• Title/Summary/Keyword: Complex impedance

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Electrochemical Properties of 0.3Li2MnO3·0.7LiMn0.55Ni0.30Co0.15O2 Electrode Containing VGCF for Lithium Ion Battery

  • Kim, Jeong-Min;Jeong, Minchan;Jin, Bong-Soo;Kim, Hyun-Soo
    • Journal of Electrochemical Science and Technology
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    • v.5 no.1
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    • pp.32-36
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    • 2014
  • The $0.3Li_2MnO_3{\cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material was prepared via a co-precipitation method. The vapor grown carbon fiber (VGCF) was used as a conductive material and its effects on electrochemical properties of the $0.3Li_2MnO_3{\cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material were investigated. From the XRD pattern, the typical complex layered structure was confirmed and a solid solution between $Li_2MnO_3$ and $LiMO_2$ (M = Ni, Co and Mn) was formed without any secondary phases. The VGCF was properly distributed between cathode materials and conductive sources by a FE-SEM. In voltage profiles, the electrode with VGCF showed higher discharge capacity than the pristine electrode. At a 5C rate, 146 mAh/g was obtained compared with 232 mAh/g at initial discharge in the electrode with VGCF. Furthermore, the impedance of the electrode with VGCF did not changed much around $9-10{\Omega}$ while the pristine electrode increased from 21.5${\Omega}$ to $46.3{\Omega}$ after the $30^{th}$ charge/discharge cycling.

Design of Low-Power Hybrid LNA with Multi-Input for Mobile Ultrasound System (이동형 초음파시스템에 적합한 다중 입력방식의 저전력 혼성 저잡음 증폭기 설계)

  • Song, Jae-Yeol;Lee, Kyung-Hoon;Park, Sung-Mo
    • Journal of the Institute of Convergence Signal Processing
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    • v.15 no.2
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    • pp.64-69
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    • 2014
  • Ultrasound system is one of the complex wireless signal processing systems that are widely used in the fields of modern industry such as medical diagnostics, underwater communications, and sensor-networks. Miniaturization of ultrasound system has been raging recently. In this paper, a hybrid LNA that is suitable for miniaturization and mobile diagnostic ultrasound system has been developed. The proposed LNA has low noise figure of less than 5dB, and the feedback resistor is designed to be electrically adjusted in order to attain the impedance-matching for various ultrasound transducers. It supports the whole ultrasound frequencies from 10KHz to 150MHz frequency band and also provides sleep modes. A gain from -18.8 to -29.5 dB is achieved by adjusting each transducer to fit the system character. Power consumption can be reduced up to 90% in similar performance as compared to the existing LNA.

Polarization Resistance of (Ba0.5Sr0.5)0.99Co0.8Fe0.2O3-δ Air Electrode Synthesized by Glycine-Nitrate Process (Glycine-Nitrate 법으로 제조한 (Ba0.5Sr0.5)0.99Co0.8Fe0.2O3-δ 공기극의 분극저항)

  • Moon, Ji-Woong;Lim, Yong-Ho;Oh, You-Keun;Lee, Mi-Jai;Choi, Byung-Hyun;Hwang, Hae-Jin
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.800-807
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    • 2005
  • Cathode material, $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-\delta}$, for low temperature SOFC was prepared by the Glycine-Nitrate synthesis Process (GNP). Characteristics of the synthesized powders were studied with controlling the pH of a precursor solution. Highly acidic precursor solution increased a perovskite forming temperature. It is considered that Ba and Sr cannot complex by carboxylic acid group of glycine, because under highly acidic condition the caboxylic group mainly combined with H+ insead of alkaline earth cations. A lack of bond between cations and glycine resulted in selective precipitation of the elements during evaporation of the precursor solution. In case of using precursor solution with pH %2\~3$, a single perovskite phase was obtained at $1000^{\circ}C$. Polarization resistance of $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-\delta}$ was measured by AC impedance spectroscopy from the two electrode symmetric cell. Area specific resistance of the $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-\delta}$ air electrode at $500^{\circ}C\;and\;600^{\circ}C$ were $0.96{\Omega}{\cdot}cm^2\;and\;0.16{\Omega}{\cdot}cm^2$, respectively.

Effect of M2O3 on the Sinterbility and Electrical Conductivity of ZrO2(Y2O3) System(III) : Ceramics of the ZrO2-Y2O3-Ln2O3 System (ZrO2(Y2O3)계 세라믹스의 소결성과 전기전도도에 대한 M2O3의 영향(III) : ZrO2-Y2O3-Ln2O3계 세라믹스)

  • 오영제;정형진;이희수
    • Journal of the Korean Ceramic Society
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    • v.24 no.2
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    • pp.123-132
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    • 1987
  • Yttria-stabilized zirconia with erbia-lanthana were investigated with respect to the amount of Ln2O3 (Ln; Er, La) addition in the range of 0.5∼5 mol% to the base composition of 8 mol% yttriazirconia. Following analysis and measurement were adopted for the characterization of synthesizes of solid electrolyte; phase transformation, lattice parameter, crystallite size, relative density, chemical composition and SEM/EDS. Electrical conductivity by two-probe method versus temperature from 350$^{\circ}C$ to 800$^{\circ}C$ and frequency in the range of 5Hz∼13MHz by complex impedance method was also conducted together with the determination of oxygen ion transference number by EMF method for the evaluation of their electrical properties. The results were as followsing; Electrical conductivity were decreased with increase in Ln2O3 content, but their activation energies increased. In the case of La2O3 addition, espicially, its electrical conductivity was decreased owing to the segregation of second phases at the grain-boundary. Grain-boundary conductivity of the specimen contained 0.5 mol% Er2O3 exhibited a maximum conductivity among thecompositions experimented. However, their bulk conductivities decreased in both case. Oxygen ion transference number was also reduced with decrease in oxygen partial pressure. For example, in the case of Er2O3 addition it retained value in the range of 0.97∼0.94 abvove 4.74${\times}$10-2in oxygen partial pressure. With the increase in the quantities of the evaporation of additive components, the crystallite size of stabilized zirconia decreased, and their relative density also reduced owing to the formation of porosity in their matrices. In the case of La2O3 the sinterbility was improved in the limited amount of addition up to 0.5 mol%, in the same range of addition the strength of sintered bodies were improved perhaps owing to the precipitation of metastable tetragonal phase in the fully stabilized zirconia.

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Effect of Salt Concentration on the Glass Transition Temperature and Ionic Conductivity of Poly(ethylene glycol)-Polyurethane/$LiClO_4$ Complexes

  • Huh, Pil-Ho;Park, Myung-Geun;Jo, Nam-Ju;Lee, Jin-Kook;Lee, Jang-Oo;Wongkang Yang
    • Macromolecular Research
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    • v.12 no.4
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    • pp.422-426
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    • 2004
  • Solid polymer electrolytes based on poly(ethylene glycol)-polyurethane (PEG-PU) complexed with LiClO$_4$ salt have been prepared by the solvent casting method. A PEG-PU material (PEG:4,4'-diphenylmethane diisocyanate: l,4-butanediol = 1:2:1) was synthesized through a typical two-step condensation reaction. We investigated the effects of the salt concentration on the ionic conductivity ($\sigma$) and the glass transition temperature (T$_{g}$ ) of the complex electrolytes by using alternating current impedance spectroscopy, differential scanning calorimetry, and dynamic mechanical thermal analysis. The measured values of both $\sigma$ and T$_{g}$ exhibited similar tendencies in that they had maxima within the range studied, probably because of two opposite effects, i.e., the increased number of carrier ions and the decreased chain mobility (or increased T$_{g}$ ) caused by the increase in the salt concentration. The highest conductivity, on the order of 2.43 ${\times}$ 10$^{6}$ S$cm^{-1}$ /, was obtained at an [O]/[Li$^{+}$] ratio of ca. 16 (0.92 ㏖ salt per kg of matrix polymer).

A Persistence Framework Based SQL (SQL 기반 퍼시스턴스 프레임워크)

  • Cho, Dongil-Il;Rhew, Sung-Yul
    • The KIPS Transactions:PartD
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    • v.15D no.4
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    • pp.549-556
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    • 2008
  • Web-based Enterprise Intranet System is developed Object-oriented programming language and data management is constructed using RDBMS. Between Object-oriented programming language and RDBMS bring about "Object-Relational Impedance Mismatch" due to heterogeneous paradigm. To solve this kinds of problems commonly use the ORM Framework that it is converting data between incompatible type systems in databases and object-oriented programming languages, uses complex mapping metadata. It causes difficult to develop and maintain because of inflexible in changes. This paper proposed persistence framework that solve the existing complexity of ORM framework and has more flexible in evolution of database table. This persistence framework is unnecessary meta information that connecting with entity of database table and the objects, it offers users convenience of maintenance and it allows far more flexible and affordable systems to be built because of automatically code generation. The result of testing based on the proposed persistence framework with Hibernate, iBATIS, It is similar response time with iBATIS and it has more about three times faster than Hibernate. But iBATIS has problems of mass data processing.

A Filter Synthesis Method without Bandwidth Reduction for Dual-Band Filters Based on Coupled Lines (결합 선로 이중 대역 필터의 대역폭이 줄지 않는 설계 방법)

  • Lee, Seung-Ku;Ha, Jung-Je;Lee, Yong-Shik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.3
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    • pp.245-252
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    • 2010
  • This paper proposes an improved filter synthesis method for dual-band filters based on coupled lines loaded with shunt stubs. The conventional design method relies on equality of the response of the conventional single-band filter and its dual-band counterpart at two frequencies. On the other hand, the proposed method is based on equivalence of the propagation constants and the image impedances of the two filters. Therefore, the proposed method does not suffer from bandwidth reduction phenomena, which requires complex compensating process in the conventional method. Also, the alternative design parameters provided by the demonstrated method enable to construct dual-band filters with more flexibility. For experimental verification, a Chebyshev type dual-band filter with center frequencies at 1 GHz and 3.5 GHz is designed and fabricated. The measured results are in excellent agreement with the full-wave simulated results.

A Study on Distance Relay of Transmission UPFC Using Artificial Neural Network (신경회로망을 이용한 UPFC가 연계된 송전선로의 거리계전기에 관한 연구)

  • Lee, Jun-Kyong;Park, Jeong-Ho;Lee, Seung-Hyuk;Kim, Jin-O
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.6
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    • pp.37-44
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    • 2004
  • This paper represents a new approach for the protective relay of power transmission lines using a Artificial Neural Network(ANN). A different fault m transmission lines need to be detected classified and located accurately and cleared as fast as possible. However, The protection range of the distance relay is always designed on the basis of fixed settings, and unfortunately these approach do not have the ability to adapt dynamically to the system operating condition. ANN is suitable for the adaptive relaying and the detection of complex faults. The backpropagation algerian based multi-layer protection is utilized for the teaming process. It allows to make control to various protection functions. As expected, the simulation result demonstrate that this approach is useful and satisfactory.

Properties of Synthesis (BaSr)$(CoFe)O_3$ Cathode for IT-SOFC by GNP (GNP 법을 이용한 저온형 SOFC용 (BaSr)$(CoFe)O_3$ 공기극의 제조 및 특성 평가)

  • Lee, Mi-Jai;Moon, Ji-Woong;Kim, Sei-Ki;Ji, Mi-Jung;Hwang, Hae-Jin;Lim, Yong-Ho;Choi, Byung-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.51-54
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    • 2006
  • Cathode material, $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$, for low temperature SOFC was prepared by the glycine-nitrate synthesis process (GNP). The characteristics of the synthesized powders were studied with controlling pH of a precursor. The synthesis BSCF powders with pH were agglomeration state and calcinations temperature has not influence on particles. Highly acidicprecursor solution increased a single phase forming the temperature. Also, synthesis BSCF powder was show result for thermal analysis and alteration of difference crystal with pH. It is considered that Ba and Sr cannot complex by carboxylic acid group of glycine, because under highly acidic condition the caboxylic group mainly combined with $H^+$ insead of alkali and alkaline earth cations. In case of using precursor solution with pH $2{\sim}3$, a single perovskite phase was obtained at $1000^{\circ}C$. Polarization resistance of $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ was measured by AC impedance spectroscopy from the two electrode symmetric cell. Area specific resistance of the $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ air electrode at $500^{\circ}C\;and\;600^{\circ}C$ were $0.96{\Omega}?cm^2$ and $0.16{\Omega}?cm^2$, respectively.

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Antenna Gain Enhancement Using FSS(Frequency Selective Surface) with Defect Mode Characteristic (결함 모드 특성을 갖는 주파수 선택적 표면에 의한 안테나 이득 향상)

  • Kim, June-Hyong;Nam, Sung-Soo;Cho, Tae-Joon;Lee, Hong-Min
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.2
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    • pp.147-153
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    • 2009
  • In this paper, FSS(Frequency Selective Surface) using defect mode characteristic is proposed. The unit cell using defect mode characteristic of the proposed FSS is offered lower resonant frequency in the same cell size. The number of suitable array is optimized 13 by 13. Also, the patch antennas operated in WCDMA(Wideband Code Division Multiple Access) Tx band and Rx band are designed for the comparison. The gain value of proposed FSS-1 complex structure (the patch antenna of Tx band and FSS) is improved 3.3 dB from 9.98 dBi to 13.28 dBi in Tx band. The gain value of proposed FSS-2 complex structure(the patch antenna of Rx band and FSS) is improved 5.53 dB from 9.81 dBi to 15.34 dBi in Rx band. Also the measured impedance bandwidth($VSWR{\leq}2$) of manufactured $13{\times}13$ array antenna is from 337 MHz(1.87 to 2.21 GHz). The measured radiation gain is 11.39 dBi(1.94 GHz), 13.11 dBi(2.05 GHz), 11.09 dBi(2.14 GHz). The measured radiation efficiency is 81 %. Because the proposed FSS structure has more higher gain, it will be applied to antenna of WCDMA repeater system.