu}m$로 높게 나왔다. 유리전이온도 측정으로부터 공중합체는 1~2개의 전이곡선 그리고 다중 core-shell 복합입자는 3개의 전이곡선을 얻었다. 전체적으로 접착박리강도의 크기는 shell 단량체가 MMA core인 경우 EMA/MAA > EMA/2-HEMA > EMA/GMA의 순으로 되었다.

• Steel and Composite Structures
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• 제51권5호
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• pp.543-562
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• 2024

While the external axial compressive load is applied to only the shell edge of stringer-stiffened shell in the most of numerical and analytical previous studies (entitled as conventional approach), a part of external load is applied to the stringers in real conditions. It leads to decrease the accuracy of the axial buckling load calculated by the conventional eigenvalue analysis approach performed in the most of previous studies. In this study, the distribution of stress in the pre-buckling analysis was enhanced by applying the axial external compressive load to both shell and stringers to perform an accurate eigenvalue analysis of the stringer-stiffened composite shell. In this regard, a model was developed in FORTRAN environment to simulate the laminated stringer-stiffened shell under axial compressive load using finite strip method. The axial buckling load of the shell was obtained through eigenvalue analysis. A comparison was made between the results obtained from the model and those available in the previous studies to evaluate the validity of the results obtained from the model. Through a parametric study, the effects of different parameters such as stringer properties and composite layup on the buckling load of the shell under different loading patterns were investigated. The results indicated that in some cases, the axial buckling load obtained for the conventional approach used in the most of previous studies is significantly overestimated or underestimated due to neglecting the stringer in distribution of external load applied to the stringer-stiffened shell. According to the results obtained from the parametric study, some graphs were derived to show the accuracy of the axial buckling load obtained from the conventional approach utilized in the literature.

• Steel and Composite Structures
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• 제27권5호
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• pp.555-566
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• 2018

A 1/3 composite cylindrical shell with a central rectangular opening was axially compressed experimentally, and its critical buckling load and displacement, and strains were measured. A finite element model (FEM) of the shell with Hashin failure criteria was established to analyze its buckling and post-buckling behaviors by nonlinear Newton-Raphson method. The geometric imperfection sensitivity and the effect of side supported conditions of the shell were investigated. It was found that the Newton-Raphson method can be used to analyze the buckling and post-buckling behaviors of the shell. The shell is not sensitive to initial geometric imperfection. And the support design of the shell by side stiffeners is a good way to obtain the critical buckling load and simplify the experimental fixture.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 추계학술발표대회 논문집
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• pp.69-72
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• 2004

A new three-node triangular shell element based on higher order zig-zag theory is developed for laminated composite shells with multiple delaminations. The present higher order zig-zag shell theory is described in a general curvilinear coordinate system and in general tensor notation. All the complicated curvatures of surface including twisting curvatures can be described in an exact manner in the present shell element because this element is based on geometrically exact surface representation. The displacement field of the proposed finite element includes slope of deflection, which requires continuity between element interfaces. Thus the nonconforming shape function of Specht's three-node triangular plate bending element is employed to interpolate out-of-plane displacement. The present element passes the bending and twisting patch tests in flat surface configurations. The developed element is evaluated through the eigenvalue problems of composite cylindrical shells with multiple delaminations. Through the numerical examples it is demonstrated that the proposed shell element is efficient because it has minimal degrees of freedom per node. The present shell element should serve as a powerful tool in the prediction of natural frequency and modes of multi-layered thick laminated shell structures with arbitrary-shaped multiple delaminations.